Mechanics of Composite Materials

, Volume 51, Issue 6, pp 761–770 | Cite as

Sorption and diffusion of moisture in polymer composite materials with drop-weight impact damage

  • V. O. Startsev
  • S. V. Panin
  • O. V. Startsev

The effect of drop-weight impact energy on the moisture diffusion coefficient and the limiting moisture saturation of next-generation GFRPs and CFRPs was investigated. The damage induced by a drop-weight impact decreased the compression strength and increased the moisture diffusion coefficient and the limiting moisture saturation of five tested polymer composite materials by 20-70% on the average. For describing the moisture uptake kinetics, the Langmuir model is found to be preferable, because the model with bonded and free water provided a coefficient of determination R 2 ≥ 0.998.


GFRP CFRP drop-weight impact diffusion coefficient limiting moisture saturation bonded water free water 



This study was financially supported by the Ministry of Education and Sciences of the Russian

Federation within the framework of Agreement on granting No. 14.505.21.0002 of 22.08.2014, identifier No. RFMEFI59514X0002, with the use of equipment of TsKP for climatic tests of FSUE VIAM.


  1. 1.
    ASTM Standard D7136, Standard Test Method for Measuring the Damage Resistance of a Fiber-Reinforced Polymer Matrix Composite to a Drop-Weight Impact Event (2005).Google Scholar
  2. 2.
    ASTM Standard D7137, Standard Test Method for Compressive Residual Strength Properties of Damaged Polymer Matrix Composite Plates. ASTM Int., West Conshohocken, PA (2012).Google Scholar
  3. 3.
    K. Berketis and D. Tzetzis, “The compression-after-impact strength of woven and non-crimp fabric reinforced composites subjected to long-term water immersion ageing,” J. Mater. Sci., 45, Iss. 20, 5611-5623 (2010).Google Scholar
  4. 4.
    K. Imielinska and L. Guillaumat, “The effect of water immersion ageing on low-velocity impact behavior of woven aramid-glass fiber/epoxy composites,” Compos. Sci. Technol., 64, Iss. 13-14, 2271-2278 (2004).Google Scholar
  5. 5.
    H. Saito and I. Kimpara, “Damage evolution behavior of CFRP laminates under post-impact fatigue with water absorption environment,” Compos. Sci. Technol., 69, Iss. 6, 847-855 (2009).Google Scholar
  6. 6.
    Y. Aoki, K. Yamada, and T. Ishikawa, “Effect of hygrothermal condition on compression after impact strength of CFRP laminates,” Compos. Sci. Technol., 68, Iss. 6, 1376-1383 (2008).Google Scholar
  7. 7.
    H. Park and C. Kong, “A study on low velocity impact damage evaluation and repair technique of small aircraft composite structure,” Composites: Pt A, 42, Iss. 9, 1179-1188 (2011).Google Scholar
  8. 8.
    K. E. Kutsevich, Adhesive Prepregs and CFRPs Based on Them. PhD thesis, Moscow (2014).Google Scholar
  9. 9.
    V. G. Zheleznyak, Binders for Polymer Composite Materials with Increased Fracture Toughness. PhD thesis, Moscow (2014).Google Scholar
  10. 10.
    R. R. Mukhametov, “Cyanate-ester binders for composite materials,” Euro-Asian Union of Scientists (EUS), No. 8, Pt. 5, 30-31 (2014).Google Scholar
  11. 11.
    N. F. Lukina, L. A. Dementyeva, and K. E. Kutsevich, “Adhesive prepregs based on Porcher fabrics — promising materials for parts and units made of PCM,” Proc. VIAM, No. 6 (2014).Google Scholar
  12. 12.
    A. E. Raskutin, “Structural CFRPs based on new binders of melt type and Porcher fabrics,” Nov. Materialoved. Nauka Tekhn., No. 5, 1-18 (2013).Google Scholar
  13. 13.
    I. I. Sokolov and A. E. Raskutin, “Carbon- and glass-fiber-reinforced plastics of new generation,” Proc. VIAM, No. 4, ( (2013).Google Scholar
  14. 14.
    V. V. Subbotin and M. A. Grinev, “Application experience of FSUE VIAM and Porcher materials in the structures of units and parts of aircraft power plants made of polymer composite materials,” Nov. Materialoved. Nauka Tekhn., No. 5, 1-7 (2013).Google Scholar
  15. 15.
    J. Crank, The mathematics of Diffusion, Clarendonpress, Oxford, UK (1975).Google Scholar
  16. 16.
    A. V. Lykov, Theory of Thermal Conduction [in Russian], Vysshaya Shkola, Moscow (1967).Google Scholar
  17. 17.
    A. N. Aniskevich and Yu. O. Yanson, “Study of moisture absorption by an organoplastic,” Mech. Compos. Mater., 26, No. 4, 455-462 (1990).CrossRefGoogle Scholar
  18. 18.
    A. N. Aniskevich and Yu. V. Ivanov, “Calculation of the moisture concentration field in a multilayered plate,” Mech. Compos. Mater., 30, No. 4, 364-370 (1994).CrossRefGoogle Scholar
  19. 19.
    O. Startsev, A. Krotov, and G. Mashinskaya, “Climatic ageing of organic fiber reinforced plastics: water effect,” Int. J. Polym. Mater., 37, Iss. 3-4, 161-171 (1997).CrossRefGoogle Scholar
  20. 20.
    O. V. Startsev, A. S. Krotov, O. G. Senatorova, L. I. Anihovskaya, V. V. Antipov, and D. V. Grashchenkov, “Sorption and diffusion of moisture in layered metal-polymer composite materials of “SIAL” type,” Materialoved., No. 12, 38-44 (2011).Google Scholar
  21. 21.
    O. V. Startsev, L. I. Anikhovskaya, A. A. Litvinov, and A. S. Krotov, “Increase in the reliability of predicting the properties of polymer composites in hygrothermal aging,” Dokl. Khim., 428, Iss. 1, 228-232 (2009).Google Scholar
  22. 22.
    L. T. Startseva, S. V. Panin, O. V. Startsev, and A. S. Krotov, “Moisture diffusion into fiberglasses after their climatic aging,” Dokl. Akad. Nauk, 456, No. 3, 305-309 (2014).Google Scholar
  23. 23.
    H. G. Carter and K. G. Kibler, “Langmuir-type model for anomalous moisture diffusion in composite resins,” J. Compos. Mater., 12, Iss. 5, 118-131 (1978).CrossRefGoogle Scholar
  24. 24.
    P. Bonniau and A. R. Bunsell, “A comparative study of water absorption theories applied to glass epoxy composites,” J. Compos. Mater., 15, Iss. 5, 272-293 (1981).CrossRefGoogle Scholar
  25. 25.
    T. I. Glaskova, R. M. Guedes, J. J. Morais, and A. N. Aniskevich, “A comparative analysis of moisture transport models as applied to an epoxy binder,” Mech. Compos. Mater., 43, No. 4, 377-388 (2007).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • V. O. Startsev
    • 1
  • S. V. Panin
    • 1
  • O. V. Startsev
    • 1
  1. 1.Akimov Gelendzhik Climatic Testing CenterGelendzhikRussia

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