Skip to main content
Log in

Coulometric device within a unit for state primary standards

  • Published:
Measurement Techniques Aims and scope

The operating principle and composition of the VNIIFTRI coulometric device is based on a three-chamber electrochemical cell of vertical construction that is part of the set of primary state standards for the pH scale and indices of pX ion indices. Metrological characteristics of the device ensure reproducibility of pH in the standard with an error of not more than 0.003 in the range of pH = 1.0–12, and this corresponds to the best world analogs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. I. L. Knunyants (ed.), Large Encyclopaedic Dictionary. Chemistry [in Russian], BSE, Moscow (1998), p. 292.

  2. M. Mariassy, K. W. Pratt, and P. Spitzer, “Major application of electrochemical techniques at national metrology institutes,” Metrologia, 46, 199213 (2009).

    Article  Google Scholar 

  3. CODATA 2006, http://physics.nist.gov/cgi-bin/cuu/Value?f.

  4. B. Taylor,V. Parker, and D. Landenberg, Fundamental Constants and Quantum Electrodynamics [Russian translation], Atomizdat, Moscow (1972).

    Google Scholar 

  5. K. W. Pratt, “Automated, high-precision coulometric titrimetry,” Analytica Chimica Acta, 289, 125 (1964).

    Article  Google Scholar 

  6. M. Breitenbach, Precision Constant Current Coulometry System, http://www.bam.de/en/kompetenzen/pruefeinrichtungen_geraete/index.htm.

  7. M. Máriássy, L. Vyskocil, and A. Mathiasová, “Link to the SI via primary direct methods,” Accred. Qual. Assur., No. 5, 437 (2000).

    Google Scholar 

  8. “Measurement of pH. Definition, standards and procedures (UPAC Recommendations 2002),” Pure Appl. Chem., 74, 2169 (2002).

  9. A. S. Doinikov et al., “Commentary on the introduction of interstate standard GOST 8.134-98 Aqueous Solution pH scale,” Elektrokhimiya, 36, No. 3, 374 (2000).

    Google Scholar 

  10. O. V. Karpov, “VNIIFTRI standard base in the field of physicochemical measurements,” Proc. 3rd Int. Sci.-Pract. Conf. Khimmet-3–2008, Kiev (2008).

  11. O. V. Karpov, V. D. Kutovoi, and V. A. Zvezdina, “State primary standard of pX ion activity indices in aqueous solutions,” ibid.

  12. V. E. Bower and R. S. Davis, “The electrochemical equivalent of pure silver: a value of the Faraday constant,” J. Res. NBS, 85, No. 3, 175 (1980).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. A. Artemenkov.

Additional information

Translated from Izmeritel’naya Tekhnika, No. 4, pp. 13–15, April, 2010.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Artemenkov, M.A., Karpov, O.V., Kutovoi, V.D. et al. Coulometric device within a unit for state primary standards. Meas Tech 53, 368–372 (2010). https://doi.org/10.1007/s11018-010-9512-z

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11018-010-9512-z

Key words

Navigation