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Reactions of 2,4,6-tripyridyl-1,3,5-s-triazine and its Fe(ii) complex with OH· and eaq-

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Summary

Pulse radiolysis studies indicated that OH· and eaq- formed adducts with 2,4,6-tripyridyl-1,3,5-s-triazine (tptz). The OH-adduct showed an absorption maximum at 290 nm, while the adduct formed from the attack of eaq- and subsequent protonation of the anion, has an absorption maximum at 300 nm. In case of the complex, Fe(tptz)22+, both OH· and eaq- gave ligand centered adducts. All the adducts decayed by second order dimerization or disproportionation, a disproportionation reaction in case of the complex.

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Authors and Affiliations

  1. Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan

    Pamidipati Gayatri Hela

  2. School of Chemistry, Andhra University, Visakhapatnam - 530 003, INDIA

    Ramireddy Nageswara Reddy

  3. School of Chemistry, Andhra University, Visakhapatnam - 530 003, INDIA

    Nageswara Rao Anipindi

  4. Radiation and Chemical Dynamics Division, Bhabha Atomic Research Center, Trombay, Mumbai, India

    K. Indira Priyadarsini

  5. Radiation and Chemical Dynamics Division, Bhabha Atomic Research Center, Trombay, Mumbai, India

    Tulsi Mukherji

Authors
  1. Pamidipati Gayatri Hela
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  2. Ramireddy Nageswara Reddy
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  3. Nageswara Rao Anipindi
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  4. K. Indira Priyadarsini
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  5. Tulsi Mukherji
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Gayatri Hela, P., Nageswara Reddy, R., Rao Anipindi, N. et al. Reactions of 2,4,6-tripyridyl-1,3,5-s-triazine and its Fe(ii) complex with OH· and eaq-. React Kinet Catal Lett 85, 79–87 (2005). https://doi.org/10.1007/s11144-005-0246-x

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  • DOI: https://doi.org/10.1007/s11144-005-0246-x

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