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Improving adhesion performance of polyethylene surfaces by cold plasma treatment

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Abstract

In this paper, the effects of low pressure plasma treatment on surface energy of polyethylene samples and on shear properties of adhesive bonded joints based on these substrates have been investigated. In particular, the optimization of two plasma process parameters, exposure time and power input, was studied performing contact angle evaluation and lap-shear tests. The plasma treatment was also compared with a conventional primer treatment, for which it is a clean and effective alternative. As a measure of the durability of both treatments, the bond shear strength immediately after bonding was compared with that after a storage period in the laboratory environment. The experimental results show that the optimized plasma process may remarkably increase wettability properties of polyethylene surfaces and shear strength of bonded joints, even higher than those treated with primer and that these good properties remain quite unchanged even after some days of storage in a laboratory.

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References

  1. Hayat F (2011) Comparing properties of adhesive bonding, resistance spot welding and adhesive weld bonding of coated and uncoated DP 600 steel. Int J Iron Steel Res 18(9):70–78

    Article  Google Scholar 

  2. Sadowski T, Kneć M, Golewski P (2010) Experimental investigations and numerical modelling of steel adhesive joints reinforced by rivets. Int J Adhes Adhes 30:338–346

    Article  Google Scholar 

  3. Da Silva LFM, Pirondi A, Ochsner A (2011) Hybrid adhesive joints. Springer, Heidelberg

    Book  Google Scholar 

  4. Petrie EM (2000) Handbook of adhesives and sealants. McGraw-Hill, New York

    Google Scholar 

  5. Baldan A (2004) Review adhesively-bonded joints and repairs in metallic alloys, polymers and composite materials: adhesives, adhesion theories and surface pretreatment. J Mater Sci 39:1–49

    Article  ADS  Google Scholar 

  6. Underhill PR, DuQuesnay DL (2009) The dependence of the fatigue life of adhesive joints on surface preparation. Int J Adhes Adhes 26:62–66

    Article  Google Scholar 

  7. ASTM D2093–03 (2003) Standard practice for preparation of surfaces of plastics prior to adhesive bonding

  8. Wegman RF, Van Twisk J (2013) Surface preparation techniques for adhesive bonding. Elsevier, Amsterdam

    Google Scholar 

  9. Iqbal HMS, Bhowmik S, Benedictus R (2010) Surface modification of high performance polymers by atmospheric pressure plasma and failure mechanism of adhesive bonded joints. Int J Adhes Adhes 30:418–424

    Article  Google Scholar 

  10. Encinas N, Abenojar J, Martínez MA (2012) Development of improved polypropylene adhesive bonding by abrasion and atmospheric plasma surface modifications. Int J Adhes Adhes 33:1–6

    Article  Google Scholar 

  11. Schulz U, Munzert P, Kaiser N (2001) Surface modification of PMMA by DC glow discharge and microwave plasma treatment for the improvement of coating adhesion. Surf Coat Technol 142:507–511

    Article  Google Scholar 

  12. Zhenga Z, Rena L, Fenga W, Zhaia Z, Wanga Y (2012) Surface characterization of polyethylene terephthalate films treated by ammonia low-temperature plasma. Appl Surf Sci 258:7207–7212

    ADS  Google Scholar 

  13. Cioffi MOH, Voorwald HJC, Hein LRC, Ambrosio L (2005) Effect of cold plasma treatment on mechanical properties of PET/PMMA composites. Composites A 36:615–623

    Article  Google Scholar 

  14. Baumgärtner KM, Schneider J, Schulz A, Feichtinger J, Walker M (2001) Short-time plasma pre-treatment of polytetrafluoroethylene for improved adhesion. Surf Coat Technol 142:501–506

    Article  Google Scholar 

  15. Abenojar J, Torregrosa-Coque R, Martínez MA, Martín-Martínez JM (2009) Surface modifications of polycarbonate (PC) and acrylonitrile butadiene styrene (ABS) copolymer by treatment with atmospheric plasma. Surf Coat Technol 203:2173–2180

    Article  Google Scholar 

  16. Carrino L, Moroni G, Polini W (2002) Cold plasma treatment of polypropylene surface: a study on wettability and adhesion. J Mater Process Technol 121:373–382

    Article  Google Scholar 

  17. Park J, Won-tae J, Paek K, Kim Y, Choi Y, Kim J, Hwang Y (2003) Pre-treatments of polymers by atmospheric pressure ejected plasma for adhesion improvement. Surf Coat Technol 174:547–552

    Article  Google Scholar 

  18. Ku JH, Jung IH, Rhee KY, Park SJ (2013) Atmospheric pressure plasma treatment of polypropylene to improve the bonding strength of polypropylene/aluminum composites. Composites B 45:1282–1287

    Article  Google Scholar 

  19. Lehocky M, Drnovska H, Lapčíková B, Barros-Timmons AM, Trindade T, Zembala M, Lapčík L Jr (2003) Plasma surface modification of polyethylene. Colloids Surf A 222:125–131

    Article  Google Scholar 

  20. Ting JAS, Rosario LMD, Lacdan MCC, Lee HV Jr, De Vero CJ, Ramos HJ, Tumlos RB (2013) Enhanced adhesion of epoxy-bonded steel surfaces using O2/Ar microwave plasma treatment. Int J Adhes Adhes 40:64–69

    Article  Google Scholar 

  21. Lee CJ, Lee SK, Ko DC, Kim DJ, Kim BM (2009) Evaluation of surface and bonding properties of cold rolled steel sheet pretreated by Ar/O2 atmospheric pressure plasma at room temperature. J Mater Process Technol 209:4769–4775

    Article  Google Scholar 

  22. Sorrentino L, Carrino L (2009) Influence of process parameters of oxygen cold plasma treatment on wettability ageing time of 2024 aluminium alloy. Int J Adhes Adhes 29:136–143

    Article  Google Scholar 

  23. Tang S, Kwon OJ, Lu N, Choi HS (2005) Surface characteristics of AISI 304L stainless steel after an atmospheric pressure plasma treatment. Surf Coat Technol 195:298–306

    Article  Google Scholar 

  24. Choi DM, Park CK, Cho K, Park CE (1997) Adhesion improvement by plasma treatment of polyethylene. Polymer 38:6243–6249

    Article  Google Scholar 

  25. Petasch W, Räuchle E, Walker M, Eisner P (1995) Improvement of the adhesion of low-energy polymers by a short-time plasma treatment. Surf Coat Technol 74:682–688

    Article  Google Scholar 

  26. Fombuena V, Balart J, Boronat T, Sánchez-Nácher L, Garcia-Sanoguera D (2013) Improving mechanical performance of thermoplastic adhesion joints by atmospheric plasma. Mater Des 47:49–56

    Article  Google Scholar 

  27. Tanarro I, Herrero VJ, Carrasco E, Jiménez-Redondo M (2011) Cold plasma chemistry and diagnostics. Vacuum 85:1120–1124

    Article  Google Scholar 

  28. Tendero C, Tixier C, Tristant P, Desmaison J, Leprince P (2006) Atmospheric pressure plasmas: a review. Spectrochim Acta 61:2–30

    ADS  Google Scholar 

  29. Sanchis R, Fenollar O, Garcìa D, Sánchez L, Balart R (2008) Improved adhesion of LDPE films to polyolefin foams for automotive industry using low-pressure plasma. Int J Adhes Adhes 28:445–451

    Article  Google Scholar 

  30. Mühlhan C, Weidner ST, Friedrich J, Nowack H (1999) Improvement of bonding properties of polypropylene by low pressure plasma treatment. Surf Coat Technol 116:783–787

    Article  Google Scholar 

  31. Loctite (2013) Technical data sheet Loctite® 401™

  32. Loctite (2013) Technical data sheet Loctite® 770™

  33. ASTM D3163–01 (2008). Standard test method for determining strength of adhesively bonded rigid plastic lap-shear joints in shear by tension loading

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Acknowledgments

The authors wish to thank Gambetti Kenologia S.r.l, for the plasma reactor supply, and Henkel SpA Italy for the materials and all their support in carrying out this investigation.

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Correspondence to C. Mandolfino.

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Mandolfino, C., Lertora, E., Gambaro, C. et al. Improving adhesion performance of polyethylene surfaces by cold plasma treatment. Meccanica 49, 2299–2306 (2014). https://doi.org/10.1007/s11012-014-9993-y

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  • DOI: https://doi.org/10.1007/s11012-014-9993-y

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