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Effect of metal additives on the composition and combustion characteristics of primary combustion products of B-based propellants

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Abstract

The application of a metal additive is an effective way to improve the performance of B-based propellants. This study focused on the effect of metal additives on the energy release properties of primary combustion products of B-based propellants (hereafter referred to as primary combustion products) to facilitate an understanding of the stages of the secondary combustion of B-based propellants. Mg–Al alloy (MA), Mg metal, Al metal, and Ti metal were used to prepare the primary combustion product samples. A comparative analysis was also made of samples (with MA) obtained under different gas generator pressures. X-ray diffraction, X-ray photoelectron spectroscopy, and inductively coupled plasma chromatography were used to analyze the sample components. The ignition, combustion, and thermal oxidation properties of the samples were studied with a laser ignition experimental system and a thermobalance, respectively. The primary combustion product samples mainly contained C, B13C2, B4C, B2O3, H3BO3, NH4Cl, BN, B, and their respective metal additives. The degree of primary combustion of the samples increased with the gas generator pressure. The presence of MA effectively increased the combustion intensity of the samples. The average combustion temperature of the samples with added MA reached 1440.36 °C. The ignition delay time of the samples ranged between 61 and 146 ms. The self-sustaining combustion time of the samples ranged between 1174 and 1254 ms. MA and Ti both helped to shorten the ignition delay time and prolong the self-sustaining combustion time. The samples obtained under higher gas generator pressures exhibited inferior combustion characteristics. MA decreased the initial oxidation temperature of C (492.6 °C), and Ti decreased the initial oxidation temperature of B (738.1 °C). Mg could improve the oxidation efficiency of B at high-temperature conditions. Among the four metal additives, MA was the most beneficial to the energy release of the primary combustion products, whereas Al had the weakest effect.

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References

  1. Mao CL, Li BX, Hu SQ, Wang YH. Overview of models of boron particle ignition in hot air. J Propuls Technol. 2001;221:6–9.

    Google Scholar 

  2. Zang L. An investigation on boron used as a component of solid propellant. J Propuls Technol. 1990;4:56–62.

    Google Scholar 

  3. Obuchi K, Tanabe M, Kuwahara T. Ignition characteristics of boron particles in the secondary combustor of ducted rockets, effects of magnalium particle addition. In: 46th AIAA aerospace sciences meeting and exhibit, AIAA Paper; 2008. p. 1–8.

  4. Mellor AM. Particulate matter in the exhaust of a boron-loaded solid propellant. AIAA J. 1971;9:1944–7.

    Article  CAS  Google Scholar 

  5. Schadow K. Boron combustion characteristics in ducted rockets. Combust Sci Technol. 1972;5:107–17.

    Article  CAS  Google Scholar 

  6. King MK. Ignition and combustion of boron particles and clouds. J Spacecr Rockets. 1982;19(4):294–306.

    Article  CAS  Google Scholar 

  7. Chen DM, Luh SP, Liu TK, Wu GK, Perng HC. Combustion study of boron-based fuel-rich solid propellant. Int J Energ Mater Chem Propuls. 1993;2:1–6.

    Google Scholar 

  8. Yeh CL, Kuo KK. Ignition and combustion of boron particles. Prog Energy Combust Sci. 1996;22(6):511–41.

    Article  CAS  Google Scholar 

  9. Spalding MJ. Boron particle ignition and combustion in a shock tube using time-resolved spectroscopy. Ph.D. Thesis, University of Illinois at Urbana-Champaign; 2000.

  10. Liu L, He G, Wang Y. Thermal reaction characteristics of the boron used in the fuel-rich propellant. J Therm Anal Calorim. 2013;114:1057–68.

    Article  CAS  Google Scholar 

  11. Ao W, Wang Y, Li H, Xi J, Liu J, Zhou J. Effect of initial oxide layer on ignition and combustion of boron powder. Propellants Explos Pyrotech. 2014;39:185–91.

    Article  CAS  Google Scholar 

  12. Xi J, Liu J, Wang Y, Hu Y, Zhang Y, Zhou J. Metal oxides as catalysts for boron oxidation. J Propuls Power. 2014;30:47–53.

    Article  CAS  Google Scholar 

  13. Guo Y, Zhang W, Zhou X, Bao T. Magnesium boride sintered as high-energy fuel. J Therm Anal Calorim. 2013;113:787–91.

    Article  CAS  Google Scholar 

  14. Mei X, Yang H, Li X, Li Y, Cheng Y. The effect of 5-amino-1H-tetrazole on the combustion performance and ignition capability of boron/potassium nitrate igniter. J Therm Anal Calorim. 2015;. doi:10.1007/s10973-015-4512-5.

    Google Scholar 

  15. Liu L, He G, Wang Y. Study on the calculation of the combustion products of the boron-based fuel-rich propellant during first combustion stage. Chin J Explos Propellants. 2013;36:46–51.

    Google Scholar 

  16. Hu J, Xia Z, Shen H, Kong L, Huang L. Experimental investigation on powdered fuel ramjet combustion performance. Trans Jpn Soc Aeronaut Space Sci. 2013;56:337–42.

    Article  Google Scholar 

  17. Hu J, Xia Z, Wang D, Huang L. Experimental investigation and numerical simulation of secondary combustor flow in boron-based propellant ducted rocket. Trans Jpn Soc Aeronaut Space Sci. 2013;56:145–52.

    Article  Google Scholar 

  18. Zhou H. The study of ignition and combustion of the primary combustion products of the boron-based fuel-rich propellant. Master Thesis, Zhejiang University; 2012.

  19. King MK, Komar J, Fry RS. Fuel-rich solid propellant boron combustion. Alexandria: Atlantic Research Corp.; 1984.

    Google Scholar 

  20. Yeh CL, Hsieh WH, Felder W. Ignition and combustion of Mg-coated and uncoated boron particles. Int J Energ Mater Chem Propuls. 1994;3:1–6.

    Google Scholar 

  21. Pace KK, Jarymowycz TA, Yang V. Effect of magnesium-coated boron particles on burning characteristics of solid fuels in high-speed crossflows. Int J Energ Mat Chem Propuls. 1993;2:1–6.

    Google Scholar 

  22. Rosenband V, Natan B, Gany A. Ignition of boron particles coated by a thin titanium film. J Propuls Power. 1995;11:1125–31.

    Article  Google Scholar 

  23. Mao G, Wu W, Hu S, Wang Y. Influence of HTPB/MA content on pressure exponent of boron-based fuel-rich propellant. Mech Sci Technol Aerosp Eng. 2008;1:5–8.

  24. Li S, Ji R. Composition analysis of combustion residues of metallized solid propellant. J Propuls Technol. 1996;1:83–8.

    Google Scholar 

  25. Spalding MJ, Krier H, Burton RL. Boron suboxides measured during ignition and combustion of boron in shocked Ar/F/O2 and Ar/N2/O2 mixtures. Combust Flame. 2000;120:200–10.

    Article  CAS  Google Scholar 

  26. Liang D, Wang Z, Liu J, Zhang Y, Ao W, Xi J, Wang Y, Zhou J. Effect of carbon on the ignition and combustion characteristics of amorphous boron particles. Chin J Energ Mater Chem Propuls. 2014;22:386–91.

    CAS  Google Scholar 

  27. Liu L, He G, Wang Y. Effects of fuels on primary combustion of boron based fuel-rich propellant. Chin J Energ Mater Chem Propuls. 2012;4:021.

    Google Scholar 

  28. Yao Y, Watanabe T, Yano T, Iseda T, Sakamoto O, Iwamoto M, Inoue S. An innovative energy-saving in-flight melting technology and its application to glass production. Sci Technol Adv Mater. 2008;9:025013.

    Article  Google Scholar 

  29. Chen H, Sun Y, Fu Y. Direct preparation of anhydrous lanthanide chlorides from lanthanide oxides chlorinated by NH4Cl. Chin Rare Earths. 2008;2:015.

    CAS  Google Scholar 

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Acknowledgements

This work was funded by the National Natural Science Foundation of China (Grant No. 51106135) and the Aerospace Science Technology Foundation of China (Grant No. YF-2014-0106-wx).

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Authors and Affiliations

  1. State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou, 310027, China

    Daolun Liang, Jianzhong Liu, Jianfei Xi & Junhu Zhou

  2. Institute of Aerospace Chemotechnology, Xiangyang, 441003, China

    Jinwu Xiao

  3. Institute of Industrial Technology, Zhejiang University, Hangzhou, 310027, China

    Yang Wang

Authors
  1. Daolun Liang
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  2. Jianzhong Liu
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  3. Jinwu Xiao
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  4. Jianfei Xi
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  5. Yang Wang
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Correspondence to Jianzhong Liu.

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Liang, D., Liu, J., Xiao, J. et al. Effect of metal additives on the composition and combustion characteristics of primary combustion products of B-based propellants. J Therm Anal Calorim 122, 497–508 (2015). https://doi.org/10.1007/s10973-015-4750-6

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  • DOI: https://doi.org/10.1007/s10973-015-4750-6

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