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Reaction Kinetics and Catalysis Letters

, Volume 96, Issue 1, pp 5–12 | Cite as

Primary kinetic isotope effect in the nitrosation of 1,3- dialkylureas

  • Guillermo González-Alatorre
  • Daniel Pérez-Méndez
  • Andrés Godínez-García
  • Eleazar M. Escamilla-Silva
  • Vicente Rico-Ramírez
Article

Abstract

In the nitrosation mechanism of 1,3 dialkylureas, the existence of protonic transfer to the solvent as a rate-limiting step was confirmed when a primary kinetic isotope effect was observed in these reactions.

Keywords

Primary kinetic isotope 1,3-dialkylureas 

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Copyright information

© Springer Science+Business Media, LLC. 2009

Authors and Affiliations

  • Guillermo González-Alatorre
    • 1
  • Daniel Pérez-Méndez
    • 1
  • Andrés Godínez-García
    • 1
  • Eleazar M. Escamilla-Silva
    • 1
  • Vicente Rico-Ramírez
    • 1
  1. 1.Instituto Tecnológico de CelayaMéxico CPMéxico

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