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Nonlinear optical properties of new synthesized conjugated organic molecules based on pyrimidine and oxazepine

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Abstract

The third order nonlinear optical properties were reported for a new synthesized molecules based on triazepine and thianine, using the third harmonic generation (THG) technique. After synthesis, the powders were deposited on glass substrates using dip coating technique in order get thin films. These thin films were characterized, by different techniques, we mention the absorption and X-ray diffraction. The measurements of third order nonlinear optical susceptibilities were performed on these thin films, using the THG technique at 1064 nm. These investigations were completed by theoretical studies, using energy levels theory HOMO–LUMO and the second order hyperpolarizabilities (γ) results. Good agreement was obtained between the theoretical and experimental results.

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Acknowledgments

This work was supported by “Académie Hassan II des Sciences et Techniques”, Rabat, Morocco. Calculations have been carried out in Wroclaw Centre for Networking and Supercomputing (http://www.wcss.pl), Grant No. 282.

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Authors and Affiliations

  1. LOPCM Laboratory, Faculty of Science, Ibn Tofail University, Kenitra, Morocco

    Z. Sofiani, S. Khannyra & A. Boucetta

  2. Ecole Nationale des Sciences Appliquées (ENSAJ), Université Chouaïb Doukkali, El Jadida, Morocco

    M. ElJouad

  3. Chemistry Department, Faculty of Exact Sciences and Informatics, University of Jijel, Jijel, Algeria

    K. Bouchouit

  4. Laboratoire de Synthese Organique, Organomtallique et Théorique, Faculty of Sciences, Ibn Tofail University, Kenitra, Morocco

    H. Serrar, S. Boukhris & A. Souizi

  5. Faculty of Mathematics and Natural Sciences, Institute of Physics, J. Dlugosz Academy of Czestochowa, Al. ArmiiKrajowej 13/15, Czestochowa, Poland

    A. Migalska-Zalas

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  1. Z. Sofiani
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  2. S. Khannyra
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  3. A. Boucetta
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  4. M. ElJouad
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  5. K. Bouchouit
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  6. H. Serrar
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  7. S. Boukhris
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  8. A. Souizi
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  9. A. Migalska-Zalas
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Correspondence to Z. Sofiani or A. Migalska-Zalas.

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This article is part of the Topical Collection on Advanced Materials for Photonics and Electronics.

Guest Edited by Bouchta Sahraoui, Yahia Boughaleb, Kariem Arof, Anna Zawadzka.

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Sofiani, Z., Khannyra, S., Boucetta, A. et al. Nonlinear optical properties of new synthesized conjugated organic molecules based on pyrimidine and oxazepine. Opt Quant Electron 48, 282 (2016). https://doi.org/10.1007/s11082-016-0549-3

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  • DOI: https://doi.org/10.1007/s11082-016-0549-3

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