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Iron carbide nanoparticles growth in room temperature ionic liquids [C n -MIM][BF4] (n = 12, 16)

  • Lenaïc Lartigue
  • Jérôme Long
  • Xavier Dumail
  • Sergey I. Nikitenko
  • Camille Cau
  • Yannick Guari
  • Lorenzo Stievano
  • Moulay T. Sougrati
  • Christian Guérin
  • Claudio Sangregorio
  • Joulia Larionova
Research Paper

Abstract

The thermal decomposition of Fe x (CO) y precursors for the synthesis of nanoparticles of iron carbides and their superstructures with sizes ranging from 2.8 to 15.1 nm is developed using imidazolium-based ionic liquids as solvents, stabilizers, and carbon source. A study of the influence of some synthesis parameters such as the heating temperature, nature, and concentration of the iron carbonyl precursor and chain length of the N-alkyl substituent on the imidazolium ring on the size and organization of the iron carbide nanoparticles is presented. These iron carbides nano-objects were characterized by infra-red spectroscopy, transmission electronic microscopy, powder X-ray diffraction, Mossbauer spectroscopy, and magnetic analyses.

Keywords

Nanoparticle Cementite Iron carbide Ionic Liquids Magnetic properties 

Notes

Acknowledgments

The authors thank Mme Corine Reibel (ICGM, Montpellier, France) for magnetic measurements. This work was supported by the University of Montpellier II, CNRS and French ANR-2010-BLAN-0810 NEQSON project. L. L. thanks the UFI (GF/IR/732/07, n°25) for financial support.

Supplementary material

11051_2013_1490_MOESM1_ESM.doc (128 kb)
Supplementary material 1 (DOC 127 kb)

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Copyright information

© Springer Science+Business Media Dordrecht 2013

Authors and Affiliations

  • Lenaïc Lartigue
    • 1
    • 4
    • 5
  • Jérôme Long
    • 1
  • Xavier Dumail
    • 1
  • Sergey I. Nikitenko
    • 2
  • Camille Cau
    • 2
  • Yannick Guari
    • 1
  • Lorenzo Stievano
    • 3
  • Moulay T. Sougrati
    • 3
  • Christian Guérin
    • 1
  • Claudio Sangregorio
    • 4
    • 5
  • Joulia Larionova
    • 1
  1. 1.Institut Charles Gerhardt Montpellier, UMR5253, Chimie Moléculaire et Organisation du SolideUniversité Montpellier IIMontpellier Cedex5France
  2. 2.Institut de Chimie Séparative de Marcoule, UMR 5257, Centre de MarcouleBagnols sur CèzeFrance
  3. 3.Institut Charles Gerhardt Montpellier, UMR 5253, Agrégats, Interfaces et Matériaux pour l’EnergieUniversité Montpellier IIMontpellier Cedex5France
  4. 4.CNR-ISTMMilanItaly
  5. 5.INSTM Research Unit-Dip. di ChimicaUniv. di FirenzeSesto FiorentinoItaly

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