Dynamic nuclear polarization in strong-field nuclear magnetic resonance (NMR) spectroscopy requires terahertz radiation with moderate power levels. Nowadays, conventional gyrotrons are used almost exclusively to generate such radiation. In this review paper, we consider alternative variants of electronic microwave oscillators which require much weaker magnetic fields for their operation, namely, large-orbit gyrotrons operated at high cyclotron-frequency harmonics and Čerenkov-type devices, such as a backward-wave oscillator and a klystron frequency multiplier with tubular electron beams. Additionally, we consider the possibility to use the magnetic field created directly by the solenoid of an NMR spectrometer for operation of both the gyrotron and the backward-wave oscillator. Location of the oscillator in the spectrometer magnet makes it superfluous to use an additional superconducting magnet creating a strong field, significantly reduces the length of the radiation transmission line, and, in the case of Čerenkov-type devices, allows one to increase considerably the output-signal power. According to our calculations, all the electronic devices considered are capable of ensuring the power required for dynamic nuclear polarization (10 W or more) at a frequency of 260 GHz, whereas the gyrotrons, including their versions proposed in this paper, remain a single option at higher frequencies.
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L. R. Becerra, G. J. Gerfer, R. J. Temkin, et al., Phys. Rev. Lett., 71, 3562 (1993).
R. G. Griffin and T. F. Prisner, Phys. Chem. Chem. Phys., 12, 5737 (2010).
E. A. Nanni, A. B. Barnes, R. G. Griffin, and R. J. Temkin, IEEE Trans. THz Sci. Technol., 1, 145 (2011).
C. Griesinger, M. Bennati, H. M. Vieth, et al., Progress in NMR Spectrosc., 64, 4 (2012).
V. S. Bajaj, C. T. Farrar, M. K. Hornstein, et al., J. Magn. Resonance, 213, 404 (2011).
T. Idehara, T. Saito, I. Ogawa, et al., Appl. Magn. Resonance., 34, 265 (2008).
V. Denisenkov, M. J. Prandolini, M. Gafurov M., et al., Phys. Chem. Chem. Phys., 12, 5786 (2010).
V. E. Zapevalov, S. Yu. Kornishin, and A. V. Kotov, Radiophys. Quantum Electron., 53, No. 4, 229 (2010).
H. Jory, R&D Technical Report ECOM-01873-F, Varian Associates, Palo Alto (1968).
D. B. McDermott, N. C. Luhmann, Jr., A. Kupiszewski, and H. R. Jory, Phys. Fluids, 26, No. 7, 1936 (1983).
W. Lawson, W. W. Destler, and C. D. Striffler, IEEE Trans. Plasma Sci., 13, 444 (1985).
V. L. Bratman, A. E. Fedotov, Yu. K. Kalynov, et al., IEEE Trans. Plasma Sci., 27, No. 2, 456 (1999).
V. L. Bratman, Yu. K. Kalynov, V. N. Manuilov, and S. V. Samsonov, Radiophys. Quantum Electron., 48, Nos. 10–11, 731 (2005).
V. L. Bratman, Yu. K. Kalynov, and V. N. Manuilov, J. Commun. Technol. Electron., 56, No. 4, 500 (2011).
V. L. Bratman, Yu. K. Kalynov, and V. N. Manuilov, Radiophys. Quantum Electron., 52, No. 7, 472 (2009).
V. L. Bratman, Y. K. Kalynov, and V. N. Manuilov, Phys. Rev. Lett., 102, No. 24, 245101 (2009).
V. I. Fedorov, A. S. Pogodin, and Yu. K. Kalynov, Millimetr. Volny Biol. Med, No. 3. (63), 27 (2011).
V. L. Bratman, V. G. Zorin, Y. K. Kalynov, et al., Phys. Plasmas, 18, No. 8, 083507 (2011).
V. E. Zapevalov, S. A. Malygin, V. G. Pavel’ev, and Sh. E. Tsimring, Radiophys. Quantum Electron., 27, No. 9, 846 (1984).
V. E. Zapevalov, A. N. Kuftin, V. N. Manuilov, et al., in: Proc. 8th Int. Workshop “Strong Microwaves and Terahertz Waves: Sources and Applications” (SMP-2011), Nizhny Novgorod–St. Petersburg, Russia, July 9–16, 2011, p. 143.
V. L. Bratman, M. Yu. Glyavin, V. E. Zapevalov, et al., in: IInd Dynamic Nuclear Polarization Symposium: Theory, Hardware, Applications, Radicals, Koenigstein, Germany, Sept. 2–4, 2009, p.5.
V. L. Bratman, A. E. Fedotov, Yu. K. Kalynov, in: 8th Int. Workshop “Strong Microwaves and Terahertz Waves: Sources and Applications” (SMP-2011), Nizhny Novgorod–St. Petersburg, Russia, July 9-16, 2011, p. 9.
J. R. Sirigiri and T. Maly, “Integrated high-frequency generator system utilizing the magnetic field of the target application”, Patent Application No. US 2012/0176133 A1, July 12, 2012.
L. A. Surin, B. S. Dumesh, F. Lewen, et al., Rev. Sci. Instrum., 72, No. 6, 2535 (2001).
D. Chernin, A. Burke, I. Chernyavskiy, et al., in: Proc. 11th Int. Vacuum Electronics Conf., Monterey, California, May 18–20, 2010, p. 217.
A. Roitman, P. Horoyski, B. Steer, and D. Berry, in: Proc. 14th IEEE Int. Vacuum Electronics Conf., May 21–23, 2013, Paris, France, http://www.cpii.com/product.cfm/7/40/158.
S. S. Ponomarenko, S. A. Kishko, V. V. Zavertanniy, et al., IEEE Trans. Plasma Sci., 41, No. 1, 82 (2013).
V. P. Shestopalov, ed. , Generators of Diffraction Radiation [in Russian], Naukova Dumka, Kiev (1991).
V. L. Bratman, B. S. Dumesh, A. E. Fedotov, et al., IEEE Trans. Plasma Sci., 38, 1466 (2010).
V. L. Bratman, V. A. Gintsburg, Yu. A. Grishin, et al., Radiophys. Quantum Electron., 49, No. 11, 866 (2006).
V. L. Bratman, A. E. Fedotov, and P. B. Makhalov, Phys. Plasmas, 19, No. 2, 020704 (2012).
E. A. Nanni, S. M. Lewis, M. A. Shapiro, and R. J. Temkin, in: Proc. 14th IEEE Int. Vocuum Electronics Conf., May 21–23, 2013, Paris, France, doi: 10.1109/IVEC.2013.657 1109
I. V. Bandurkin, V. L.Bratman, Y. K. Kalynov, et al., in: Proc. 33rd IEEE Int. Conf. Infrared, Millimeter and Terahertz Waves (2008).
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 56, Nos. 8–9, pp. 589–600, August–September 2013.
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Bratman, V.L., Kalynov, Y.K., Makhalov, P.B. et al. New Versions of Terahertz Radiation Sources for Dynamic Nuclear Polarization in Nuclear Magnetic Resonance Spectroscopy. Radiophys Quantum El 56, 532–541 (2014). https://doi.org/10.1007/s11141-014-9456-2
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DOI: https://doi.org/10.1007/s11141-014-9456-2