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Reaction Kinetics and Catalysis Letters

, Volume 95, Issue 2, pp 313–320 | Cite as

Oxidation of isobutane over hydrothermally synthesized Mo-V-Te-Nb-O mixed oxide catalysts

  • Jingqi Guan
  • Ying Yang
  • Bo Liu
  • Yuanyuan Ma
  • Xiaofang Yu
  • Jing Liu
  • Qiubin Kan
Article

Abstract

MoV0.3Te0.17 and MoV0.3Te0.17Nb0.12 catalysts were prepared by a hydrothermal synthesis route and tested for the oxidation of isobutane and isobutene. Characterization results showed that the structure and property of Mo-V-Te-based catalysts are relatively different depending on the presence of the Nb element. Catalytic tests showed that the selectivity of methacrolein can comparatively be improved by the addition of Nb into the MoV0.3Te0.17 catalyst for the selective oxidation of isobutane.

Keywords

Isobutane selective oxidation methacrolein Mo-V-Te-Nb-O mixed oxide catalysts 

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References

  1. 1.
    T. Ushikubo, H. Nakamura, Y. Koyasu, S. Wajiki: US Pat. 5380933 (1995).Google Scholar
  2. 2.
    M. Lin, M.W. Linsen: Eur. Pat. 962253 (1999).Google Scholar
  3. 3.
    J.M.M. Millet, H. Roussel, A. Pigamo, J.L. Dubois, J.C. Jumas: Appl. Catal. A, 232, 77 (2002).CrossRefGoogle Scholar
  4. 4.
    J.M. Oliver, J.M. López Nieto, P. Botella, A. Mifsud: Appl. Catal. A, 257, 67 (2004).CrossRefGoogle Scholar
  5. 5.
    R.K. Grasselli, J.D. Burrington, D.J. Buttrey, P. DeSanto Jr., C.G. Lugmair, A.F. Volpe Jr., T. Weingand: Top. Catal., 23, 5 (2003).CrossRefGoogle Scholar
  6. 6.
    J. Guan, M. Jia, S. Jing, Z. Wang, L. Xing, H. Xu, Q. Kan: Catal. Lett., 108, 125 (2006).CrossRefGoogle Scholar
  7. 7.
    J. Guan, S Jing, S. Wu, H Xu, Z. Wang, Q. Kan: React. Kinet. Catal. Lett., 90, 27 (2007).CrossRefGoogle Scholar
  8. 8.
    J.Q. Guan, S.J. Wu, H.S. Wang, S.B. Jing, G.J. Wang, K.J. Zhen, Q.B. Kan: J. Catal., 251, 354 (2007).CrossRefGoogle Scholar
  9. 9.
    H. Murayama, D. Vitry, W. Ueda, G. Fuchs, M. Anne, J.L. Dubois: Appl. Catal. A, 318, 137 (2000).Google Scholar
  10. 10.
    W. Ueda, D. Vitry, T. Katou: Catal. Today, 99, 43 (2005).CrossRefGoogle Scholar
  11. 11.
    V.V. Guliants, R. Bhandari, B. Swaminathan, V.K. Vasudevan, H.H. Brongersma, A. Knoester, A.M. Gaffney: J. Phys. Chem. B, 109, 24046 (2005).CrossRefGoogle Scholar
  12. 12.
    L. Kihlborg: Acta Chem. Scand., 23, 1834 (1969).CrossRefGoogle Scholar
  13. 13.
    T. Ekstrom, M. Nygren: Acta Chem. Scand., 26, 1827 (1972).CrossRefGoogle Scholar
  14. 14.
    J.W. Robinson: Handbook of Spectroscopy, Vol. 1, p. 615, CRC Press, Boca Raton, FL, 1974.Google Scholar

Copyright information

© Springer Science+Business Media, LLC. 2008

Authors and Affiliations

  • Jingqi Guan
    • 1
  • Ying Yang
    • 1
  • Bo Liu
    • 1
  • Yuanyuan Ma
    • 1
  • Xiaofang Yu
    • 1
  • Jing Liu
    • 1
  • Qiubin Kan
    • 1
  1. 1.College of ChemistryJilin UniversityChangchunPeople’s Republic of China

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