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Cationic Complexes of Monovalent Nickel as Catalysts for Styrene Polymerization

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Abstract

The interaction of the [Ni(PPh3)3]BF4 complex with styrene and the products of styrene conversion in the polymerization reaction were studied by EPR and 13C NMR spectroscopy. The structure of the σ-carbocationic complex of Ni(I) formed by the interaction of styrene with the [Ni(PPh3)3]BF4 cationic phosphine complex of Ni(I) was characterized in detail. It was found that the reaction of styrene polymerization occurred with the participation of the coordination center of the σ-carbocationic complex (coordination catalysis), whereas the reaction of telomerization occurred with the participation of the cationic center of this complex (ionic catalysis). The resulting polymer contained active terminal double bonds; it is a promising macromonomer for the synthesis of grafted copolymers. The discovered capacity of alcohols to undergo nucleophilic addition to a growing polymer chain offers strong possibilities for preparing functional polymers and block copolymers.

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Authors and Affiliations

  1. Irkutsk State University, Irkutsk, 664033, Russia

    V. V. Saraev, P. B. Kraikivskii, A. I. Vil'ms & D. A. Matveev

  2. Institute of Limnology, Siberian Division, Russian Academy of Sciences, Irkutsk, 664033, Russia

    V. V. Annenkov & E. N. Danilovtseva

  3. Favorskii Institute of Chemistry, Siberian Division, Russian Academy of Sciences, Irkutsk, 664033, Russia

    T. G. Ermakova & N. P. Kuznetsova

  4. Vrije Universiteit, Amsterdam, the Netherlands

    K. Lammertsma

Authors
  1. V. V. Saraev
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  2. P. B. Kraikivskii
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  3. V. V. Annenkov
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  4. A. I. Vil'ms
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  5. D. A. Matveev
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  6. E. N. Danilovtseva
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  7. T. G. Ermakova
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  8. N. P. Kuznetsova
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  9. K. Lammertsma
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__________

Translated from Kinetika i Kataliz, Vol. 46, No. 5, 2005, pp. 757–763.

Original Russian Text Copyright © 2005 by Saraev, Kraikivskii, Annenkov, Vil'ms, Matveev, Danilovtseva, Ermakova, Kuznetsova, Lammertsma.

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Saraev, V.V., Kraikivskii, P.B., Annenkov, V.V. et al. Cationic Complexes of Monovalent Nickel as Catalysts for Styrene Polymerization. Kinet Catal 46, 712–718 (2005). https://doi.org/10.1007/s10975-005-0126-4

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  • DOI: https://doi.org/10.1007/s10975-005-0126-4

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