Skip to main content
SpringerLink
Log in

Physicochemical Principles of the Synthesis of Porous Composite Materials through the Hydrothermal Oxidation of Aluminum Powder

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The main versions of the synthesis of a new class of porous cermet materials such as Al2O3/Al, MOx/Al2O3/Al, and M1/MOx/Al2O3/Al and ceramic composites on their basis were analyzed. These ceramic composites were prepared through the stage of the hydrothermal oxidation of aluminum powder and were designed for catalytic and adsorption processes. Equations that express the dependence of the apparent density of the resulting composite on the density of the initial powder mixture, on the concentration of the powdered active component, and on the conversion of aluminum are given. It was found that the formal kinetics of aluminum oxidation with water at 100°C can be described by the Kolmogorov-Erofeev equation. The results were compared with data obtained in an autoclave at higher temperatures and steam pressures. The synthesis parameters that affect the total pore volume and the specific surface area of aluminum oxide obtained from aluminum powder were determined. For the case of the transfer of soluble components from an autoclave to a press mold, the molar coefficients of this process were calculated. The texture peculiarities of composites were analyzed. The texture exhibited a polymodal character with developed micropore, mesopore, and ultramacropore structures, which are responsible for the high permeability of granulated composites. Factors affecting the mechanical properties of metal ceramics were studied. The catalysts and products of composite materials were exemplified.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Andreeva, V.A., Osnovy fiziko-khimii i tekhnologii kompozitov (Composites: Fundamentals of Physical Chemistry and Technology), Moscow: IRZhR, 2001.

    Google Scholar 

  2. Sungkono, I., Kameyama, H., and Koya, T., Appl. Surf. Sci., 1997, vol. 121/122, p. 425.

    Article  CAS  Google Scholar 

  3. Patermarakis, G. and Nicopoulos, N., J. Catal., 1999, vol. 187, p. 311.

    Article  CAS  Google Scholar 

  4. Burgos, N., Paulis, M., Antxustegi, M.M., et al., Appl. Catal., vol. 38, p. 251.

  5. Varghese, O.K., Gong, D., Paulose, M., et al., J. Mater. Res., 2002, vol. 17, no.5, p. 1162.

    CAS  Google Scholar 

  6. Solntsev, K.A., Shustorovich, E.M., Chernyavskii, A.S., et al., Dokl. Akad. Nauk, 2002, vol. 385, no.3, p. 372.

    Google Scholar 

  7. Anan'in, V.N., Belyaev, V.V., Parmon, V.N., et al., Tezisy dokladov XIV Mendeleevskogo s”ezda po obshchei i prikladnoi khimii (Proc. XIV Mendeleev Cong. on General and Applied Chemistry), Minsk: Navuka i Tekhnika, 1993.

    Google Scholar 

  8. Yakerson, V.I., Dykh, Zh.L., Subbotin, A.N., et al., Kinet. Katal., 1995, vol. 356, no.6, p. 918.

    Google Scholar 

  9. Poristye pronitsaemye materialy (Porous Permeable Materials) Belov, S.V., Ed., Moscow: Metallurgiya, 1987, p. 175.

    Google Scholar 

  10. Tikhov, S.F., Fenelonov, V.B., Sadykov, V.A., et al., Kinet. Katal., 2000, vol. 41, no.6, p. 907.

    Google Scholar 

  11. Tikhov, S.F., Potapova, Yu.V., Fenelonov, V.B., et al., Kinet. Katal., 2004, vol. 45, no.4, p. 642.

    Google Scholar 

  12. Rabinovich, V.A. and Khavin, Z.Ya., Kratkii khimicheskii spravochnik (Concise Handbook of Chemistry), Leningrad: Khimiya, 1978.

    Google Scholar 

  13. Spravochnik khimika (Chemist's Handbook), Leningrad: Khimiya, 1968, vol. 2.

  14. Fenelonov, V.B., Kinet. Katal., 1994, vol. 35, no.5, p. 795.

    CAS  Google Scholar 

  15. Fenelonov, V.B., Extended Abstract of Doctoral (Chem.) Dissertation, Novosibirsk: Inst. of Catalysis, 1987.

  16. Peronius, N. and Sweeting, T.J., Powder Technol., 1985, vol. 42, p. 113.

    Google Scholar 

  17. Shkrabina, R.A., Extended Abstract of Doctoral (Chem.) Dissertation, Novosibirsk: Inst. of Catalysis, 1997.

  18. Riekert, L. and Ulrich, R., Chem.-Ing.-Tech., 1984, vol. 56, no.2, p. 149.

    Article  CAS  Google Scholar 

  19. Zhilinskii, V.V. and Lokenbakh, A.K., Latv. PSR Zinat. Akad. Vestis. Kim. Ser., 1988, no. 5, p. 622.

  20. Zhilinskii, V.V., Lokenbakh, A.K., and Lepin, L.K., Latv. PSR Zinat. Akad. Vestis. Kim. Ser., 1986, no. 2, p. 151.

  21. Zhilinskii, V.V., Shcherbakov, V.K., Lokenbakh, A.K., et al., in Sovershenstvovanie protsessov lit'ya i obrabotki alyuminiya i proizvodstva kremniya (Improvement of Aluminum Casting and Machining and Silicon Manufacture Processes), Leningrad: VAMI, 1985, p. 45.

    Google Scholar 

  22. Rat'ko, A.I., Romanenkov, V.E., and Krupen'kina, Zh.V., Dokl. Nats. Akad. Nauk Belarusi, 2003, vol. 47, no.4, p. 55.

    Google Scholar 

  23. Rat'ko, A.I., Romanenkov, V.E., Bolotnikova, E.V., et al., Dokl. Nats. Akad. Nauk Belarusi, 2003, vol. 47, no.5, p. 62.

    Google Scholar 

  24. Erofeev, B.V., Dokl. Akad. Nauk SSSR, 1946, vol. 52, no.6, p. 515.

    Google Scholar 

  25. Panchenkov, G.M. and Lebedev, V.P., Khimicheskaya kinetika i kataliz (Chemical Kinetics and Catalysis), Moscow: Khimiya, 1985.

    Google Scholar 

  26. Vityaz', P.A., Sheleg, V.K., Anan'in, V.N., et al., Dokl. Akad. Nauk BSSR, Ser. Khim., 1986, vol. 30, no.3, p. 240.

    Google Scholar 

  27. Tikhov, S.F., Potapova, Yu.V., Fenelonov, V.B., et al., Kinet. Katal., 2003, vol. 44, no.2, p. 322.

    Google Scholar 

  28. Tikhov, S.F., Zaikovskii, V.I., Fenelonov, V.B., et al., Kinet. Katal., 2000, vol. 41, no.6, p. 916.

    Google Scholar 

  29. Anan'in, V.N., Belyaev, V.V., Romanenkov, V.E., et al., Vestsi Akad. Navuk BSSR, 1988, no. 5, p. 17.

  30. Lur'e, B.A., Chernyshev, A.N., Perova, N.N., et al., Kinet. Katal., 1976, vol. 17, no.6, p. 1453.

    Google Scholar 

  31. Lyashko, A.P., Medvidinskii, A.A., Savel'ev, G.G., et al., Kinet. Katal., 1990, vol. 31, no.4, p. 967.

    CAS  Google Scholar 

  32. Rat'ko, A.I., Romanenkov, V.E., Bolotnikova, E.V., and Krupen'kina, Zh.V., Kinet. Katal., 2004, vol. 45, no.2, p. 299.

    Google Scholar 

  33. Tikhov, S.F., Potapova, Yu.V., Sadykov, V.A., et al., Mater. Res. Innov., 2005 (in press).

  34. Rat'ko, A.I., Romanenkov, V.E., Bolotnikova, E.V., et al., Kinet. Katal., 2004, vol. 44, no.1, p. 169.

    Google Scholar 

  35. Tikhov, S.F., Sadykov, V.A., Potapova, Yu.V., et al., Stud. Surf. Sci. Catal., 1998, vol. 118, p. 797.

    CAS  Google Scholar 

  36. Zaporina, N.A. and Lokenbakh, A.K., Latv. PSR Zinat. Akad. Vestis. Kim. Ser., 1987, no. 6, p. 696.

  37. Rat'ko, A.I., Romanenkov, V.E., Bolotnikova, E.V., et al., Vestsi Nats. Akad. Navuk Belarusi, Ser. Kolloidn. Khim., 2003, no. 3, p. 5.

  38. Ivanova, A.S., Skripchenko, E.V., Moroz, E.M., et al., Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk, 1989, no. 6, p. 116.

  39. Koryabkina, N.A., Ismagilov, Z.R., Shkrabina, R.A, et al., Kinet. Katal., 1991, vol. 32, no.4, p. 1013.

    CAS  Google Scholar 

  40. Koryabkina, N.A., Litvak, G.S., Shkrabina, R.A., et al., Kinet. Katal., 1993, vol. 34, no.5, p. 913.

    CAS  Google Scholar 

  41. Koryabkina, N.A., Shkrabina, R.A., Ushakov, V.A., et al., Kinet. Katal., 1997, vol. 38, no.1, p. 128.

    Google Scholar 

  42. Segalova, E.E., Tulovskaya, Z.D., Brutskus, T.K., et al., Zh. Prikl. Khim., 1964, vol. 37, no.6, p. 1227.

    CAS  Google Scholar 

  43. Pavlova, S., Tikhov, S., Sadykov, V., et al., Stud. Surf. Sci. Catal, 2004, vol. 147, p. 223.

    CAS  Google Scholar 

  44. Tikhov, S.F., Fenelonov, V.B., Zaikovskii, V.I., et al., Microporous Mesoporous Mater., 1999, vol. 33, p. 137.

    CAS  Google Scholar 

  45. Zagrafskaya, R.V., Karnaukhov, A.P., and Fenelonov, V.B., Kinet. Katal., 1979, vol. 20, no.2, p. 465.

    CAS  Google Scholar 

  46. Leonov, A.N., Smorygo, O.L., Romashko, A.N., et al., Kinet. Katal., 1998, vol. 39, no.5, p. 691.

    Google Scholar 

  47. Buyanov, R.A. and Krivoruchko, O.P., Kinet. Katal., 1979, no. 3, p. 765.

  48. Rat'ko, A.I., Romanenkov, V.E., Bolotnikova, E.V., et al., Kinet. Katal., 2004, vol. 44, no.1, p. 162.

    Google Scholar 

  49. Panova, N.B., Probl. Upr. Teor. Inf., 2001, no. 4, p. 74.

  50. Leshko, N.B., Probl. Upr. Teor. Inf., 2001, no. 6, p. 26.

  51. Matus, P.P., Matematicheskoe modelirovanie v biologii i meditsine (Mathematical Modeling in Biology and Medicine), Minsk, 1997.

  52. Kafarov, V.V., Metody kibernetiki v khimii i khimicheskoi tekhnologii (Cybernetic Methods in Chemistry and Chemical Engineering), Moscow: Khimiya, 1985.

    Google Scholar 

  53. Kuznetsova, L.I., Ananin, V.N., Pashis, A.V., and Belyaev, V.V., React. Kinet. Catal. Lett., 1991, vol. 43, no.2, p. 545.

    CAS  Google Scholar 

  54. Tikhov, S.F., Sadykov, V.A., Salanov, A.N., et al., Mater. Res. Soc. Symp. Proc., 1998, vol. 497, p. 121.

    CAS  Google Scholar 

  55. Tikhov, S.F., Sadykov, V.A., Bobrova, I.I., et al., Stud. Surf. Sci. Catal., 2001, vol. 139, p. 105.

    Google Scholar 

  56. Ismagilov, Z.R., Podyacheva, O.Yu., Pushkarev, V.V., et al., Stud. Surf. Sci. Catal., 2000, vol. 130, p. 2759.

    Google Scholar 

  57. Tikhov, S.F., Kurkin, V.I., Sadykov, V.A., et al., Stud. Surf. Sci. Catal., 2004, vol. 147, p. 37342.

    Google Scholar 

  58. Kuznetsova, L.I., Zaikovskii, V.I., Ziborov, A.V., et al., React. Kinet. Catal. Lett., 1991, vol. 43, no.2, p. 553.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    S. F. Tikhov, V. A. Sadykov & V. N. Parmon

  2. Institute for the Advanced Training and Retraining of Personnel in New Areas of the Development of Engineering, Technology, and Economics, Belarussian State Technical University, Minsk, Belarus

    V. E. Romanenkov

  3. Institute of General and Inorganic Chemistry, Belarussian Academy of Sciences, Minsk, 270072, Belarus

    A. I. Rat'ko

Authors
  1. S. F. Tikhov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. E. Romanenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. A. Sadykov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. N. Parmon
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. I. Rat'ko
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Kinetika i Kataliz, Vol. 46, No. 5, 2005, pp. 682–700.

Original Russian Text Copyright © 2005 by Tikhov, Romanenkov, Sadykov, Parmon, Rat'ko.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tikhov, S.F., Romanenkov, V.E., Sadykov, V.A. et al. Physicochemical Principles of the Synthesis of Porous Composite Materials through the Hydrothermal Oxidation of Aluminum Powder. Kinet Catal 46, 641–659 (2005). https://doi.org/10.1007/s10975-005-0120-x

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10975-005-0120-x

Keywords

Search

Navigation