Abstract
The oxidation behavior of Ti3Al1-x Si x C2 (x ⩽ 0.25) solid solutions was investigated in flowing air at 1000–1400°C for up to 20 hrs. Similar to Ti3AlC2, Ti3Al1-x Si x C2 (x⩽ 0.15) solid solutions display excellent oxidation resistance at all temperatures because of the formation of the continuous α-Al2O3 protective layers. However, Al2(SiO4)O formed during oxidation of Ti3Al1-x Si x C2 (x=0.2 and 0.25) solid solutions at and above 1100°C, which is believed to be responsible for the deterioration of oxidation resistance of Ti3Al0.75Si0.25C2 at 1300°C. Additionally, Ti5Si3 was also found in the oxidized samples. This implies that Ti5Si3 precipitated from Ti3Al1-x Si x C2 solid solutions during oxidation. But it has been proven that Ti5Si3 has little effect on the oxidation resistance of the material, which is attributed to an interstitial carbon effect.
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References
Pietzka M.A., and Schuster J.C. (1994) Journal of Phase Equilibrium 15:392
Tzenov N.V., and Barsoum M.W. (2000) Journal of American Ceramics Society 83:825
Wang X.H., and Zhou Y.C. (2002) Acta Materialias 50:3141
Low I.M. (1998) Journal of European Ceramics Society 18:709
Wang X.H., and Zhou Y.C. (2003) Corrosion Science 45:891
Y. C. Zhou, J. X. Chen, and J. Y. Wang (2006) Acta Materialia 54:1317
Zhu J.Q., Mei B.C., Xu X.W., and Liu J. (2004) Materials Letters 58:588
Zhou Y.C., Zhang H.B., Liu M.Y., Wang J.Y., and Bao Y.W. (2004) Materials Research Innovation 8:97
Zhang H.B., Zhou Y.C., Bao Y.W., and Li M.S. (2004) Acta Materialia 52:3631
Zhou Y.C., Sun Z.M., Chen S.Q., and Zhang Y. (1998) Materials Research Innovation 2:142
Wang X.H., and Zhou Y.C. (2002) Journal of Materials Chemistry 12:455
Jedlinski J., and Mrowec S. (1987) Materials Science and Engineering 87:281
Becker S., Rahmel A., Schorr M., and Schutze M. (1992) Oxidation of Metals 38:425
Y.G. Gogotsi, Porz L.F., and Dransfield G. (1993) Oxidation of Metals 39:69
R. A. Young, The Rietveld Method (Chapter 1), (Oxford University Press, 1993)
Thom A.J., Akinc M., Cavin O.B., and Hubbard C.R. (1994) Journal of Materials Science Letters 13:1657
Thom A.J., Young V.G., and Akinc M. (2000) Journal of Alloys Compounds 296:59
Williams J.J., Ye Y.Y., Kramer M.J., Ho K.M., Hong L., Fu C.L., and Malik S.K. (2000) Intermetallics 8:937
Williams J.J., and Akinc M. (2002) Oxidation Metals 58:57
Sun Z.M., Zhou Y.C., and Li M.S. (2001) Corrosion Science 43:1095
Sun Z.M., Zhou Y.C., and Li M.S. (2001) Acta Materialia 49:4347
Barsoum M.W., El-Raghy T., and Ogbuji LUJT (1997) Journal of Electrochemical Society 144:2508
Acknowledgments
This work was supported by the National Outstanding Young Scientist Foundation for Y. C. Zhou under Grant No. 59925208, Natural Sciences Foundation of China under Grant No. 50232040, No. 50302011, No.90403027, and ‘863’ project.
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Chen, J.X., Zhou, Y.C. Effect of SI Content on the Oxidation Resistance of Ti3Al1-x Si x C2 (x⩽ 0.25) Solid Solutions at 1000–1400°C in Air. Oxid Met 65, 123–135 (2006). https://doi.org/10.1007/s11085-006-9007-0
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DOI: https://doi.org/10.1007/s11085-006-9007-0