Abstract
The third order nonlinear optical response of some oligophenylene dyads were obtained at 30 ps, 532 nm using the Z-scan technique. The large nonlinearity of oligomers deriving from different substituted anisole is attributed to its rigid planar and intrachain charge transfer within the structure. The nonlinear absorption has been attributed to reverse saturable absorption-type behavior of the samples, while the imaginary part of the third order nonlinear susceptibility found has been of the order of 10\(^{-13}\) esu.
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Ben Khalifa, I.: About some properties of electro-synthesized short Oligo(Para-Fluoro-Anisole) (OPFA): a combined experimental and theoretical study. J. Mol. Struct. 997, 37–45 (2011)
Boyd, R.W.: Nonlinear Optics. Rochester, New York (2007)
Couris, S., Koudoumas, E., Ruth, A.A., Leach, S.: Concentration and wavelength dependence of the effective third-order susceptibility and optical limiting of C60 in toluene solution. J. Phys. B: At. Mol. Opt. Phys. 28, 4537–4554 (1995)
El Ouazzani, H., Iliopoulos, K., Pranaitis, M., Krupka, O., Smokal, V., Kolendo, A., Sahraoui, B.: Second- and third-order nonlinearities of novel push-pull azobenzene polymers. J. Phys. Chem. B 115, 1944 (2011)
El Ouazzani, H., Dabos-Seignon, S., Gindre, D., Iliopoulos, K., Todorova, M., Bakalska, R., Penchev, P., Sotirov, S., Kolev, T.S., Serbezov, V., Arbaoui, A., Bakasse, M., Sahraoui, B.: Novel styrylquinolinium dye thin films deposited by pulsed laser deposition for nonlinear optical applications. J. Phys. Chem. C 116, 7144–7152 (2012)
Fuks-Janczarek, I., Luc, J., Sahraoui, B., Dumur, F., Hudhomme, P., Berdowski, J., Kityk, I.V.: Third-order nonlinear optical figure of merits for conjugated TTF-quinone molecules. J. Phys. Chem. B 109(20), 10179–10183 (2005)
Iliopoulos, K., El-Ghayoury, A., Derkowska, B., Ranganathan, A., Batail, P., Gindre, D., Sahraoui, B.: Effect of the counter cation on the third order nonlinearity in anionic Au dithiolene complexes. Appl. Phys. Lett. 101, 261105–261105-4 (2012a)
Iliopoulos, K., El-Ghayoury, A., El Ouazzani, H., Pranaitis, M., Belhadj, E., Ripaud, E., Mazari, M., Sallé, M., Gindre, D., Sahraoui, B.: Nonlinear absorption reversing between an electroactive ligand and its metal complexes. Opt. Express 20, 25311–25312 (2012b)
Jiang, L., Chang, Q., Ouyang, Q.Y., Liu, H.B., Wang, Y.X., Zhang, X.R., et al.: Fabrication and nonlinear optical properties of an ultrathin film with acceptor–donor periodically overlapping structure. Chem. Phys. 324(2–3), 556–562 (2006)
Kajar, F., Nunzi, J.M.: Functional Organic and Polymeric Materials. Wiley, New York (2000)
Krupka, O., El-Ghayoury, A., Rau, I., Sahraoui, B., Grote, J.G., Kajzar, F.: NLO properties of functionalized DNA. Thin Solid Films 516, 8932–8936 (2008)
Rosso, V., Loicp, J., Renotte, Y., Lion, Y.: Optical non-linearity in disperse red 1 dye-doped sol-gel. J. Non Cryst. Solids 342(1–3), 140–145 (2004)
Sahraoui, B., Rivoire, G., Zaremba, J., Terkia-Derdra, N., Sallé, M.: Third-order nonlinear optical properties of new bisdithiafulvenyl-substituted tetrathiafulvalene. J. Opt. Soc. Am. B 15(2), 923–928 (1998)
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The authors would like to thank Prof. Bouchta Sahraoui, Dr. Konstantinos Iliopoulos and Dr. Abdelkrim El-Ghayoury for helpful discussions.
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Guezguez, I., Hjiri, M., Haj Said, A. et al. Third order nonlinear optical properties of oligophenylene dyads by open-aperture Z-scan technique. Opt Quant Electron 46, 7–13 (2014). https://doi.org/10.1007/s11082-013-9684-2
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DOI: https://doi.org/10.1007/s11082-013-9684-2