, Volume 52, Issue 7–8, pp 477–481 | Cite as

Relationship between the electrochemical behavior of phosphides and amorphous iron alloys that contain chromium and phosphorus

  • M. V. Gerasimov
  • Yu. N. Simirskii

A study is made of the electrochemical behavior of a chromium-and phosphorus-bearing iron alloy and phosphides of iron and chromium. It is established that a high (more than 10 at. %) phosphorus content has a positive effect on the passivability of the alloy and the phosphides. It is conjectured that phosphorus forms a covalent bond with chromium and that compounds of the Cr-P type accumulate on the surface during dissolution, thereby facilitating passivation of the alloy.

Key words

amorphous alloy phosphide passivability chromium phosphorus 


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Copyright information

© Springer Science+Business Media, Inc. 2008

Authors and Affiliations

  1. 1.Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscow GSP-1Russia
  2. 2.Russian Science Center Kurchatov InstituteKurchatovRussia

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