The effect of functionalization on structure and electrical conductivity of multi-walled carbon nanotubes
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Carbon nanotubes (CNTs) are of interest in many areas of nanotechnology and used in a number of novel applications. However effective dispersion remains a problem and one solution is to functionalize the nanotubes. Any functionalization that is undertaken must preferably not influence other key properties such as strength and electrical conductivity. In this work, multi-walled CNTs are functionalized for comparison, using a range of oxidative techniques, including thermal treatment, acid reflux, and dry UV-ozonolysis. The effects of these treatments on the multi-walled carbon nanotubes (MWCNTs) and their electrical properties were characterized using a range of surface and compositional techniques. The electrical conductivity of MWCNTs was found to increase with functionalization in all cases, and dry UV-ozonolysis was shown to be the treatment technique which best increased conductivity, whilst at the same time maintaining the structural integrity of the nanotubes, even though the level of modification was less than by the other treatment methods.
KeywordsNanotube Ozonolysis Conductivity MWCNT
- Hirsch A, Vostrowsky O (2005) Functionalization of carbon nanotubes. Top Curr Chem 245:193–237Google Scholar
- Piccozi S, Santucci S, Lozzi L, Cantalini C, Baratto C, Sbervegelieri G, Armentano I, Kenny JM, Valentini L, Delley B (2004) Ozone adsorption on carbon nanotubes: ab initio calculations. J Vac Sci Technol A 22:1466–1470Google Scholar
- Sears A, Batra RC (2006) Buckling of multiwalled carbon nanotubes under axial compression. Phys Rev B Condens Matter Mater Phys 73:085410Google Scholar