Advertisement

Reaction Kinetics and Catalysis Letters

, Volume 91, Issue 2, pp 391–398 | Cite as

Effect of acidic and metallic sites on the catalytic performance of Pd/ZSM-5 catalysts in the one-step synthesis of mibk

  • Piaoping Yang
  • Yongchen Shang
  • Jun Wang
  • Jianfeng Yu
  • Tonghao Wu
Article

Abstract

The acidic properties of Pd/ZSM-5 catalysts were characterized by NH3-TPD and FT-IR of d3-acetonitrile adsorption. Effect of Pd loading on the catalytic activity and product distribution was studied in the one-step synthesis of methyl isobutyl ketone from acetone. The results indicated that a proper balance between acidic and metallic sites was necessary to obtain high catalytic performance.

Keywords

Acidity metal sites one-step synthesis MIBK 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    W. Reith, M. Dettmet, H. Widdecke, B. Fleischer: Stud. Surf. Sci. Catal., 59, 487 (1991).CrossRefGoogle Scholar
  2. 2.
    K. Schmitt, J. Distodorf, W. Flakus: U.S. 3, 953,517 (1976).Google Scholar
  3. 3.
    C.U. Pittman, Y. F. Liang: J. Org. Chem., 45, 5048 (1980).CrossRefGoogle Scholar
  4. 4.
    J. Wollner, K.K. Moers: U.S. 3, 405, 178 (1968).Google Scholar
  5. 5.
    Y. Watanabe, Y. Matsumura, Y. Izumi: Bull. Chem. Soc. Jpn., 47, 2922 (1974).CrossRefGoogle Scholar
  6. 6.
    Y. Higashio, T. Nakayama: Catal. Today, 28, 127 (1996).CrossRefGoogle Scholar
  7. 7.
    E.F. Smith, T. Haute: U.S. 5, 499, 172 (1950).Google Scholar
  8. 8.
    Y. Too, T. Nakayama: Jpn. 6, 225, 835 (1987).Google Scholar
  9. 9.
    T. Maki, T. Yokohama, Y. Sumino: Jpn. 6, 396, 145 (1998).Google Scholar
  10. 10.
    K.H. Lin, A. N. Ko: Appl. Catal. A, 147, L259 (1996).Google Scholar
  11. 11.
    T.J. Huang, W.O. Haag: U.S. 4, 339, 606 (1982).Google Scholar
  12. 12.
    K.D. Olson: U.S. 4, 704, 478 (1987).Google Scholar
  13. 13.
    L.M. Gandia, R. Malm, R. Marchand: Appl. Catal. A: Gen., 114, L1 (1994).Google Scholar
  14. 14.
    Y.Z. Chen, C.M. Hwang, C.W. Liaw: Appl. Catal. A: Gen., 169, 207 (1998).CrossRefGoogle Scholar
  15. 15.
    B. Wichterlová, Z. Tvarůžková, Z. Sobalik, P. Sarv: Micropor. Mesopor. Mater., 24, 223 (1998).CrossRefGoogle Scholar
  16. 16.
    J.G. Post, J.H.C. van Hoff: Zeolites, 4, 9 (1984).CrossRefGoogle Scholar
  17. 17.
    N. Kumar, R. Byggningsbacka, M. Korpi, L.E. Linfors, T. Salmi: Appl. Catal. A: Gen., 227, 97 (2002).CrossRefGoogle Scholar
  18. 18.
    S.M. Yang, Y.M. Wu: Appl. Catal. A: Gen., 192, 211 (2000).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media LLC 2007

Authors and Affiliations

  • Piaoping Yang
    • 1
  • Yongchen Shang
    • 2
  • Jun Wang
    • 1
  • Jianfeng Yu
    • 3
  • Tonghao Wu
    • 3
  1. 1.College of Material Science and Chemical EngineeringHarbin Engineering UniversityHarbinP.R. China
  2. 2.College of ChemistryHarbin Normal UniversityHarbinP.R. China
  3. 3.College of ChemistryJilin UniversityChangchunP.R. China

Personalised recommendations