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Synthesis of highly dispersible IZO and ITO nanocrystals for the fabrication of transparent nanocomposites in UV- and near IR-blocking

  • Shaojuan Luo
  • Jifei Zou
  • Hao Luo
  • Jiyun Feng
  • Ka Ming Ng
Research Paper
  • 129 Downloads

Abstract

Indium-doped zinc oxide (IZO) nanocrystals were successfully synthesized via the alcohol-assisted pyrolysis of a mixture of indium stearate and zinc stearate, which were fabricated by the direct reaction between the metals and molten stearic acid at a temperature of 260–270 °C. The ~ 10 nm IZO nanocrystals could be dispersed homogeneously in non-polar solvents such as hexane or chloroform, forming an optically clear solution. Transparent IZO-ITO (indium tin oxide)/polyvinyl butyral (PVB) nanocomposite with 10% IZO and 2% ITO loading shows more than 75% visible light transmittance, 100% UV-blocking (below 380 nm), and 100% blocking of NIR from 1600 to 2500 nm. Equilibrium molecular dynamic simulation results clearly stated the stearic acid wrapped IZO nanocrystals in PVB matrix would hardly affect the solubility parameter of PVB composite, indicating their good compatibility and guaranteeing the high transparency of PVB-based composites. Our strategy paves the way to facile synthesize non-polar solvent soluble nanocrystals and fabricate transparent PVB-based functional nanocomposite.

Keywords

IZO nanocrystals Dispersion Transparent nanocomposite UV- and NIR-blocking Equilibrium molecular dynamic simulation 

Notes

Author contributions

S.J. Luo and J.F. Zou contributed equally to this work. The manuscript was written through contributions of all authors. All authors have given approval to the final version of the manuscript.

Funding

This study is financially supported by the University Grants Council of the Hong Kong Government, Natural Science Foundation of Guangdong Province (2016A030310048), Student Innovation Development Foundation of Shenzhen University (PIDFP-ZR2017023) and China Postdoctoral Science Foundation (2016 M592530). Also, the technical support of the Raith-HKUST Nanotechnology Laboratory (project No. SEG_HKUST08) at MCPF of HKUST is appreciated.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

11051_2018_4198_MOESM1_ESM.docx (3.8 mb)
ESM 1 (DOCX 3915 kb)

References

  1. Al Dahoudi N, AlKahlout A, Heusing S et al (2013) Indium doped zinc oxide nanopowders for transparent conducting coatings on glass substrates. J Sol-Gel Sci Technol 67:556–564CrossRefGoogle Scholar
  2. Althues H, Henle J, Kaskel S (2007) Functional inorganic nanofillers for transparent polymers. Chem Soc Rev 36:1454–1465CrossRefGoogle Scholar
  3. Becheri A, Durr M, Lo Nostro P et al (2008) Synthesis and characterization of zinc oxide nanoparticles: application to textiles as UV-absorbers. J Nanopart Res 10:679–689CrossRefGoogle Scholar
  4. Beena D, Lethy KJ, Vinodkumar R, Mahadevan Pillai VP, Ganesan V, Phase DM, Sudheer SK (2009) Effect of substrate temperature on structural, optical and electrical properties of pulsed laser ablated nanostructured indium oxide films. Appl Surf Sci 255:8334–8342CrossRefGoogle Scholar
  5. Chava RK, Kang M (2017) Improving the photovoltaic conversion efficiency of ZnO based dye sensitized solar cells by indium doping. J Alloys Compd 692:67–76CrossRefGoogle Scholar
  6. Chen L, Xu J, Holmes JD, Morris MA (2010) A facile route to ZnO nanoparticle superlattices: synthesis, functionalization, and self-assembly. J Phys Chem C 114:2003–2011CrossRefGoogle Scholar
  7. Chen M, Wang Z, Han D, Gu F, Guo G (2011) Porous ZnO polygonal nanoflakes: synthesis, use in high-sensitivity NO2 gas sensor, and proposed mechanism of gas sensing. J Phys Chem C 115:12763–12773CrossRefGoogle Scholar
  8. Chen YF, Kim M, Lian G, Johnson MB, Peng X (2005) Side reactions in controlling the quality, yield, and stability of high quality colloidal nanocrystals. J Am Chem Soc 127:13331–13337CrossRefGoogle Scholar
  9. Dattoli EN, Lu W (2011) ITO nanowires and nanoparticles for transparent films. MRS Bull 36:782–788CrossRefGoogle Scholar
  10. Dou QQ, Ng KM (2016) Synthesis of various metal stearates and the corresponding monodisperse metal oxide nanoparticles. Powder Technol 301:949–958CrossRefGoogle Scholar
  11. Hammarberg E, Prodi-Schwab A, Feldmann C (2009) Microwave-assisted polyol synthesis of aluminium- and indium-doped ZnO nanocrystals. J Colloid Interf Sci 334:29–36CrossRefGoogle Scholar
  12. Hansen CM (2007) Hansen solubility parameters: a user’s handbook, Second Edition. CRC Press Inc., Boca Raton, FloridaGoogle Scholar
  13. Jiang C, Cheng MJ, Liu HT, Shao L, Zeng X, Zhang Y, Shi F (2013) Fabricating transparent multilayers with UV and near-IR double-blocking properties through layer-by-layer assembly. Ind Eng Chem Res 52:13393–13400CrossRefGoogle Scholar
  14. Khrenov V, Klapper M, Koch M, Müllen K (2005) Surface functionalized ZnO particles designed for the use in transparent nanocomposites. Macromol Chem Phys 206:95–101CrossRefGoogle Scholar
  15. Kim GH, Shin HS, Ahn BD, Kim KH, Park WJ, Kim HJ (2009) Formation mechanism of solution-processed nanocrystalline InGaZnO thin film as active channel layer in thin-film transistor. J Electrochem Soc 156:H7–H9CrossRefGoogle Scholar
  16. Kirchberg S, Rudolph M, Ziegmann G et al (2012) Nanocomposites based on technical polymers and sterically functionalized soft magnetic magnetite nanoparticles: synthesis, processing, and characterization. J Nanomater 2012:8CrossRefGoogle Scholar
  17. Lee JH, Park BO (2003) Transparent conducting ZnO: Al, In and Sn thin films deposited by the sol-gel method. Thin Solid Films 426:94–99CrossRefGoogle Scholar
  18. Lee S (2009) Developing UV-protective textiles based on electrospun zinc oxide nanocomposite fibers. Fibers Polym 10:295–301CrossRefGoogle Scholar
  19. Li P, Liang Y-H, Ma P-S, Zhu C (1997) Estimations of enthalpies of vaporization of pure compounds at different temperatures by a corresponding-states group-contribution method. Fluid Phase Equilib 137:63–74CrossRefGoogle Scholar
  20. Li ST, Qiao XL, Chen HG et al (2006) Effects of temperature on indium tin oxide particles synthesized by co-precipitation. J Cryst Growth 289:151–156CrossRefGoogle Scholar
  21. Lizundia E, Ruiz-Rubio L, Vilas JL et al (2016) Poly(L-lactide)/ZnO nanocomposites as efficient UV-shielding coatings for packaging applications. J Appl Polym Sci 133:7CrossRefGoogle Scholar
  22. Luo SJ, Feng JY, Ng KM (2014a) Large scale synthesis of nearly monodisperse, variable-shaped In2O3 nanocrystals via a one-pot pyrolysis reaction. CrystEngComm 16:9236–9244CrossRefGoogle Scholar
  23. Luo SJ, Feng JY, Ng KM (2015) Effect of fatty acid on the formation of ITO nanocrystals via one-pot pyrolysis reaction. CrystEngComm 17:1168–1172CrossRefGoogle Scholar
  24. Luo SJ, Yang DN, Feng JY, Ng KM (2014b) Synthesis and application of non-agglomerated ITO nanocrystals via pyrolysis of indium-tin stearate without using additional organic solvents. J Nanopart Res 16:2561CrossRefGoogle Scholar
  25. Luo SJ, Yang DN, Zhuang JL, Ng KM (2013) Synthesis and characterization of nearly monodisperse deltoidal icositetrahedral In2O3 nanocrystals via one-pot pyrolysis reaction. CrystEngComm 15:8065–8068CrossRefGoogle Scholar
  26. Mahltig B, Bottcher H, Rauch K et al (2005) Optimized UV protecting coatings by combination of organic and inorganic UV absorbers. Thin Solid Films 485:108–114CrossRefGoogle Scholar
  27. Maldonado A, Olvera MDL, Guerra ST et al (2004) Indium-doped zinc oxide thin films deposited by chemical spray starting from zinc acetylacetonate: effect of the alcohol and substrate temperature. Sol Energ Mat Sol Cells 82:75–84CrossRefGoogle Scholar
  28. Morimoto T, Tomonaga H, Mitani A (1999) Ultraviolet ray absorbing coatings on glass for automobiles. Thin Solid Films 351:61–65CrossRefGoogle Scholar
  29. Mozaffari S, Li W, Thompson C et al (2017) Colloidal nanoparticle size control: experimental and kinetic modeling investigation of the ligand-metal binding role in controlling the nucleation and growth kinetics. Nano 9:13772–13785Google Scholar
  30. NanoMarkets L (2014) Smart Windows Markets 2014Google Scholar
  31. Olvera ML, Gómez H, Maldonado A (2007) Doping, vacuum annealing, and thickness effect on the physical properties of zinc oxide films deposited by spray pyrolysis. Sol Energ Mat Sol Cells 91:1449–1453CrossRefGoogle Scholar
  32. Raj AME, Lalithambika KC, Vidhya VS et al (2008) Growth mechanism and optoelectronic properties of nanocrystalline In2O3 films prepared by chemical spray pyrolysis of metal-organic precursor. Physica B 403:544–554CrossRefGoogle Scholar
  33. Rappe AK, Casewit CJ, Colwell KS, Goddard WA, Skiff WM (1992) UFF, a full periodic table force field for molecular mechanics and molecular dynamics simulations. J Am Chem Soc 114:10024–10035CrossRefGoogle Scholar
  34. Rudolph M, Peuker UA (2011) Coagulation and stabilization of sterically functionalized magnetite nanoparticles in an organic solvent with different technical polymers. J Colloid Interf Sci 357:292–299CrossRefGoogle Scholar
  35. Shaheen TI, El-Naggar ME, Abdelgawad AM et al (2016) Durable antibacterial and UV protections of in situ synthesized zinc oxide nanoparticles onto cotton fabrics. Int J Biol Macromol 83:426–432CrossRefGoogle Scholar
  36. Sirvio JA, Visanko M, Heiskanen JP et al (2016) UV-absorbing cellulose nanocrystals as functional reinforcing fillers in polymer nanocomposite films. J Mater Chem A 4:6368–6375CrossRefGoogle Scholar
  37. Sun D, Sue HJ, Miyatake N (2008) Optical properties of ZnO quantum dots in epoxy with controlled dispersion. J Phys Chem C 112:16002–16010CrossRefGoogle Scholar
  38. Sunde TOL, Garskaite E, Otter B, Fossheim HE, Sæterli R, Holmestad R, Einarsrud MA, Grande T (2012) Transparent and conducting ITO thin films by spin coating of an aqueous precursor solution. J Mater Chem 22:15740–15749CrossRefGoogle Scholar
  39. Tao F, Xiaomeng H, Zulan L et al (2016) UV-blocking property of nano-ZnO thin film coating on silk fabric. Appl Mech Mater 835:50–54CrossRefGoogle Scholar
  40. Wang QL, Yang YF, He HP, Chen DD, Ye ZZ, Jin YZ (2010) One-step synthesis of monodisperse in-doped ZnO nanocrystals. Nanoscale Res Lett 5:882–888CrossRefGoogle Scholar
  41. Wienke J, Booij AS (2008) ZnO: in deposition by spray pyrolysis—influence of the growth conditions on the electrical and optical properties. Thin Solid Films 516:4508–4512CrossRefGoogle Scholar
  42. Zayat M, Garcia-Parejo P, Levy D (2007) Preventing UV-light damage of light sensitive materials using a highly protective UV-absorbing coating. Chem Soc Rev 36:1270–1281CrossRefGoogle Scholar
  43. Zhang B, Han J (2016) Preparation and UV-protective property of PVAc/ZnO and PVAc/TiO2 microcapsules/poly(lactic acid) nanocomposites. Fibers Polym 17:1849–1857CrossRefGoogle Scholar
  44. Zhao Y, Kong XR, Zeng XF et al (2009) Preparation of ITO nanoparticles and their composite films with infrared property. J B Univ Chem Technol (Nat Sci Ed) 36:4–7Google Scholar

Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  1. 1.Shenzhen Engineering Laboratory of Phosphorene and Optoelectronics, International Collaborative Laboratory of 2D Materials for Optoelectronic Science and TechnologyShenzhen UniversityShenzhenPeople’s Republic of China
  2. 2.Department of Chemical and Biological EngineeringThe Hong Kong University of Science and TechnologyKowloonHong Kong
  3. 3.The National Engineering Research Center of Novel Equipment for Polymer ProcessingSouth China University of TechnologyGuangzhouPeople’s Republic of China

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