Skip to main content

Advertisement

Log in

The Use of the Weights-of-Evidence Modeling Technique to Estimate the Vulnerability of Groundwater to Nitrate Contamination

  • Published:
Natural Resources Research Aims and scope Submit manuscript

Abstract

The occurrence of elevated nitrate (NO 3 ) concentration in the aquifer of the Province of Milan (northern Italy) is related to both natural and anthropogenic variables. Using the weights-of-evidence modeling technique a specific vulnerability assessment has been performed. This study presents an evolution of previous applications of the proposed methodology as a consequence of an updating of the available database, in terms of data type, quality, and accuracy, and of a more specific and enhanced statistical controls onto the final results.

A comparison between the spatial distribution of vulnerability classes and the frequency of occurrences of nitrate in wells shows a high degree of correlation, both for low and high nitrate concentration. Similar results may be evidenced considering the correlation between posterior probability classes and mean nitrate concentrations in wells located in each of these classes: a high R 2 value (0.99) and the agreement with the threshold concentration value used to define prior probability testifies a general good quality of results. Groundwater-specific vulnerability has been classified in terms of vulnerability classes and, according to the outcomes of the model, the density of population can be considered the most impacting source of nitrate. Mean annual irrigation and groundwater depth can be identified as influencing factors in the distribution of nitrate, while agricultural practice appears a negligible factor.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8

Similar content being viewed by others

References

  • Acutis, M., and Provolo, M., 2003, Stime dei carichi diffusi di Azoto, Fosforo e Fitofarmaci da agricoltura nelle acque di superficie della Lombardia: IReR, Piano di Tutela delle Acque della regione Lombardia, Allegato 7, 53 p

  • Agterberg, F. P., Bonham-Carter, G. F., and Wright D. F., 1989, Weights of Evidence modelling: a new approach to mapping mineral potential, in Agterberg, F. P., and Bonham-Carter, G. F., eds., Statistical Applications in the Earth Sciences: Geol. Survey Canada, Paper 89-9, p. 171–183

  • Alberti, L., Francani, V., Masetti, M., and Parri, A., 2000, Valutazione del livello massimo raggiungibile dalla falda nel Comune di Milano: Quaderni di Geologia Applicata, Pitagora Editrice, Bologna, no. 7-4, p. 13–28

  • Bonham-Carter G. F., Agterberg F. P., Wright D. F., 1988, Integration of geological datasets for gold exploration in Nova Scotia: Photogrammetric Engineering and Remote Sensing, 54, 11, 1585–1592

    Google Scholar 

  • Calabrese E. J., Kostecki P.T. 1988, Soils contaminated by petroleum: Environmental and public health effects John Wiley & Sons, New York, 458

    Google Scholar 

  • Carranza E. J. M. 2004, Weights of evidence modeling of mineral potential: A case study using small number of prospects, Abra, Philippines: Natural Resources Research, 13, 3, 173–187

    Article  Google Scholar 

  • Chowdury S., Kehew A., Passero R. 2003, Correlation between nitrate contamination and ground water pollution potential: Ground Water, 41, 6, 735–745

    Article  Google Scholar 

  • Chung C. F., Fabbri A. G., 1999, Probabilistic prediction models for landslide hazard zonation, Photogrammetric Engineering & Remote Sensing 65, 12, 1389–1399

    Google Scholar 

  • Cohen, S., Creeger, S., Carsel, R., and Enfield, C., 1984, Potential for pesticide contamination of groundwater resulting from agriculture uses, in Krueger, R. R., and Seiber, J. N., eds., Treatement and Disposals of Pesticides Wastes: Am. Chemical Soc. Symp. Ser. No. 259 ACS, Washington, DC., p. 297–325

  • European Community, 1991, Council Directive 91/676/EEC of 12 December 1991 concerning the protection of waters against pollution caused by nitrates from agricultural sources, (Nitrate Directive) OJ L 375, 31.12.1991: p. 1–8

  • ERSAF (Ente di Ricerca per lo Sviluppo Agricolo e Forestale), 2004, Strumenti ed indirizzi per la gestione multifunzionale dei suoli agricoli (SIGMA), Piano di Tutela delle Acque della regione Lombardia, Allegato 10, 102 p

  • Fetter C. W. 1999. Contaminant hydrogeology: Prentice-Hall, Englewood Cliffs, New Jersey, 500 p

    Google Scholar 

  • Harrison, R. M., ed., 1992, Pollution: causes, effect and control: The Royal Society of Chemistry, London, Spec. Publ. No. 44, 322 p

  • ISTAT (Istituto di STatistica Applicata al Territorio), 2001, General Population and Housing Census. http://dawinci.istat.it/pop/

  • Kemp, L. D., Bonham-Carter, G. F., Raines, G. L., and Looney, C. G., 2001, Arc-SDM: Arcview extension for spatial data modelling using weights of evidence, logistic regression, fuzzy logic and neural network analysis. http://www.ige.unicamp.br/sdm/default_e.htm

  • Lake I. R., Lovett A. A., Hiscock K., Betson M., Foley A., Sunnenberg G., Evers S., Fletcher S. 2003 Evaluating factors influencing groundwater vulnerability to nitrate pollution: Developing the potential of GIS: Jour. Environmental Management, 68, 315–328

    Article  Google Scholar 

  • Lichtenberg E., Shapiro L. 1997 Agriculture and nitrate concentrations in Maryland community water system wells: Jour. Environmental Quality, 26(1) 145–153

    Article  Google Scholar 

  • Masetti M., Poli S., Sterlacchini S. 2005 Aquifer vulnerability assessment using weights of evidence modelling technique: application to the Province of Milan, northern Italy. Proc. of IAMG 2005: GIS and Spatial Analysis l, 499–504

    Google Scholar 

  • Nas B., Berktay A. 2006 Groundwater contamination by nitrates in the city of Konya, (Turkey): A GIS perspective Jour. Environmental Management v. 79, p.1–8

    Article  Google Scholar 

  • Nolan B. T., Hitt K. J., Ruddy B. C., 2002, Probability of nitrate contamination of recently recharged groundwaters in the conterminous United States: Environmental Science and Technology, 36, 10. 2138–2145

    Article  Google Scholar 

  • Raines G. L., 1999, Evaluation of weights of evidence to predict epithermal-gold deposits in the Great Basin of the Western United States: Natural Resources Research, 8, 4, 257–276

    Article  Google Scholar 

  • Sawatzky, D. L., Raines, G. L., Bonham-Carter, G. F., and Looney, C. G., 2004, ARCSDM3.1: ArcMAP extension for spatial data modelling using weights of evidence, logistic regression, fuzzy logic and neural network analysis. http://www.ige.unicamp.br/sdm/default_e.htm

  • Schwab G. O., Fangmeier D. D., Elliot W.J., Freveret R. K. 1993, Soil and water conservation engineering: John Wiley & Sons, New York 507 p

    Google Scholar 

  • Tesoriero A., Voss J. F. 1997, Predicting the probability of elevated nitrate concentrations in the Puget sound basin: implications for aquifer susceptibility and vulnerability: Ground Water, 35, 6 1029–1039

    Article  Google Scholar 

  • U.S. Soil Conservation Service, 1964, Hydrology. Section 4, SCS National Engineering Handbook: Washington, D.C., 30 p

  • Worral F., Besien T. (2005) The vulnerability of groundwater to pesticide contamination estimated directly from observations of presence or absence in wells. Jour. Hydrology 303(1–4):92–107

    Article  Google Scholar 

Download references

Acknowledgment

The authors would like to thank Jonathan Arthur from Florida Geological Survey and Gary Lee Raines from United States Geological Survey for comments and suggestions on the manuscript.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Masetti.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Masetti, M., Poli, S. & Sterlacchini, S. The Use of the Weights-of-Evidence Modeling Technique to Estimate the Vulnerability of Groundwater to Nitrate Contamination. Nat Resour Res 16, 109–119 (2007). https://doi.org/10.1007/s11053-007-9045-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11053-007-9045-6

Keywords

Navigation