Features of Chromium Carbide Synthesis Using Different Forms of Carbon

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The interaction of chromium oxide with different forms of carbon in a wide temperature range is investigated. The phase composition and morphology of the resulting powder product are examined. It is established that Cr3C2 and Cr7C3 single-phase chromium carbide is formed at 1400 and 1500°C, respectively. It is shown that the smallest particle size (0.85 μm) is due to the mixed structural state of Cr7C3 and Cr3C2 carbides.

Keywords

chromium carbide carbon nanotubes exfoliated graphite natural graphite chromium oxide synthesis induction furnace 

References

  1. 1.
    Z. Zhao, H. Zheng, Y. Wang, et al., “Synthesis of chromium carbide (Cr3C2) nanopowders by the carbonization of the precursor,” Int. J. Ref. Met. Hard Mater., 29, No. 5, 614–617 (2011).CrossRefGoogle Scholar
  2. 2.
    R. E. Kahrizsangi, H. M. Zadeh, and V. Nemati, “Synthesis of chromium carbide by reduction of chromium oxide with methane,” Int. J. Ref. Met. Hard Mater., 28, No. 3, 412–415 (2010).CrossRefGoogle Scholar
  3. 3.
    A. Nikitin, Y. Gogotsi, and H. S. Nalwa, “Nanostructured Carbide-Derived Carbon”: in: Encyclopedia of Nanoscience and Nanotechnology. Vol. 7, American Scientific Publishers, CA (2004), pp. 553–574.Google Scholar
  4. 4.
    S. Loubiere, Ch. Laurent, J. P. Bonino, and A. Rousset, “Microstructure and reactivity of Cr3C2 powders of different morphology,” Mater. Res. Bull., 30, No. 12, 1535–1546 (1995).CrossRefGoogle Scholar
  5. 5.
    Hao-Tung Lin, Sheng-Chang Wang, Jow-Lay Huang, Shin-Yun Chang, “Processing of hot pressed Al2O3–Cr2O3/Cr-carbide nanocomposite prepared by MOCVD in fluidized bed,” J. Eur. Ceram. Soc., 27, No. 16, 4759–4765 (2007).CrossRefGoogle Scholar
  6. 6.
    I. G. Chernysh, I. I. Karpov, G. P. Prikhod’ko, and V. M. Shai, Physical–Chemical Properties of Graphite and Its Compounds [in Russian], Nauk. Dumka, Kiev (1990), p. 199.Google Scholar
  7. 7.
    R. Kiffer and P. Shwartskopf, Hard Alloys [in Russian], Metallurgizdat, Moscow (1957), p. 664.Google Scholar
  8. 8.
    G. V. Samsonov and Ya. S. Umanskii, Hard Compounds of Refractory Metals [in Russian], Metallurgizdat, Moscow (1957), p. 388.Google Scholar
  9. 9.
    R. Berkane, J. C. Gachon, J. Charles, and J. Hortz, “A thermodynamic study of the chromium–carbon system,” CALPHAD, 11, No. 2, 152–159 (1987).Google Scholar
  10. 10.
    E. A. Levashov, A. S. Rogachev, V. I. Yukhvid, and I. P. Borovinskaya, Physical-Chemical and Process Fundamentals of Self-Propagating High-Temperature Synthesis [in Russian], BINOM, Moscow (1999), p. 176.Google Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • N. A. Pinchuk
    • 1
  • M. P. Gadzyra
    • 1
  • I. D. Hnylytsia
    • 2
  1. 1.Frantsevich Institute for Problems of Materials ScienceNational Academy of Sciences of UkraineKyivUkraine
  2. 2.Ivano-Frankivsk National Technical University of Oil and GasIvano-FrankivskUkraine

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