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Kinetics and Catalysis

, Volume 45, Issue 6, pp 809–812 | Cite as

The role of free radicals in the reaction of dimethyldioxirane with adamantane

  • S. A. Grabovskiy
  • A. V. Antipin
  • N. N. Kabal’nova
Peroxides-XI

Abstract

The products and the kinetics of the reaction of dimethyldioxirane with adamantane in CCl4 were studied. It was found that the reaction simultaneously occurred via molecular and radical paths. The contribution of the radical process was 65% at 30.6°C. The activation parameters of the reaction of dimethyldioxirane with adamantane in the presence of an inhibitor were determined: logk = (7.33 ± 0.14)-(58.5 ± 0.8)/Θ, Θ = 2.3RT(kJ/mol) (10.3-69.3 °C).

Keywords

Physical Chemistry Catalysis Free Radical CCl4 Activation Parameter 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2004

Authors and Affiliations

  • S. A. Grabovskiy
    • 1
  • A. V. Antipin
    • 1
  • N. N. Kabal’nova
    • 1
  1. 1.Institute of Organic Chemistry, Ufa Scientific CenterRussian Academy of SciencesBashkortostanRussia

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