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Reaction Kinetics and Catalysis Letters

, Volume 97, Issue 2, pp 165–171 | Cite as

Size dependent interface energy and catalytic kinetics on non-ideal surfaces

  • Dmitry Yu. Murzin
Article

Abstract

Thermodynamic analysis is applied to describe the size dependent kinetics on surfaces with lateral interactions. A two-step sequence, often used in heterogeneous catalysis to account for catalytic kinetics, was modified to include the dependency of interfacial free energy on the particle size.

Keywords

Nanocatalysis Thermodynamics Non-ideal surfaces Kinetics 

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2009

Authors and Affiliations

  1. 1.Åbo Akademi UniversityTurku/ÅboFinland

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