The corrosion of three commercial steels in a reducing atmosphere containing HCl plus H2S in the presence of ZnCl2–KCl deposits has been investigated at 400–500°C and compared with the corrosion of the same materials in a similar gas mixture free from H2S. The presence of H2S in the gas accelerated the corrosion of the three commercial steels beneath ZnCl2–KCl deposits. All materials suffered from severe corrosion with partial detachment and spalling of the external scales. Degradation of the steels resulted from the penetration of chlorine-containing species through the scale formed initially down to the metal matrix, because chorine-rich species were detected close to the alloy/scale interface. Although the corrosion resistance generally increased with increasing Cr content, even the high-Cr stainless steel SS304 is still unable to provide good corrosion resistance against the ZnCl2–KCl deposits in the presence of H2S due to the bad adherence of the scales to the alloy. The mechanisms of attack are discussed on the basis of thermodynamic considerations and of the active-oxidation model.
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References
Grabke H. J., Reese E., Spiegel M. (1995) Corrosion Science 37:1023
Zahs A., Spiegel M., Grabke H. J. (2000) Corrosion Science 42:1093
Spiegel M., Grabke H. J. (1995) Werkstoffe und Korrosion 46:121
M. Spiegel, and R. Warnecke, Corrosion. Paper No. 01182 (2001)
Krausse H. H., Vaughan D. A., Miller P. D. (1973) Transactions on ASME, Journal of Engineering for Power A95:45
Meadowcroft D. B.(1987) Materials Science and Engineering 88:313
Meadowcroft D. B. (1989) Materials Science and Engineering A121:669
Stringer J. (1985) High Temperature Technology 3:119
Zhang K., Niu Y., Al-Omary M., Wu W.T. (2004) Oxidation of Metals 62:323
Pan T. J., Niu Y., Al-Omary M., Wu W. T. (2005) High Temperature Materials and Processes 24:193
K. Zhang, T. J. Pan, and Y. Niu, High Temperature Materials and Processes submitted for publication
Spiegel M. (1999) Materials and Corrosion 50:373
Li Y. S., Niu Y., Wu W. T. (2003) Materials Science and Engineering A345:64
McNallan M. J., Liang W. W., Oh J. M., Kang C. T. (1982) Oxidation of Metals 17:371
Takemura M., McNallan M. J. (1995) Corrosion/95, Paper No. 568. NACE Inter,HoustonTX
Li Y. S., Al-Omary M., Niu Y., Zhang K. (2002) High Temperature Materials and Processes 21:12
Ishitsuka T. Nose K. (2000) Materials and Corrosion 51:177
Shinata Y., Takahashi F., Hashiura K. (1987) Materials Science and Engineering A87:399
D. Berztiss, A. Zahs, A. Schneider, M. Spiegel, H. Viefhaus, and H. J. Grabke, Zeitschrift fur Metallkunde (1999) 90:4
Tu J. P. (1997) Corrosion 53:365
Zheng X., Rapp R. A. (1997) Oxidation of Metals 48:527
Unsitalo M. A., Vuoristo P. M. J., Mäntylä T. A. (2002) Materials Science and Engineering A322:1
A. A. Verstak and V. E. Baranovski (1999) Corrosion 99, NACE International, Paper No. 74
Y. Kawahara and M. Kira (1995) Corrosion 95, NACE International, Paper No. 563
Hou P. Y., Prussner K., Fairbrother D. H., Roberts J. G., Alexander K. B. (1999) Scripta Materialia 40:241
Hou P. Y., Zhang X. F., Cannon R. M. (2004) Scripta Materialia 50:45
Haycock E.W. (1959) Journal of the Electrochemical Society 106:764
Gesmundo F., Viani F., Znamirowski W., Godlewski K., Bregani F. (1992) Werkstoffe und Korrosion 43:83
Backensto E. B., Drew R. D., Stapleford C. C. (1956) Corrosion 12:22
Backensto E. B., Sjoberg J. W. (1959) Corrosion 15:41
F. Gesmundo, F. Viani, and G. P. Toledo, Proceedings of 10th European Corrosion Congress. In: J. M. Costa, and A. D. Merricier (eds), Vol. I, The Institute of Materials, London, 1993, pp. 825
Sorell G., Hoyt W. B. (1956) Corrosion 12:33
Sorell G. (1958) Corrosion 14:33
G. P. De Gaudenzi, F. Gesmundo, G.P. Toledo, Stainless Steel 1993 (Firenze, Ottobre 1993), AIM, Milano (1993), 3:93
Gesmundo F., Roos C., Oquab D., Viani F. (1998) High Temperature Materials and Processes 17:145
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Financial support by the National Natural Scientific Foundation of China (NSFC) under the research grant No. 50671114 is gratefully acknowledged.
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Pan, T.J., Zeng, C.L. & Niu, Y. Corrosion of Three Commercial Steels Under ZnCl2 –KCl Deposits in a Reducing Atmosphere Containing HCl and H2S at 400–500°C. Oxid Met 67, 107–127 (2007). https://doi.org/10.1007/s11085-006-9047-5
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DOI: https://doi.org/10.1007/s11085-006-9047-5