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Thermodynamic properties of tetraphenylantimony 1-adamantanecarboxylate

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Abstract

In the present work for the first time, the temperature dependence of the heat capacity \(C_{\text{p}}^{\text{o}}\) = f(T) of tetraphenylantimony (1-adamantanecarboxylate) was determined in the range 5.6–456 K by methods adiabatic vacuum calorimetry and differential scanning calorimetry. The compound fuses in the range 414–446 K without decomposition, and thermodynamic characteristics of fusion were defined and analyzed. Multifractal treatment of low-temperature heat capacity was made as a result topological structure of the compound was established. The complex of standard thermodynamic functions (enthalpy, entropy, the Gibbs energy) was given for crystal and liquid states in the range from T → 0 to 456 K. Also, standard entropy of formation of a substance in the crystalline state at T = 298.15 K was calculated. Comparison of thermodynamic properties was made for the derivatives of antimony studied in the present work and earlier.

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Acknowledgements

This work was financially supported by the Ministry of Education and Science of The Russian Federation (Organization of Scientific Research, No. 4.6138.2017/6.7).

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Authors and Affiliations

  1. Lobachevsky University, Prospekt Gagarina 23/5, Nizhny Novgorod, Russia, 603950

    D. V. Lyakaev, A. V. Markin & N. N. Smirnova

  2. South Ural State University National Research, Prospect Lenin 76, Chelyabinsk, Russia, 454080

    V. V. Sharutin & O. K. Sharutina

Authors
  1. D. V. Lyakaev
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  2. A. V. Markin
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  3. N. N. Smirnova
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  4. V. V. Sharutin
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  5. O. K. Sharutina
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Correspondence to A. V. Markin.

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Lyakaev, D.V., Markin, A.V., Smirnova, N.N. et al. Thermodynamic properties of tetraphenylantimony 1-adamantanecarboxylate. J Therm Anal Calorim 133, 1143–1148 (2018). https://doi.org/10.1007/s10973-017-6803-5

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