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Molecular Diversity

, Volume 11, Issue 2, pp 87–91 | Cite as

Synthesis of oxime phosphoranes from reaction between triphenylphosphine and acetylenic esters in the presence of oxime derivatives

  • Malek Taher Maghsoodlou
  • Sayyed Mostafa Habibi-Khorassani
  • Reza Heydari
  • Asadollah Hassankhani
  • Ghasem Marandi
  • Mahmoud Nassiri
  • Elaheh Mosaddeg
Full Length Paper

Abstract

A new one-pot, simple and effective procedure is presented for the preparation of O-containing phosphorus ylides by the Michael addition reaction of N-methylpyrrole-2-carbaldehydoxime, pyridin-2-carbaldehydoxime or acetophenonoxime with acetylenic esters.

Keywords

Stable phosphorus ylides Michael addition N-methylpyrrole-2-carbaldehydoxime Pyridin-2-carbaldehydoxime and acetophenonoxime Rotational isomers 

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Copyright information

© Springer Science+Business Media B.V. 2007

Authors and Affiliations

  • Malek Taher Maghsoodlou
    • 1
  • Sayyed Mostafa Habibi-Khorassani
    • 1
  • Reza Heydari
    • 1
  • Asadollah Hassankhani
    • 1
  • Ghasem Marandi
    • 1
  • Mahmoud Nassiri
    • 1
  • Elaheh Mosaddeg
    • 1
  1. 1.Department of ChemistryUniversity of Sistan and BalouchestanZahedanIran

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