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Kinetics and Catalysis

, Volume 46, Issue 5, pp 684–692 | Cite as

Reforming Catalysts of the PR Family: Scientific Foundations and Technological Advancement

  • A. S. Belyi
Article

Abstract

Results of investigations of the state of active sites in aluminoplatinum reforming catalysts (RCs) are summarized. Laws governing the formation and the role of platinum ionic species in the adsorption and catalytic conversion of hydrocarbons are presented. Strategies for the design of highly efficient catalysts, the development of catalyst manufacturing technologies, and operation in the production of motor fuels and aromatic hydrocarbons are formulated. Data are reported on the full-scale operation of catalyst PR-51/04 (PR-71), a new RC, and full-scale tests of the Biforming process, a new process for motor fuel production by coprocessing C3-C4 hydrocarbon gases and gasoline fractions.

Keywords

Platinum Hydrocarbon Gasoline Aromatic Hydrocarbon Ionic Species 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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REFERENCES

  1. 1.
    McHenry, K.W., Bertolachini, R.V., Brennan, H.M., and Wilson, V.L., Proc. II Int. Cong. on Catalysis, Paris, 1961, vol. 2, p. 2295.Google Scholar
  2. 2.
    Bursian, N.R., Kogan, S.B., and Davidova, Z.A., Kinet. Katal., 1967, vol. 8, no.6, p. 1283.Google Scholar
  3. 3.
    Escard, J., Poutvianne, B., Chenebeux, M.T., and Cosyus, V., Bull. Soc. Chim. Fr., 1976, no. 3/4, p. 349.Google Scholar
  4. 4.
    Belyi, A.S., React. Kinet. Catal. Lett., 1996, vol. 57, no.2, p. 349.CrossRefGoogle Scholar
  5. 5.
    Duplyakin, V.K., Belyi, A.S., Ostrovskii, N.M., Smolikov, M.D., Chalganov, E.M., and Nizovskii, A.I., Dokl. Akad. Nauk SSSR, 1989, vol. 305, no.3, p. 648.Google Scholar
  6. 6.
    Belyi, A.S., Kiryanov, D.I., Smolikov, M.D., Zatolokina, E.V., Udras, I.E., and Duplyakin, V.K., React. Kinet. Catal. Lett., 1994, vol. 53, no.1, p. 183.CrossRefGoogle Scholar
  7. 7.
    Belyi, A.S., Udras, I.E., Smolikov, M.D., and Kiryanov, D.I., 2nd Eur. Cong. on Catalysis, Maastricht, 1995, p. 183.Google Scholar
  8. 8.
    Duplyakin, V.K. and Belyi, A.S., 2nd Eur. Cong. on Catalysis, Maastricht, 1995, p. 714.Google Scholar
  9. 9.
    Smolikov, M.D., Belyi, A.S., Kiryanov, D.I., Borovkov, V.Yu., Zaitsev, A.V., Duplyakin, V.K., and Kazanskii, V.B., React. Kinet. Catal. Lett., 1994, vol. 53, no.1, p. 161.Google Scholar
  10. 10.
    Smolikov, M.D., Zaitsev, A.V., Khabibislamova, N.M., Belyi, A.S., Borovkov, V.Yu., Duplyakin, V.K., and Kazanskii, V.B., React. Kinet. Catal. Lett., 1994, vol. 53, no.1, p. 169.Google Scholar
  11. 11.
    Smolikov, M.D., Zaitsev, A.V., Zatolokina, E.V., Belyi, A.S., Borovkov, V.Yu., Duplyakin, V.K., and Kazanskii, V.B., Kinet. Katal., 1992, vol. 33, no.3, p. 625.Google Scholar
  12. 12.
    Bogomolova, O.B., Ostrovskii, N.M., Smolikov, M.D., Belyi, A.S., and Duplyakin, V.K., React. Kinet. Catal. Lett., 1989, vol. 40, no.1, p. 131.CrossRefGoogle Scholar
  13. 13.
    Ostrovskii, N.M. and Belyi, A.S., Khim. Prom-st., 1999, no. 8, p. 522.Google Scholar
  14. 14.
    Belyi, A.S. and Lugovskoi, A.I., Khim. Prom-st., 1996, no. 3, p. 35.Google Scholar
  15. 15.
    Kuznetsov, B.I., Yurchenko, E.I., Belyi, A.S., Zatolokina, E.V., Smolikov, M.D., and Duplyakin, V.K., React. Kinet. Catal. Lett., 1982, vol. 21, no.3.Google Scholar
  16. 16.
    Kuznetsov, V.I., Belyi, A.S., Yurchenco, E.N., Smolikov, M.D., Protasova, M.T., Zatolokina, E.V., and Duplyakin, V.K., J. Catal., 1986, vol. 99, no.1, p. 159.CrossRefGoogle Scholar
  17. 17.
    Belyi, A.S., Smolikov, M.D., Fenelonov, V.B., Gavrilov, V.Yu., and Duplyakin, V.K., Kinet. Katal., 1986, vol. 26, no.3, p. 703.Google Scholar
  18. 18.
    Belyi, A.S., Smolikov, M.D., Fenelonov, V.B., Gavrilov, V.Yu., and Duplyakin, V.K., Kinet. Katal., 1986, vol. 27, no.6, p. 1414.Google Scholar
  19. 19.
    Belyi, A.S., Vdovina, T.N., Smolikov, M.D., and Duplyakin, V.K., Kinet. Katal., 1988, vol. 29, no.5, p. 1216.Google Scholar
  20. 20.
    Smirnova, I.E., Belyi, A.S., Smolikov, M.D., and Duplyakin, V.K., Kinet. Katal., 1990, vol. 31, no.3, p. 687.Google Scholar
  21. 21.
    Vdovina, T.N., Belyi, A.S., Shkuropat, S.A., Startsev, A.N., and Duplyakin, V.K., Kinet. Katal., 1992, vol. 33, no.1, p. 170.Google Scholar
  22. 22.
    Smolikov, M.D., Belyi, A.S., Kolomytsev, Yu.N., and Duplyakin, V.K., in Tezisy dokladov II Vsesoyuznogo soveshchaniya po problemam dezaktivatsii katalizatorov (Proc. II All-Union Conf. on Catalyst Deactivation), Ufa, 1989, p. 27.Google Scholar
  23. 23.
    Duplyakin, V.K., Doronin, V.P., Tsymbal, T.V., Al't, L.Ya., and Belyi, A.S., Dokl. Akad. Nauk SSSR, 1985, vol. 281, no.1, p. 89.Google Scholar
  24. 24.
    Belyi, A.S., Doctoral (Chem.) Dissertation, Novosibirsk: Inst. of Catalysis, 2002.Google Scholar
  25. 25.
    Belyi, A.S., Smolikov, M.D., Kir'yanov, D.I., Proskura, A.G., Udras, I.E., Duplyakin, V.K., Loginov, S.A., and Vashchenko, P.M., Katal. Prom-sti, 2003, no. 6, p. 3.Google Scholar
  26. 26.
    Belyi, A.S., Kir'yanov, D.I., Udras, I.E., Zatolokina, E.V., Smolikov, M.D., Duplyakin, V.K., Shragina, G.M., Kashcheev, A.N., and Manaev, M.S., Neftepererab. Neftekhim., 2004, no. 4, p. 34.Google Scholar
  27. 27.
    Belyi, A.S., Kir'yanov, D.I., Duplyakin, V.K., Lugovskoi, A.I., Vashchenko, P.M., and Loginov, S.A., Khim. Tekhnol. Topl. Masel, 2000, no. 2, p. 27.Google Scholar
  28. 28.
    Gumen, M.I., Bilyk, N.I., Velichko, V.I., Khashchivskii, I.P., Boichuk, I.A., Belyi, A.S., Smolikov, M.D., Kir'yanov, D.I., Bubnov, Yu.N., and Ul'yankin, M.A., Neftepererab. Neftekhim., 2001, no. 11, p. 54.Google Scholar
  29. 29.
    Belyi, A.S., Katal. Prom-sti, 2003, no. 3.Google Scholar
  30. 30.
    RF Patent 2144056, 2000.Google Scholar
  31. 31.
    RF Patent 2144992, 1999.Google Scholar
  32. 32.
    RF Patent 2160700, 2000.Google Scholar

Copyright information

© MAIK "Nauka/Interperiodica" 2005

Authors and Affiliations

  • A. S. Belyi
    • 1
  1. 1.Institute of Hydrocarbon Processing, Siberian DivisionRussian Academy of SciencesOmskRussia

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