Abstract
A kinetic model for the β-picoline oxidation over vanadia-titania catalyst is presented. The model covers the reaction mechanism, temperature dependences and a system of kinetic equations. The activation energies and constants in these equations are calculated.
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E.M. Alkaeva, T.V. Andrushkevich, G.A. Zenkovets, M.G. Makarenko: Russian Patent 2049089, 1995; Euro Patent 0747359 A1 WO 9,520,577, 1995; US Patent 5,728,837, 1998.
D. Heinz, W. Hoelderich, S. Krill, W. Boeck, K. Huthmacher: DE Patent 19, 839,559 A12000.03.02, 2000.
E.V. Ovchinnikova, T.V. Andrushkevich, L.A. Shadrina: React. Kinet. Catal. Lett., 82, 191 (2004).
E.V. Ovchinnikova, T.V. Andrushkevich: React. Kinet. Catal. Lett., 93, 203 (2008).
V.M. Bondareva, E.V. Ovchinnikova, T.V. Andrushkevich: React. Kinet. Catal. Lett., 94, 327 (2008).
G.Ya. Popova, T.V. Andrushkevich, Yu.A. Chesalov, E.V. Ovchinnikova: React. Kinet. Catal. Lett., 87, 387 (2006).
G.Ya. Popova, Yu.A. Chesalov, T.V. Andrushkevich: React. Kinet. Catal. Lett., 83, 353 (2004).
V.M. Bondareva, T.V. Andrushkevich, Yu.D. Pankratiev: React. Kinet. Catal. Lett., 61, 337 (1997).
G.Ya. Popova, T.V. Andrushkevich, I.I. Zakharov, Yu.A. Chesalov: Kinet. Catal., 46, 217 (2005).
A.A. Davydov: in N.T. Sheppard (Eds.), Molecular Spectroscopy of Oxide Catalyst Surfaces, J. Wiley, Chichester 2003.
T.V. Andrushkevich: Kinet. Catal., 38, 266 (1997).
G.Ya. Popova, A.A. Davydov, T.V. Andrushkevich, I.I. Zakharov: Kinet. Catal., 36, 125 (1995).
G.K. Boreskov: in K.I. Zamaraev, A.V. Khasin (Eds.), Heterogeneous Catalysis, Nova Science Publ., Hauppauge 2003.
G.S. Yablonskii, V.I. Bykov, A.N. Gorban, V.I. Elokhin: in R.G. Compton (Ed.), Kinetic Models of Catalytic Reactions. Comprehensive Chemical Kinetics, Vol. 32, Chapter 4. Elsevier, Amsterdam-Oxford-New York-Tokyo 1991.
H.H. Rosenbrock, C. Storey: in Computational Techniques for Chemical Engineers, p. 107. Pergamon Press, New York 1968.
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Ovchinnikova, E.V., Popova, G.Y. & Andrushkevich, T.V. Kinetics of oxidation of β-picoline to nicotinic acid over vanadia-titania catalyst. 4. Kinetic model. React Kinet Catal Lett 96, 91–100 (2009). https://doi.org/10.1007/s11144-009-5461-4
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DOI: https://doi.org/10.1007/s11144-009-5461-4