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Oxidation of Metals

, Volume 64, Issue 3–4, pp 185–205 | Cite as

Effect of Platinum on the Growth Rate of the Oxide Scale Formed on Cast Nickel Aluminide Intermetallic Alloys

  • Y. Cadoret
  • D. Monceau
  • M. -P. Bacos
  • P. Josso
  • V. Maurice
  • P. Marcus
Article

Abstract

Thermo-Gravimetric Analysis (TGA) and Scanning Electron Microscopy (SEM) data of the initial stages of oxidation of Ni50Al50 and Ni40Pt10Al50 alloys of low and high sulfur content at 900°C and 1100°C are reported. The results show that the addition of Pt promotes the growth of the transient θ-Al2O3 oxide scale. This effect is particularly sensitive in the initial stages of oxidation at 1100°C where Pt considerably increases the total mass gain. It is attenuated in the presence of a high sulfur content in the alloy, indicating a competitive effect of Pt and S on the segregation of Al. The slower θ-to-α transition observed in the presence of Pt leads to an extended lifetime of the θ phase layer, which is proposed to be beneficial to the relaxation of the stresses created by the growth of α-Al2O3.

Keywords

nickel aluminide platinum sulfur effect high temperature oxidation transition alumina 

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Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • Y. Cadoret
    • 1
    • 3
  • D. Monceau
    • 2
  • M. -P. Bacos
    • 1
  • P. Josso
    • 1
  • V. Maurice
    • 3
  • P. Marcus
    • 3
  1. 1.Département Matériaux Métalliques et ProcédésONERAChâtillon CedexFrance
  2. 2.CIRIMAT (UMR5085) CNRS-INPT-UPS, ENSIACETToulouse Cedex 4France
  3. 3.Laboratoire de Physico-Chimie des SurfacesCNRS (UMR 7045) – Université Pierre et Marie Curie, Ecole Nationale Supérieure de Chimie de ParisParis Cedex 05France

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