Abstract
The combination between piperazine, nitrate anions and nickel/zinc metals provided two new hybrid compounds with the general formula (C4H12N2)2[MII(H2O)6](NO3)6 [MII: Ni (1) and Zn (2)]. Their characterization is performed through FTIR spectroscopy and single-crystal X-ray diffraction which gives, as a result, isotype crystal structures, according to the triclinic system (space group Pī), built from: isolated metallic cations coordinated by six water molecules in a distorted octahedral environment [MII(H2O)6]2+, free nitrate anions and protonated piperazine related together through a hydrogen bond network. These bonds together with other attractive forces, being responsible for the crystal formation, were examined using density-functional theory electron density and the non-covalent interaction plot technique. The thermal behavior of the two materials, studied by thermogravimetric analysis and thermal-dependent X-ray diffraction analysis, starts with the dehydration step proceeding differently according to the used metal. The total decomposition leads to the formation of metal oxides: NiO and ZnO. In order to evaluate their biological activity, the two hybrids have been screened against bacteria and fungi and the findings have been reported and explained.
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Acknowledgements
Special thanks are expressed to Pr. Alberto Otero-de-la-Roza (National Institute for Nanotechnology, National Research Council of Canada) for the contribution in the NCI calculations. AOR thanks the Spanish Malta/Consolider initiative (No. CSD2007-00045) and Dr. Thierry Bataille (Ecole Nationale Supérieure de Chimie de Rennes, France) for the assistance in the TDXD measurements. AOR acknowledges Dr. Thierry Roisnel (Centre de diffractométrie X CDIFX, Institue des sciences chimiques de Rennes (ISCR), université de Rennes 1, France) for supplying single-crystal data collection.
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Hassan, D.B., Rekik, W., Mefteh, F.B. et al. Thermal decomposition and biological activity of two supramolecular hybrid nitrates templated by piperazine. J Therm Anal Calorim 127, 1553–1565 (2017). https://doi.org/10.1007/s10973-016-6056-8
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DOI: https://doi.org/10.1007/s10973-016-6056-8