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Preparation, crystal structure and thermal studies of cadmium perchlorate complex with 2,2′-bipyridine

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Abstract

The mixed-ligand mononuclear hexacoordinate cadmium perchlorate complex [Cd(2,2′-bipy)2(H2O)(ClO4)]ClO4 was synthesized and characterized by FT-IR, elemental analysis and X-ray crystal structure determination. Thermal characteristics of the complex were studied by thermogravimetry (TG), differential thermal analysis and differential scanning calorimetry. The complex is stable at normal temperature and undergoes dehydration in between the temperature range 95–200 °C with loss of coordinated water (2.8 %). Thereafter, on increasing temperature, dehydrated complex shows some gradual mass loss followed by fast decomposition at higher temperature (265–380 °C). The kinetic parameters for the decomposition of the complex were investigated by applying model-fitting and isoconversional method on isothermal TG data recorded at five different temperatures. To explore the response of complex to sudden high heat, explosion delay time was recorded at five different temperatures, and kinetics of explosion was investigated using these data.

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Acknowledgements

Thanks to Secretary, Board of Management, Principal and the Head of Department of Chemistry, D.B.S. College, Kanpur, for providing laboratory facilities and University Grants Commission, New Delhi, for financial assistance. Thanks are also due to Sophisticated Test and Instrumentation Centre, Cochin University of Science and Technology for CHN, FT-IR and TG–DSC analysis.

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Authors and Affiliations

  1. Department of Chemistry, D.B.S. College, Kanpur, 208006, India

    Chandra Prakash Singh & Abhishek Singh

  2. Chemistry Department, DDU Gorakhpur University, Gorakhpur, 273009, India

    Nibha & Gurdip Singh

  3. Organisch-Chemisches Institut, Universität Münster, Münster, Germany

    Constantin G. Daniliuc

  4. Department of Chemistry, IIT, Delhi, 110016, India

    Bharat Kumar

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  1. Chandra Prakash Singh
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  2. Abhishek Singh
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Correspondence to Chandra Prakash Singh.

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Singh, C.P., Singh, A., Nibha et al. Preparation, crystal structure and thermal studies of cadmium perchlorate complex with 2,2′-bipyridine. J Therm Anal Calorim 121, 633–640 (2015). https://doi.org/10.1007/s10973-015-4613-1

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