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Platinum nanoparticle/self-doping polyaniline composite-based counter electrodes for dye-sensitized solar cells

  • Rong-Ho Lee
  • Chun-Han Chi
  • Yu-Chen Hsu
Research Paper

Abstract

In this study, we developed a series of platinum nanoparticle (PtNP)/self-doping polyaniline (SPANI) composite-based counter electrodes for dye-sensitized solar cells (DSSCs). The SPANIs with nanospherical (S-SPANI) and nanotube (T-SPANI) structures were respectively self-assembled on the indium–tin oxide glass substrate via the in situ oxidation polymerization. The S-SPANI and T-SPANI were prepared by the copolymerization of self-doping monomer o-aminobenzenesulfonic acid and aniline in different molar ratios. The PtNP/SPANI composite-based counter electrodes were further prepared through the reduction of Pt ions on the SPANI layer using reduction agents of formic acid and sodium borohydride (NaBH4). The SPANI can serve as the proposed supports to disperse PtNPs. The particles sizes of formic acid-reduced nano-platinum (F-PtNPs; 5–15 nm) were smaller than those of the NaBH4-reduced nano-platinum (S-PtNPs; 15–25 nm). Moreover, the distribution of F-PtNPs on the surface of SPANIs was more uniform than that of the S-PtNPs on the surface of SPANIs. The effects of SPANI morphology and PtNP size/distribution on the electro-chemical behavior and photovoltaic performance of these PtNPs/SPANI counter electrodes-based DSSCs were studied. The highest short-circuit current density (14.87 mA cm−2), fill factor (64.2 %), and photoenergy conversion efficiency (4.77 %) were obtained for the DSSC based on the F-PtNP/S-SPANI counter electrode.

Keywords

Dye-sensitized solar cell Platinum counter electrode Photovoltaic property 

Notes

Acknowledgments

The authors thank the National Science Council of Taiwan, ROC, for financial support (Grant NSC 101-2221-E-005-012-MY3).

References:

  1. Ameen S, Akhtar MS, Kim YS, Yang OB, Shin HS (2010) Sulfamic acid-doped polyaniline nanofibers thin film-based counter electrode: application in dye-sensitized solar cells. J Phys Chem C 114:4760–4764CrossRefGoogle Scholar
  2. Biancardo M, West K, Krebs FC (2007) Quasi-solid-state dye-sensitized solar cells: Pt and PEDOT:PSS counter electrodes applied to gel electrolyte assemblies. J Photochem Photobiol A Chem 187:395–401CrossRefGoogle Scholar
  3. Bonnemann H, Khelashvili G, Behrens S, Hinsch A, Skupien K, Dinjus E (2007) Role of the platinum nanoclusters in the iodide/triiodide redox system of dye solar cells. J Cluster Sci 18:141–155CrossRefGoogle Scholar
  4. Boyle A, Penneau JF, Genies E, Riekel C (1992) The effect of heating on polyaniline powders studied by real-time synchrotron radiation diffraction, mass spectrometry and thermal analysis. J Polym Sci Part B Polym Phys 30:265–274CrossRefGoogle Scholar
  5. Cao Y, Li S, Xue Z, Guo D (1986) Spectroscopic and electrical characterization of some aniline oligomers and polyaniline. Synth Met 16:305–315CrossRefGoogle Scholar
  6. Cha SI, Koo BK, Seo SH, Lee DY (2010) Pt-free transparent counter electrodes for dye-sensitized solar cells prepared from carbon nanotube micro-balls. J Mater Chem 20:659–662CrossRefGoogle Scholar
  7. Chen HS, Su C, Chen JL, Yang TY, Hsu NM, Li WR (2011) Preparation and characterization of pure rutile TiO2 nanoparticles for photocatalytic study and thin films for dye-sensitized solar cells. J Nanomater 2011:1–8Google Scholar
  8. Fuhrhop JH, Helfrich W (1993) Fluid and solid fibers made of lipid molecular bilayers. Chem Rev 93:1565–1582CrossRefGoogle Scholar
  9. Gratzel M (2001) Photoelectrochemical cells. Nature 414:338–344CrossRefGoogle Scholar
  10. Hsiao YS, Whang WT, Chen CP, Chen YC (2008) High-conductivity poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) film for use in ITO-free polymer solar cells. J Mater Chem 18:5948–5955CrossRefGoogle Scholar
  11. Huang KC, Wang YC, Dong RX, Tsai WC, Tsai KW, Wang CC, Chen VittalR, Lin JJ, Ho KC (2010) A high performance dye-sensitized solar cell with a novel nanocomposite film of PtNP/MWCNT on the counter electrode. J Mater Chem 20:4067–4073CrossRefGoogle Scholar
  12. Huang KC, Huang JH, Wu CH, Liu CY, Chen HW, Chu CW, Lin JT, Lin CL, Ho KC (2011) Nanographite/polyaniline composite films as the counter electrodes for dye-sensitized solarcells. J Mater Chem 21:10384–10389CrossRefGoogle Scholar
  13. Huang KC, Hu CW, Tseng CY, Liu CY, Yeh MH, Wei HY, Wang CC, Vittal R, Chu CW, Ho KC (2012) A counter electrode based on hollow spherical particles of polyaniline for a dye-sensitized solar cell. J Mater Chem 22:14727–14733CrossRefGoogle Scholar
  14. Jiang SP, Liu Z, Tang HL, Pan M (2006) Synthesis and characterization of PDDA-stabilized Pt nanoparticles for direct methanol fuel cells. Electrochim Acta 51:5721–5730CrossRefGoogle Scholar
  15. Lee RH, Huang YW (2009) Enhancing the photovoltaic performances of dye-sensitized solar-cells by modifying the TiO2 electrode-sensitized dye interface. Thin Solid Films 517:5903–5908CrossRefGoogle Scholar
  16. Lee RH, Lai HH, Wang JJ, Jeng RJ, Lin JJ (2008) Self-doping effects on the morphology, electrochemical and conductivity properties of self-assembled polyanilines. Thin Solid Films 517:500–505CrossRefGoogle Scholar
  17. Lee CP, Chen PY, Vittal R, Ho KC (2010) Iodine-free high efficient quasi solid-state dye-sensitized solar cell containing ionic liquid and polyaniline-loaded carbon black. J Mater Chem 20:2356–2361CrossRefGoogle Scholar
  18. Lee RH, Huang YW, Chang JW, Hwang JC, Chen YC, Jeng RJ (2011) Electrochemical impedance characterization and photovoltaic performance of N719 dye-sensitized solar cells using quaternized ammonium iodide containing polyfluorene electrolyte solutions. Polym Adv Technol 22:1650–1657CrossRefGoogle Scholar
  19. Li Q, Wu J, Tang Q, Lan Z, Li P, Lin J, Fan L (2008) Application of microporous polyaniline counter electrode for dye-sensitized solar cells. Electrochem Commun 10:1299–1302CrossRefGoogle Scholar
  20. Li Z, Ye B, Hu X, Ma X, Zhang X, Deng Y (2009) Facile electropolymerized-PANI as counter electrode for low cost dye-sensitized solar cell. Electrochem Commun 11:1768–1771CrossRefGoogle Scholar
  21. Murakami TN, Ito S, Wang Q, Nazeeruddin MK, Bessho T, Cesar I, Liska P, Baker RH, Comte P, Pechy P, Gratzel M (2006) Highly efficient dye-sensitized solar cells based on carbon black counter electrodes. J Electrochem Soc 153:A2255–A2261CrossRefGoogle Scholar
  22. Nazeeruddin MK, Kay A, Rodicio I, Baker RH, Muller E, Liska P, Vlachopoulos N, Gratzel M (1993) Conversion of light to electricity by cis-X2bis(2,2′-bipyridyl-4,4′-dicarboxylate)ruthenium(II) charge-transfer sensitizers (X = C1, Br, I, CN, and SCN) on nanocrystalline TiO2 electrodes. J Am Chem Soc 115:6382–6390CrossRefGoogle Scholar
  23. Nazeeruddin MK, Pechy P, Renouard T, Zakeeruddin SM, Baker RH, Comte P, Liska P, Cevey L, Costa E, Shklocer V, Spiccia L, Beacon GB, Bignozzi CA, Gratzel M (2001) Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2-based solar cells. J Am Chem Soc 123:1613–1624CrossRefGoogle Scholar
  24. Ni JS, Hung CY, Liu KY, Chang YH, Ho KC, Lin KF (2012) TiO2-based solar cells on their adsorption to titanium oxide and photovoltaic properties. J Colloid Interface Sci 386:359–365CrossRefGoogle Scholar
  25. Nyczyk A, Sniechota A, Adamczyk A, Bernasik A, Turek W, Hasik M (2008) Investigations of polyaniline–platinum composites prepared by sodium borohydride reduction. Eur Polym J 44:1594–1602CrossRefGoogle Scholar
  26. Palaniappan S, Narayana B (1994) Temperature effect on conducting polyaniline salts: thermal and spectral studies. J Polym Sci Part A Polym Chem 32:2431–2436CrossRefGoogle Scholar
  27. Papageorgiou N (2004) Counter-electrode function in nanocrystalline photoelectrochemical cell configurations. Coord Chem Rev 248:1421–1446CrossRefGoogle Scholar
  28. Peng S, Liang J, Mhaisalkar SG, Ramarkrishna SJ (2012) In situ synthesis of platinum/polyaniline composite counter electrodes for flexible dye-sensitized solar cells. Mater Chem 22:5308–5311CrossRefGoogle Scholar
  29. Qian J, Liu P, Xiao Y, Jiang Y, Cao Y, Ai X, Yang H (2009) TiO2-coated multilayered SnO2 hollow microspheres for dye-sensitized solar cells. Adv Mater 21:3663–3667CrossRefGoogle Scholar
  30. Qin Q, Tao J, Yang Y (2010) Preparation and characterization of polyaniline film on stainless steel by electrochemical polymerization as a counter electrode of DSSC. Synth Met 160:1167–1172CrossRefGoogle Scholar
  31. Qin Q, Tao J, Yang Y, Dong X (2011) In situ oxidative polymerization of polyaniline counter electrode on ITO conductive glass substrate. Polym Eng Sci 51(4):663–669CrossRefGoogle Scholar
  32. Tai Q, Chen B, Guo F, Xu S, Hu H, Sebo B, Zhao XZ (2011) In situ prepared transparent polyaniline electrode and its application in bifacial dye-sensitized solar cells. ACS Nano 5:3795–3799CrossRefGoogle Scholar
  33. Tang J, Jing X, Wang B, Wang F (1988) Infrared spectra of soluble polyaniline. Synth Met 24:231–238CrossRefGoogle Scholar
  34. Tang Z, Geng D, Lu G (2006) Electrocatalytic oxidation of carbon monoxide on platinum-modified polyaniline film electrodes. Thin Solid Films 497:309–314CrossRefGoogle Scholar
  35. Wang Q, Ito S, Gratzel M, Santiago FF, Sero IM, Bisquert J, Bessho T, Imai H (2006) Characteristics of high efficiency dye-sensitized solar cells. J Phys Chem B 110:25210–25221CrossRefGoogle Scholar
  36. Wang ZS, Koumura N, Cui Y, Miyashita M, Mori S, Hara K (2009) Exploitation of ionic liquid electrolyte for dye-sensitized solar cells by molecular modification of organic-dye sensitizers. Chem Mater 21:2810–2816CrossRefGoogle Scholar
  37. Wang G, Zhuo S, Xing W (2012a) Graphene/polyaniline nanocomposite as counter electrode of dye-sensitized solar cells. Mater Lett 69:27–29CrossRefGoogle Scholar
  38. Wang G, Xing W, Zhuo S (2012b) The production of polyaniline/graphene hybrids for use as a counter electrode in dye-sensitized solar cells. Electrochim Acta 66:151–157CrossRefGoogle Scholar
  39. Yang CH, Huang LR, Chih YK, Lin WC, Liu FJ, Wang TL (2007) Molecular assembled self-doped polyaniline copolymer ultra-thin films. Polymer 48:3237–3247CrossRefGoogle Scholar
  40. Yue J, Epstein AJ, MacDiarmid AG (1990) Sulfonic acid ring-substituted polyaniline, a self-doped conducting polymer. Mol Cryst Liq Cryst 189:255–261Google Scholar
  41. Zhang J, Hreid T, Li X, Guo W, Wang L, Shi X, Su H, Yuan Z (2010) Nanostructured polyaniline counter electrode for dye-sensitised solar cells: fabrication and investigation of its electrochemical formation mechanism. Electrochim Acta 55:3664–3668CrossRefGoogle Scholar
  42. Zhao Y, Zhai J, He J, Chen X, Chen L, Zhang L, Tian Y, Jiang L, Zhu D (2008) High-performance all-solid-state dye-sensitized solar cells utilizing imidazolium-type ionic crystal as charge transfer layer. Chem Mater 20:6022–6028CrossRefGoogle Scholar
  43. Zhou Z, Wang S, Zhou W, Jiang L, Wang G, Sun G, Zhou B, Xin Q (2003) Preparation of highly active Pt/C cathode electrocatalysts for DMFCs by an improved aqueous impregnation method. Phys Chem Chem Phys 5:5485–5488CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2013

Authors and Affiliations

  1. 1.Department of Chemical EngineeringNational Chung Hsing UniversityTaichungTaiwan

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