Abstract
The objective of this work was to develop a scale adhesion assessment method by using a tensile testing machine equipped with a CCD camera to instantaneously observe the scale failure during a given exposure. The sample studied was carbon steel oxidised at 900 °C in synthetic air for 2 min, giving the scale thickness of 3.45 μm. The strain initiating the first spallation was determined to semi-quantitatively assess the scale adhesion, which was 3.71 ± 0.86% in the present study. The Galerie–Dupeux model based on U.R. Evans’ criterion was used to quantify the adhesion energy, which was 345 ± 39 J m−2 at the strain initiating the first spallation. However, during the tensile loading the scale spalled with the increased strain and at each strain there existed a particular value of the adhesion energy. To take into account the statistical nature of the scale spallation at different strains with different spallation ratios, the present work proposed the quantification of the average adhesion energy by weighting the adhesion energy at each strain by the increase in the spallation ratio taking place at that strain. Owing to the developed testing method that could record the spallation ratio as a function of the strain, the weighted average adhesion energy at strains up to 10% was quantified giving the value of 530 ± 9 J m−2. This energy represented the scale adhesion characteristics not only at the strain that scale firstly spalled but in a wider range of the imposed strains.
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References
P. Sarrazin, A. Galerie and J. Fouletier, Mechanisms of high temperature corrosion—a kinetic approach, (Trans Tech Publication, Zurich, 2008).
R. Y. Chen and W. Y. D. Yuen, Oxidation of Metals 56, 89 (2001).
L. Suarez, R. Petrov, L. Kestens, M. Lamberigts and Y. Houbaert, Materials Science Forum 550, 557 (2007).
K. Ngamkham, N. Klubvihok, J. Tungtrongpairoj and S. Chandra-ambhorn, Steel Research International Metal Forming Special Edition, 991 (2012).
S. Taniguchi, K. Yamamoto, D. Megumi and T. Shibata, Materials Science and Engineering A. 308, 250 (2001).
L. Suarez, J. Schneider and Y. Houbaert, Defect and Diffusion Forum 273–276, 655 (2008).
Y. L. Yang, C. H. Yang, S. N. Lin, C. H. Chen and W. T. Tsai, Materials Chemistry and Physics 112, 566 (2008).
S. Chandra-ambhorn, T. Nilsonthi, Y. Wouters and A. Galerie, Corrosion Science 87, 101 (2014).
W. Wongpromrat, H. Thaikan, W. Chandra-ambhorn and S. Chandra-ambhorn, Oxidation of Metals 79, 529 (2013).
P. Promdirek, G. Lothongkum, S. Chandra-ambhorn, Y. Wouters and A. Galerie, Oxidation of Metals 81, 315 (2014).
W. Wongpromrat, V. Parry, F. Charlot, A. Crisci, L. Latu-Romain, W. Chandra-ambhorn, S. Chandra-ambhorn, A. Galerie and Y. Wouters, Materials at High Temperature. 32, 22 (2015).
A. Chattopadhyay, N. Bandyopadhyay, A. K. Das and M. K. Panigrahi, Scripta Materialia. 52, 211 (2005).
M. Zhang and G. Shao, Materials Science and Engineering A. 452–453, 189 (2007).
S. Chandra-ambhorn, T. Somphakdee and W. Chandra-ambhorn, Materials Science Forum. 696, 156 (2011).
A. Galerie, F. Toscan, E. N’Dah, K. Przybylski, Y. Wouters and M. Dupeux, Materials Science Forum. 461–464, 631 (2004).
M. M. Nagl, W. T. Evans, D. J. Hall and S. R. J. Saunders, Journal de Physique IV. 3, 933 (1993).
M. M. Nagl, S. R. J. Saunders, W. T. Evans and D. J. Hall, Corrosion Science. 35, 965 (1993).
M. M. Nagl, W. T. Evans, D. J. Hall and S. R. J. Saunders, Oxidation of Metals. 42, 431 (1994).
M. Rudolphi and M. Schutze, Oxidation of Metals. 79, 167 (2013).
M. Rudolphi and M. Schutze, Oxidation of Metals. 84, 45 (2015).
J. Mougin, M. Dupeux, L. Antoni and A. Galerie, Materials Science and Engineering A. 359, 44 (2003).
F. Toscan, L. Antoni, Y. Wouters, M. Dupeux and A. Galerie, Materials Science Forum. 461–464, 705 (2004).
S. Chandra-ambhorn, F. Roussel-Dherbey, F. Toscan, Y. Wouters, A. Galerie and M. Dupeux, Materials Science and Technology. 23, 497 (2007).
G. Bamba, Y. Wouters, A. Galerie, F. Charlot and A. Dellali, Acta Materialia. 54, 3917 (2006).
S. Chandra-ambhorn, T. Nilsonthi, Y. Madi and A. Galerie, Key Engineering Materials. 410–411, 187 (2009).
S. Chandra-ambhorn and N. Klubvihok, Oxidation of Metals. 85, 103 (2016).
T. Nilsonthi, Key Engineering Materials. 658, 106 (2015).
K. Ngamkham, S. Niltawach and S. Chandra-ambhorn, Key Engineering Materials. 462–463, 407 (2011).
S. Chandra-ambhorn, K. Ngamkham and N. Jiratthanakul, Oxidation of Metals. 80, 61 (2013).
T. Nilsonthi, S. Chandra-ambhorn, Y. Wouters and A. Galerie, Oxidation of Metals. 79, 325 (2013).
T. Nilsonthi, J. Tungtrongpairoj, S. Chandra-ambhorn, Y. Wouters and A. Galerie, Steel Research International, Metal Forming Special Edition, 987 (2012).
H. E. Evans, International Materials Review. 40, 1 (1995).
H. E. Evans, Oxidation of Metals. 79, 3 (2013).
N. Birks, G. H. Meier and F. S. Pettit, Introduction to the high-temperature oxidation of metals, (Cambridge University Press, Cambridge, 2006).
M. Krzyzanowski, J. H. Beynon and D. J. J. Farrugia, Oxide scale behavior in high temperature metal processing, (Wiley, Weinheim, 2010).
T. Nilsonthi, Ph.D. Thesis, KMUTNB, Thailand, and University of Grenoble, France, (2013).
C.-W. Yang, S.-M. Cho, Y.-H. Kang, J.-S. Lee and J.-W. Park, Materials Science and Engineering A. 556, 246 (2012).
H.-J. Kim, M.-W. Moon, D.-I. Kim, K.-R. Lee and K. H. Oh, Scripta Materialia. 57, 1016 (2007).
Acknowledgements
The authors acknowledge the research grants given by King Mongkut’s University of Technology North Bangkok (contract no. KMUTNB-NEW-59-06 and 57-10-09-217).
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Nilsonthi, T., Issaard, W. & Chandra-ambhorn, S. Development of the Scale Adhesion Assessment Using a Tensile Testing Machine Equipped with a CCD Camera. Oxid Met 88, 41–55 (2017). https://doi.org/10.1007/s11085-016-9679-z
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DOI: https://doi.org/10.1007/s11085-016-9679-z