Abstract
The spallation behaviour of alumina scales grown on FeCrAlY alloy was investigated. Substrates with different thicknesses were oxidized at 1200 °C for 25 h and cooled at various cooling rates. Generally, the scale formed on a thicker substrate or with a faster cooling rate exhibits a larger compressive stress. However, the failure behaviour of alumina scales is more complicated than expected for a compressed film. Specifically, (i) the extent of the spallation is not proportional to the residual stress in the oxide; (ii) the spallation does not occur immediately after cooling, but requires a period of incubation. This indicates that the residual stress is not the sole reason for the failure of scales. It was found that the carbide forms at the oxide–metal interface after cooling, which acts in conjunction with the residual stress to control the spallation of oxides. In addition, the mechanics analysis suggests that the microscopic roughness at the interface is another important factor.
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References
F. H. Stott, G. C. Wood and J. Stringer, Oxidation of Metals 44, 113 (1995).
V. K. Tolpygo, J. R. Dryden and D. R. Clarke, Acta Materialia 46, 927 (1998).
V. K. Tolpygo and D. R. Clarke, Materials Science and Engineering A 278, 142 (2000).
C. Zhu, X. F. Zhao, I. S. Molchana, G. E. Thompsona, G. Y. Liang and P. Xiao, Materials Science and Engineering A 528, 8687 (2011).
P. Y. Hou, Materials and Corrosion 51, 329 (2000).
P. Y. Hou, Journal of Material Science Letters 19, 577 (2000).
P. Y. Hou and J. Moskito, Oxidation of Metals 59, 559 (2003).
V. K. Tolpygo and H. Viefhaus, Oxidation of Metals 52, 1 (1999).
J. W. Hutchinson and Z. Suo, Advances in Applied Mechanics 29, 63 (1992).
J. L. Smialek, Materials Science and Engineering A 332, 11 (2002).
J. L. Smialek, JOM. 58, 29 (2006).
J. L. Smialek, Materials Science Forum 595–598, 191 (2008).
J. L. Smialek, D. M. Zhu and M. D. Cuy, Scripta Materialia 59, 67 (2008).
J. L. Smialek and B. A. Pint, Materials Science Forum 369–372, 459 (2001).
W. Zhang, J. R. Smith, X. G. Wang and A. G. Evans, Physical Review B 67, 245414 (2003).
X. G. Wang and J. R. Smith, Physical Review B 70, 081401 (2004).
V. Kochubey, D. Naumenko, E. Wessel, J. Le Coze, L. Singheiser, H. Al-Badairy, G. J. Tatlock and W. J. Quadakkers, Materials Letters 60, 1654 (2006).
D. M. Lipkin and D. R. Clarke, Oxidation of Metals 45, 267 (1996).
X. Zhao, J. Liu, D. S. Rickerby, R. J. Jones and P. Xiao, Acta Materialia 59, 6401 (2011).
V. K. Tolpygo and D. R. Clarke, Materials Science and Engineering A 278, 151 (2000).
M. Y. He, A. G. Evans and J. W. Hutchinson, Materials Science and Engineering A 245, 168 (1998).
V. Kochubey, D. Naumenko, E. Wessel, J. Le Coze, L. Singheiser, H. Al-Badairy, G. J. Tatlock and W. J. Quadakkers, Materials Letters 60, 1564 (2006).
P. Y. Hou and J. Stringer, Oxidation of Metals 38, 323 (1992).
P. Y. Hou, Annual Review of Materials Research 38, 275–298 (2008).
P. Y. Hou and G. D. Ackerman, Applied Surface Science 178, 156 (2001).
X. Y. Gong and D. R. Clarke, Oxidation of Metals 50, 355 (1998).
V. K. Tolpygo and D. R. Clarke, Acta Materialia 46, 5153 (1998).
M. Nicholas, Journal of Materials Science 3, 571 (1968).
V. K. Tolpygo and D. R. Clarke, Acta Materialia 46, 5167 (1998).
M. Y. He, A. G. Evans and J. W. Hutchinson, Acta Materialia 48, 2593 (2000).
A. G. Evans, M. Y. He and J. W. Hutchinson, Acta Materialia 45, 3543 (1997).
J. P. Buban, K. Matsunaga, J. Chen, N. Shibata, W. Y. Ching, T. Yamamoto and Y. Ikuhara, Science 311, 212 (2006).
S. K. Sharma, G. D. Ko and K. J. Kang, Journal of the European Ceramic Society 29, 355 (2009).
Acknowledgments
The authors would thank the financial support from the “1000 Plan Program”, the Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning (No. SHDP201303), the National Natural Science Foundation of China (No. 51271120 and No. 51401170) and the Key Program for Basic Research of Shanghai Science and Technology Committee (No. 12DJ1400400).
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Zhu, C., Zhao, X., Chen, Y. et al. Spallation Behaviour of Alumina Scale Formed on FeCrAlY Alloy After Isothermal Oxidation. Oxid Met 85, 391–408 (2016). https://doi.org/10.1007/s11085-015-9602-z
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DOI: https://doi.org/10.1007/s11085-015-9602-z