Abstract
Sr3MgSi2O8:Dy3+ Nano-rods were synthesized by using solid state reaction method. The structural properties, morphology and band structure properties of the phosphor was studied. The structural properties were examined by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. Bonding behaviour of the phosphor was also determined by recording the FTIR spectra of the phosphor. Band structure i.e. band gap of the phosphor was determined by recording the absorption spectrum. The absorption spectrum was recorded for the sample and the band gap was determined by using Tauc plot. Band gap of the phosphor was found around 5.4 eV.
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Bisen, D.P., Sharma, R., Brahme, N., Tamrakar, R.: Effect of temperature on the synthesis of CdS: Mn doped nanoparticles. Chalcogenide Lett. 6(9), 427–431 (2009)
Chen, Y., Zhou, B., Sun, Q., Wang, Y., Yan, B.: Synthesis and luminescence properties of Sr3MgSi2O8:Ce3 + , Tb3 + for application in near ultraviolet excitable white light-emitting-diodes. Superlattices Microstruct. 100, 158–167 (2016)
Gong, Y., Wang, Y., Xu, X., Li, Y., Xin, S., Shi, L.: The persistent energy transfer of Eu2+ and Mn2+ and the thermoluminescence properties of long-lasting phosphor Sr3MgSi2O8:Eu2+, Mn2+, Dy3+. Opt. Mater. 33(2011), 1781–1785 (2011)
Gou, Z., Chang, J., Zhai, W.: Preparation and characterization of novel bioactive dicalcium silicate ceramics. J. Eur. Ceram. Soc. 25, 1507–1514 (2005)
Hong, Y., Zi, W., Lan, S., Gan, S., Zou, H., Xub, X., Hong, G.: Photoluminescence properties and energy transfer in Ce3+/Dy3+ co-doped Sr3MgSi2O8 phosphors for potential application in ultraviolet white light-emitting diodes. Luminescence 28, 679–684 (2013)
Hwangbo, S., Jeon, Y.S., Kang, B.A., Kim, Y.S., Hwang, K.S., Kim, J.T.: Sol-gel derived blue-emitting Sr3MgSi2O8:Eu2+ oxide phosphor for ultraviolet emitting diodes. J. Ceram. Process. Res. 11(4), 513–515 (2010)
Kannan, R.Y., Salacinski, H.J., Butler, P.E., Seifalian, A.M.: Polyhedraloligomeric silsesquioxane nanocomposites: the nextgeneration material for biomedical applications. Acc. Chem. Res. 38(11), 879–884 (2005)
Kickelbick, G.: Concepts for the incorporation of inorganic building blocks into organic polymers on a nanoscale. Prog. Polym. Sci. 28, 83–114 (2003)
Kling, A., Rodriguez, A., Sangrador, J., Ortiz, M.I., Rodriguez, T., Ballesteros, C., et al.: Combined grazing incidence RBS and TEM analysis of luminescent nano-SiGe/SiO2multilayers. Nucl. Instrum. Methods Phys. Res. B 266, 1397–1401 (2008)
Lastusaari, M., Bos, A.J.J., Dorenbos, P., Laamanen, T., Malkamäki, M., Rodrigues, L.C.V., Hölsä, J.: Wavelength-sensitive energy storage in Sr3MgSi2O8:Eu2 + , Dy3+. J. Therm. Anal. Calorim. 121, 29–35 (2015)
Pabisch, S., Feichtenschlager, B., Kickelbick, G., Peterlik, H.: Effect of interparticle interactions on size determination ofzirconia and silica based systems—a comparison of SAXS, DLS, BET, XRD and TEM. Chem. Phys. Lett. 521, 91–97 (2012)
Pan, W., Ning, G.: Synthesis and luminescence properties of Sr3MgSi2O8:Eu2 + , Dy3 + by a novel silica-nanocoating method. Sens. Actuators A 139, 318–322 (2007)
Park, J.K., Choi, K.J., Kim, C.H., Park, H.D., Kim, H.K.: Luminescence characteristics of Sr3MgSi2O8: Eu blue phosphor for light-emitting diodes. Electrochem. Solid-State Lett. 7(10), H42–H43 (2004)
Presting, H., König, U.: Future nanotechnology developments for automotive applications. Mater. Sci. Eng. C 23(6–8), 737–741 (2003)
Sahu, I.P., Bisen, D.P., Brahme, N., Tamrakar, R.K.: Photoluminescence properties of europium doped di-strontium magnesium di-silicate phosphor by solid state reaction method. J. Radiat. Res. Appl. Sci. 8, 104–109 (2015)
Sanchez, C., Julien, B., Belleville, P., Popall, M.: Applications of hybrid organic–inorganic nanocomposites. J. Mater. Chem. 15, 3559–3592 (2005)
Talwar, G.J., Joshi, C.P., Moharil, S.V., Dhopte, S.M., Muthal, P.L., Kondawar, V.K.: Combustion synthesis of Sr3MgSi2O8:Eu2+ and Sr2MgSi2O7:Eu2+ phosphors. J. Lumin. 129, 1239–1241 (2009)
Tamrakar, R.K.: Studies on Absorption Spectra of Mn Doped CdS Nanoparticles. LAP LAMBERT Academic Publishing, Saarbrücken (2012)
Tamrakar, R.K., Bisen, D.P.: Optical and kinetic studies of CdS: Cu nanoparticles. Res. Chem. Intermed. 39(7), 3043–3048 (2013)
Tamrakar, R.K., Bisen, D.P., Upadhyay, K.: Change in thermoluminescence behaviour of cubic Gd2O3: Yb3+ phosphors with successive increase in Yb3+ ion concentrations. Radiat. Phys. Chem. 130, 321–333 (2017)
Wan, Y., Zhao, D.: On the controllable soft-templating approachto mesoporous silicates. Chem. Rev. 107, 2821–2860 (2007)
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Authors are thankful to Dr. Mukul Gupta and Dr. N. P. Lalla of UGC-DAE CSR for their kind support during XRD and TEM measurements facilities.
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Dewangan, P., Bisen, D.P., Brahme, N. et al. Growth and synthesis of Sr3MgSi2O8:Dy3+ nanorod arrays by a solid state reaction method. Opt Quant Electron 50, 367 (2018). https://doi.org/10.1007/s11082-018-1634-6
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DOI: https://doi.org/10.1007/s11082-018-1634-6