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S/N dual-doped carbon nanosheets decorated with Co x O y nanoparticles as high-performance anodes for lithium-ion batteries

  • XiaoFei Wang
  • Yong Zhu
  • Sheng Zhu
  • JinChen Fan
  • QunJie Xu
  • YuLin Min
Research Paper

Abstract

In this work, we have successfully synthesized the S/N dual-doped carbon nanosheets which are strongly coupled with Co x O y nanoparticles (SNCC) by calcinating cobalt/dithizone complex precursor following KOH activation. The SNCC as anode shows the wonderful charge capacity of 1200 mAh g−1 after 400th cycles at 1000 mA g−1 for Li-ion storage. The superior electrochemical properties illustrate that the SNCC can be a candidate for high-performance anode material of lithium-ion batteries (LIBs) because of the facile preparation method and excellent performance. Significantly, we also discuss the mechanism for the SNCC from the strong synergistic effect perspective.

Keywords

Carbon nanosheets Composite material Anode Lithium-ion battery Energy storage 

Notes

Funding information

This work was supported by the National Natural Science Foundation of China (NSFC) (Grant nos. 21671133, 21271010, 21604051, 21507081), Sailing Program of Shanghai Science and Technology Commission (15YF1404700), Shanghai Municipal Natural Science Foundation (15ZR1417800), Science and Technology Commission of Shanghai Municipality (14JC1402500), Shanghai Municipal Education Commission (No. 15ZZ088; No. 15SG49), and International Joint Laboratory on Resource Chemistry. Additionally, the study was also sponsored by “Chenguang Program” supported by Shanghai Education Development Foundation and Shanghai Municipal Education Commission (14CG54).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

11051_2018_4163_MOESM1_ESM.docx (481 kb)
ESM 1 (DOCX 481 kb)

References

  1. Cao F, Zhao M, Yu Y, Chen B, Huang Y, Yang J, Cao X, Lu Q, Zhang X, Zhang Z (2016) Synthesis of two-dimensional CoS1.097/nitrogen-doped carbon nanocomposites using metal–organic framework nanosheets as precursors for supercapacitor application. J Am Chem Soc 138(22):6924–6927.  https://doi.org/10.1021/jacs.6b02540 CrossRefGoogle Scholar
  2. Chen YM, Yu L, Lou XWD (2016) Hierarchical tubular structures composed of Co3O4 hollow nanoparticles and carbon nanotubes for lithium storage. Angew Chem Int Ed 55(20):5990–5993.  https://doi.org/10.1002/anie.201600133 CrossRefGoogle Scholar
  3. Chen X, Huang Y, Zhang K (2017a) Cobalt fibers anchored with tin disulfide nanosheets as high-performance anode materials for lithium ion batteries. J Colloid Interface Sci 506:291–299.  https://doi.org/10.1016/j.jcis.2017.07.055 CrossRefGoogle Scholar
  4. Chen X, Huang Y, Zhang K (2017b) Synthesis and high-performance of carbonaceous polypyrrole nanotubes coated with SnS2 nanosheets anode materials for lithium ion batteries. Chem Eng J 330:470–479.  https://doi.org/10.1016/j.cej.2017.07.180 CrossRefGoogle Scholar
  5. Chen X, Huang Y, Zhang K (2018) Porous TiO2 nanobelts coated with mixed transition-metal oxides Sn3O4 nanosheets core-shell composites as high-performance anode materials of lithium ion batteries. Electrochim Acta 259:131–142.  https://doi.org/10.1016/j.electacta.2017.10.180 CrossRefGoogle Scholar
  6. Dou Y, Xu J, Ruan B (2016) Atomic layer-by-layer Co3O4/graphene composite for high performance lithium-ion batteries. Adv Energy Mater 6(8):1501835.  https://doi.org/10.1002/aenm.201501835 CrossRefGoogle Scholar
  7. Du K, Xie H, Hu G, Peng Z, Cao Y, Yu F (2016) Enhancing the thermal and upper voltage performance of Ni-rich cathode material by a homogeneous and facile coating method: spray-drying coating with nano-Al2O3. ACS Appl Mater Interfaces 8:17713–17720.  https://doi.org/10.1021/acsami.6b05629 CrossRefGoogle Scholar
  8. Eom W, Kim A, Park H, Kim H, Han TH (2016) Graphene-mimicking 2D porous Co3O4 nanofoils for lithium battery applications. Adv Funct Mater 26(42):7605–7613.  https://doi.org/10.1002/adfm.201602320 CrossRefGoogle Scholar
  9. Gu X, Chen L, Ju Z (2013) Controlled growth of porous α-Fe2O3 branches on β-MnO2 nanorods for excellent performance in lithium-ion batteries. Adv Funct Mater 23(32):4049–4056.  https://doi.org/10.1002/adfm.201203779 CrossRefGoogle Scholar
  10. Hao W, Ge W, Wen L (2016) Facile fabrication of ethoxy-functional polysiloxane wrapped LiNi0.6Co0.2Mn0.2O2 cathode with improved cycling performance for rechargeable Li-ion battery. ACS Appl Mater Interfaces 8(28):18439–18449.  https://doi.org/10.1021/acsami.6b04644 CrossRefGoogle Scholar
  11. Huang G, Zhang F, Du X, Qin Y, Yin D, Wang L (2015) Metal organic frameworks route to in situ insertion of multiwalled carbon nanotubes in Co3O4 polyhedra as anode materials for lithium-ion batteries. ACS Nano 2:1592–1599.  https://doi.org/10.1021/nn506252u CrossRefGoogle Scholar
  12. Jiang C, Yuan C, Li P (2016) Nitrogen-doped porous graphene with surface decorated MnO2 nanowires as a high-performance anode material for lithium-ion batteries. J Mater Chem A 4(19):7251–7256 http://pubs.rsc.org/-/content/articlelanding/2016/ta/c5ta10711c CrossRefGoogle Scholar
  13. Kaun T, Nelson P, Redey L, Vissers D, Henriksen G (1993) High temperature lithium/sulfide batteries. Electrochim Acta 38(9):1269–1287 https://www.sciencedirect.com/science/article/pii/0013468693800577 CrossRefGoogle Scholar
  14. Li X, Wang H, Robinson JT, Sanchez H, Diankov G, Dai H (2009) Simultaneous nitrogen doping and reduction of graphene oxide. J Am Chem Soc 131(43):15939–15944.  https://doi.org/10.1021/ja907098f CrossRefGoogle Scholar
  15. Li L, Seng KH, Chen Z (2013) Self-assembly of hierarchical star-like Co3O4 micro/nanostructures and their application in lithium ion batteries. Nano 5(5):1922–1928 http://pubs.rsc.org/en/content/articlelanding/2013/nr/c2nr33223j Google Scholar
  16. Li L, Wang L, Zhang X, Xie M, Wu F, Chen R (2015) Structural and electrochemical study of hierarchical LiNi1/3Co1/3Mn1/3O2 cathode material for lithium-ion batteries. ACS Appl Mater Interfaces 7:21939–21947.  https://doi.org/10.1021/acsami.5b06584 CrossRefGoogle Scholar
  17. Li H, Su Y, Sun W, Wang Y (2016) Carbon nanotubes rooted in porous ternary metal sulfide@N/S-doped carbon dodecahedron: bimetal-organic-frameworks derivation and electrochemical application for high-capacity and long-life lithium-ion batteries. Adv Funct Mater 26:8345–8353.  https://doi.org/10.1002/adfm.201601631 CrossRefGoogle Scholar
  18. Maier J (2005) Nanoionics: ion transport and electrochemical storage in confined systems. Nat Mater 4(11):805–815 https://www.nature.com/articles/nmat1513 CrossRefGoogle Scholar
  19. Polat BD, Keles O, Chen ZH (2016) Si–Cu alloy nanowires grown by oblique angle deposition as a stable negative electrode for Li-ion batteries. J Mater Sci 51(13):6207–6219.  https://doi.org/10.1007/s10853-016-9918-3 CrossRefGoogle Scholar
  20. Qiao L, Sun X, Yang Z, Wang X, Wang Q, He D (2013) Network structures of fullerene-like carbon core/nano-crystalline silicon shell nanofibers as anode material for lithium-ion batteries. Carbon 54:29–35 https://www.sciencedirect.com/science/article/pii/S0008622312008792 CrossRefGoogle Scholar
  21. Ren XC, Guo CL, Xu LQ, Li T, Hou LF, Wei YH (2015) Facile synthesis of hierarchical mesoporous honeycomb-like NiO for aqueous asymmetric supercapacitors. ACS Appl Mater Interfaces 7:19930–19940.  https://doi.org/10.1021/acsami.5b04094 CrossRefGoogle Scholar
  22. Sinha NN, Munichandraiah N (2009) Synthesis and characterization of carbon-coated LiNi1/3Co1/3Mn1/3O2 in a single step by an inverse microemulsion route. ACS Appl Mater Interfaces 1:1241–1249.  https://doi.org/10.1021/am900120s CrossRefGoogle Scholar
  23. Song H, Cui H, Wang C (2014) Abnormal cyclibility in Ni@graphene core–shell and yolk–shell nanostructures for lithium ion battery anodes. ACS Appl Mater Interfaces 6(16):13765–13769.  https://doi.org/10.1021/am503016s CrossRefGoogle Scholar
  24. Sun Y, Hu X, Luo W, Huang Y (2012) Ultrathin CoO/graphene hybrid nanosheets: a highly stable anode material for lithium-ion batteries. J Phys Chem C 116(39):20794–20799.  https://doi.org/10.1021/jp3070147 CrossRefGoogle Scholar
  25. Sun X, Wang X, Feng N, Qiao L, Li X, He D (2013a) A new carbonaceous material derived from biomass source peels as an improved anode for lithium ion batteries. J Anal Appl Pyrolysis 100:181–185 https://www.sciencedirect.com/science/article/pii/S0165237012002604 CrossRefGoogle Scholar
  26. Sun H, Xin G, Hu T (2013b) High-rate lithiation-induced reactivation of mesoporous hollow spheres for long-lived lithium-ion batteries. Nat Commun 5:4526–4526 https://www.nature.com/articles/ncomms5526 Google Scholar
  27. Sun X, Hao GP, LuX XL, Liu B, Si W, Ma C, Liu Q, Zhang Q, Kaskel S (2016) High-defect hydrophilic carbon cuboids anchored with Co/CoO nanoparticles as highly efficient and ultra-stable lithium-ion battery anodes. J Mater Chem A 4(26):10166–10173 http://pubs.rsc.org/-/content/articlehtml/2016/ta/c6ta03098j CrossRefGoogle Scholar
  28. Verma P, Maire P, Novak P (2010) A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries. Electrochim Acta 2010(55):6332–6341 https://www.sciencedirect.com/science/article/pii/S0013468610007747 CrossRefGoogle Scholar
  29. Wang X, Zhang J, Kong X, Huang X, Shi B (2016a) Increasing rigidness of carbon coating for improvement of electrochemical performances of Co3O4 in Li-ion batteries. Carbon 104:1–9 https://www.sciencedirect.com/science/article/pii/S0008622316302160 CrossRefGoogle Scholar
  30. Wang Q, Yu B, Li X (2016b) Core–shell Co3O4/ZnCo2O4 coconut-like hollow spheres with extremely high performance as anode materials for lithium-ion batteries. J Mater Chem A 4(2):425–433 http://pubs.rsc.org/-/content/articlelanding/2016/ta/c5ta06872j CrossRefGoogle Scholar
  31. Wang S, Zhu Y, Xu X, Sunarso J, Shao Z (2017) Adsorption-based synthesis of Co3O4/C composite anode for high performance lithium-ion batteries. Energy 125:569–575 https://www.sciencedirect.com/science/article/pii/S0360544217303389 CrossRefGoogle Scholar
  32. Wang X, Tang Y, Shi P, Fan J, Xu Q, Min Y (2018) Self-evaporating from inside to outside to construct cobalt oxide nanoparticles-embedded nitrogen-doped porous carbon nanofibers for high-performance lithium ion batteries. Chem Eng J 334:1642–1649.  https://doi.org/10.1016/j.cej.2017.11.155 CrossRefGoogle Scholar
  33. Wei HH, Zhang Q, Wang Y (2017, 2017) Baby diaper-inspired construction of 3D porous composites for long-term lithium-ion batteries. Adv Funct Mater.  https://doi.org/10.1002/adfm.201704440
  34. Xiong S, Lou XW (2012) Mesoporous Co3O4 and CoO@C topotactically transformed from chrysanthemum-like Co(CO3)0.5(OH)·0.11H2O and their lithium-storage properties. Adv Funct Mater 22(4):861–871.  https://doi.org/10.1002/adfm.201102192 CrossRefGoogle Scholar
  35. Yan C, Chen G, Zhou X, Sun J, Lv C (2016) Template-based engineering of carbon-doped Co3O4 hollow nanofibers as anode materials for lithium-ion batteries. Adv Funct Mater 26(9):1428–1436.  https://doi.org/10.1002/adfm.201504695 CrossRefGoogle Scholar
  36. Yang T, Liu Y, Huang Z (2015) A facile strategy for fabricating hierarchically mesoporous Co3O4 urchins and bundles and their application in Li-ion batteries with high electrochemical performance. RSC Adv 5(31):24486–24493 http://pubs.rsc.org/-/content/articlehtml/2015/ra/c4ra16871b CrossRefGoogle Scholar
  37. Yao X, Xin X, Zhang Y, Wang J, Liu Z, Xu X (2012) Co3O4 nanowires as high capacity anode materials for lithium ion batteries. J Alloys Compd 521:95–100 https://www.sciencedirect.com/science/article/pii/S0925838812000953 CrossRefGoogle Scholar
  38. Zhang Z, Li W, Zou R (2015) Layer-stacked cobalt ferrite (CoFe2O4) mesoporous platelets for high-performance lithium ion battery anodes. J Mater Chem A 3(13):6990–6997 http://pubs.rsc.org/-/content/articlelanding/2015/ta/c5ta00073d CrossRefGoogle Scholar
  39. Zhang L, Yan B, Zhang J (2016a) Design and self-assembly of metal-organic framework-derived porous Co3O4 hierarchical structures for lithium-ion batteries. Ceram Int 42(4):5160–5170 https://www.sciencedirect.com/science/article/pii/S0272884215023299 CrossRefGoogle Scholar
  40. Zhang K, Li P, Ma M (2016b) Core–shelled low-oxidation state oxides@ reduced graphene oxides cubes via pressurized reduction for highly stable lithium ion storage. Adv Funct Mater 26(17):2959–2965.  https://doi.org/10.1002/adfm.201504979 CrossRefGoogle Scholar
  41. Zhang K, Gao X, Zhang Q (2018) Fe3O4 nanoparticles decorated MWCNTs@ C ferrite nanocomposites and their enhanced microwave absorption properties. J Magn Magn Mater 452:55–63.  https://doi.org/10.1016/j.jmmm.2017.12.039
  42. Zhao G, Zhang N (2013) Electrochemical preparation of porous MoO3 film with a high rate performance as anode for lithium ion batteries. J Mater Chem A 1(2):221–224 http://pubs.rsc.org/-/content/articlelanding/2013/ta/c2ta00361a CrossRefGoogle Scholar
  43. Zhao H, Gao Y, Wang J (2016) Egg yolk-derived phosphorus and nitrogen dual doped nano carbon capsules for high-performance lithium ion batteries. Mater Lett 167:93–97 https://www.sciencedirect.com/science/article/pii/S0167577X15311009 CrossRefGoogle Scholar
  44. Zhu S, Li J, Deng X, He C, Liu E, He F, Shi C, Zhao N (2017, 2017) Ultrathin-nanosheet-induced synthesis of 3D transition metal oxides networks for lithium ion battery anodes. Adv Funct Mater.  https://doi.org/10.1002/adfm.201605017

Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  1. 1.Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric PowerShanghai University of Electric PowerShanghaiPeople’s Republic of China

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