Fe-containing nanoparticles used as effective catalysts of lignin reforming to syngas and hydrogen assisted by microwave irradiation

  • M. V. Tsodikov
  • O. G. Ellert
  • S. A. Nikolaev
  • O. V. Arapova
  • O. V. Bukhtenko
  • Yu. V. Maksimov
  • D. I. Kirdyankin
  • A. Yu. Vasil’kov
Research Paper
  • 109 Downloads

Abstract

Active iron-containing nanosized components have been formed on the lignin surface. The metal was deposited on the lignin from an ethanol solution of Fe(acac)3 and from a colloid solution of iron metal particles obtained beforehand by metal vapor synthesis. These active components are able to absorb microwave radiation and are suitable for microwave-assisted high-rate dehydrogenation and dry reforming of lignin without addition of a carbon adsorbent, as a supplementary radiation absorbing material, to the feedstock. The dependence of the solid lignin heating dynamics on the concentration of supported iron particles was investigated. The threshold Fe concentration equal to 0.5 wt.%, providing the highest rate of sample heating up to the reforming and plasma generation temperature was identified. The microstructure and magnetic properties of iron-containing nanoparticles supported on lignin were studied before and after the reforming. The Fe3O4 nanoparticles and also core-shell Fe3O4@γ-Fe-С nanostructures are formed during the reforming of lignin samples. The catalytic performance of iron-based nanoparticles toward the lignin conversion is manifested as increasing selectivity to hydrogen and syngas, which reaches 94% at the Fe concentration of 2 wt.%. It was found that with microwave irradiation under argon, hydrogen predominates in the gas. In the СО2 atmosphere, dry reforming takes place to give syngas with the СО/Н2 ratio of ~ 0.9. In both cases, the degree of hydrogen recovery from lignin reaches 90–94%.

Graphical abstract

The microwave-supported deposition of iron on the lignin surface gives active well defined nanoparticles Fe3O4 and also core-shell Fe3O4@γ-Fe-С nanostructures. These nanocomponents provide for high-rate microwave-assisted dehydrogenation and dry reforming of lignin.

Keywords

Lignin Syngas Hydrogen Microwave irradiation Nanoparticles of Fe Catalysis 

Notes

Acknowledgments

This investigation was carried out within the State Assignment of Fundamental Research to the A.V. Topchiev Institute of Petrochemical Synthesis of the RAS. The magnetic measurements were carried out within the State Assignment of Fundamental Research to the Kurnakov Institute of General and Inorganic Chemistry using the equipment of the JRC PMR IGIC RAS.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

11051_2018_4185_MOESM1_ESM.pdf (164 kb)
ESM 1 (PDF 163 kb)

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Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  • M. V. Tsodikov
    • 1
  • O. G. Ellert
    • 2
  • S. A. Nikolaev
    • 3
  • O. V. Arapova
    • 1
  • O. V. Bukhtenko
    • 1
  • Yu. V. Maksimov
    • 4
  • D. I. Kirdyankin
    • 2
  • A. Yu. Vasil’kov
    • 5
  1. 1.A.V. Topchiev Institute of Petrochemical Synthesis of the RASMoscowRussia
  2. 2.N.S. Kurnakov Institute of General and Inorganic Chemistry of the RASMoscowRussia
  3. 3.M. V. Lomonosov Moscow State UniversityMoscowRussia
  4. 4.N.N.Semenov Institute of Chemical Physics of the RASMoscowRussia
  5. 5.A. N. Nesmeyanov Institute of Organoelement Compounds of the RASMoscowRussia

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