Skip to main content
SpringerLink
Log in

Thermal analysis and structural characterization of copper(II) complexes with salicyladehydes

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The new copper (II) complexes with substituted salicylaldehyde ligands (X-saloH, where X = 3-methoxy and 5-methyl) formulated as [Cu(3-OCH3-salo)2(H2O)] (1) and [Cu(5-CH3-salo)2] (2), respectively, were synthesized and characterized by physicochemical methods and by spectroscopy (IR and UV–Vis). The different geometry around Cu2+ ion for the two complexes was proved by single-crystal X-ray diffraction analysis. Simultaneous TG/DTG–DTA techniques were used to analyze their thermal behavior under inert atmosphere, with particular attention to determine their thermal degradation pathways, which was found to be a multi-step decomposition accompanied by the release of the ligand molecules. The activation energy of the decomposition processes was calculated using the isoconversional Ozawa–Flynn–Wall (OFW) method and the reaction model was determined with the model fitting method.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Crisponi G, Nurchi VM, Fanni D, Gerosa C, Nemolato S, Faa G. Copper-related diseases: from chemistry to molecular pathology. Coord Chem Rev. 2010;254:876–89.

    Article  CAS  Google Scholar 

  2. Prasad RN, Agrawal A. Synthesis and spectroscopic studiesof mixed ligand complexes of cobalt(II) with salicylaldehyde, hydroxyarylketones and beta-diketones. J Indian Chem Soc. 2006;83(1):75–7.

    CAS  Google Scholar 

  3. Hussain ST, Ahmad H, Atta MA, Afzal M, Saleem M. High performance liquidchromatography (HPLC), atomic absorption spectroscopy (AAS) and infrared spectroscopy determination and solvent extraction of uranium, using bis(salicylaldehyde) propylene diamine as complexing agent. J Trace Microprobe Tech. 1998;16(2):139–49.

    CAS  Google Scholar 

  4. Yang Y-M, Lu P-C, Zhu T-T, Liu C-H. Bis(2-formylphenolato-κ2 O, O′)iron(II). Acta Cryst. 2007;E63(6):m1613.

    Google Scholar 

  5. Wang Q, Wang D-Q. Aquabis(o-vanillinato- κ2O, O′)nickel(II). Acta Cryst. 2008;E64:m298.

    Google Scholar 

  6. Pessoa JC, Cavaco I, Correira I, Tomaz I, Duarte T, Matias PM. Oxovanadium(IV) complexes with aromatic aldehydes. J Inorg Biochem. 2000;80(1):35–9.

    Article  CAS  Google Scholar 

  7. Costes JP, Dahan F, Nicodeme FA. Trinuclear gadolinium complex: structure and magnetic properties. Inorg Chem. 2001;40:5285–7.

    Article  CAS  Google Scholar 

  8. Tang J, Hewitt I, Madhu NT, Chastanet G, Wernsdorfer W, Anson CE, Benelli C, Sessoli R, Powell AK. Dysprosium triangles showing single-molecule magnet behavior of thermally excited spin states. Angew Chem Int Ed. 2006;45:1729–33.

    Article  CAS  Google Scholar 

  9. Yu G-M, Zhao L, Zou L-F, Guo Y-N, Xu G-F, Li Y-H, Tang J. A tetranuclear nickel(II) cubane complex with O-Vanillin ligand. J Chem Crystallogr. 2011;41:606–9.

    Article  CAS  Google Scholar 

  10. Tangoulis V, Lalia-Kantouri M, Gdaniec M, Papadopoulos Ch, Miletic V, Czapik A. New type of single chain magnet: pseudo-one-dimensional chain of high-spin Co(II) exhibiting ferromagnetic intrachain interactions. Inorg Chem. 2013;52:6559–69.

    Article  CAS  Google Scholar 

  11. Lalia-Kantouri M, Papadopoulos CD, Hatzidimitriou AG, Skoulika S. Hetero-heptanuclear (Fe–Na) complexes of salicylaldehydes: crystal and molecular structure of [Fe2(3-OCH3-salo)8Na5]. 3OH.8H2O. Struct Chem. 2009;20(2):177–84.

    Article  CAS  Google Scholar 

  12. Li SH, Gao SK, Liu SX, Guo YN. Five metal (II) coordination polymers constructed from two vanillin derivatives: from discrete structure to 3D diamondoid network. Cryst Growth Des. 2010;10:495–503.

    Article  CAS  Google Scholar 

  13. Ozawa T. A new method of analyzing thermogravimetric data. Bull Chem Soc Jpn. 1965;38:1881–6.

    Article  CAS  Google Scholar 

  14. Flynn JH, Wall LA. A quick direct method for the determination of activation energy from thermogravimetric data. J Polym Sci B Polym Lett. 1966;4(5):323–8.

    Article  CAS  Google Scholar 

  15. Zianna A, Psomas G, Hatzidimitriou AA, Coutouli-Argyropoulou E, Lalia-Kantouri M. Zinc complexes of salicylaldehydes: synthesis, characterization and DNA-binding properties. J Inorg Biochem. 2013;127:116–26.

    Article  CAS  Google Scholar 

  16. Zianna A, Vecchio S, Gdaniec M, Czapik A, Hatzidimitriou A, Lalia-Kantouri M. Synthesis, thermal analysis, and spectroscopic and structural characterizations of zinc(II) complexes with salicylaldehydes. J Therm Anal Calorim. 2013;112:455–64.

    Article  CAS  Google Scholar 

  17. Madison WI, Bruker Analytical X-ray Systems, Inc., Apex2, (2006), Version 2 User Manual, M86-E01078.

  18. Palatinus L, Chapuis G. Superflip—a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions. J Appl Crystallogr. 2007;40:786–90.

    Article  CAS  Google Scholar 

  19. Betteridge PW, Carruthers JR, Cooper RI, Prout K, Watkin DJ. Program CRYSTALS, software for guided crystal structure analysis. J Appl Crystallogr. 2003;36:1487.

    Article  CAS  Google Scholar 

  20. De Meulenaer J, Tompa H. The absorption correction in crystal structure analysis. Acta Cryst. 1965;19(6):1014–8.

    Article  Google Scholar 

  21. Watkin DJ, Prout CK, Pearce LG. CAMERON program, chemical crystallographic laboratory. UK.: Oxford University; 1996.

    Google Scholar 

  22. Silverstein RM, Bassler GC, Morvill G. Spectrometric identification of organic compounds. 6th ed. New York: Wiley; 1998.

    Google Scholar 

  23. Nakamoto K. Infrared and Raman spectra of inorganic and coordination compounds. 5th ed. New York: Wiley-Interscience; 1997.

    Google Scholar 

  24. Lever AB. Inorganic electronic spectroscopy, 2nd Ed., Elsevier, 1984.

  25. Addison AW, Rao TN, Reedijk J, van Rijn J, Verchoor GC. Synthesis, structure, and spectroscopic properties of copper(II) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper(II) perchlorate J. Chem Soc Dalton Trans. 1984;7:1349–56.

    Article  Google Scholar 

  26. Opfermann J. Kinetic analysis using multivatiate non-linear regression i. Basic concepts. J Therm Anal Cal. 2000;60:641–58.

    Article  CAS  Google Scholar 

  27. Sestak J. Rationale and fallacy of thermoanalytical kinetic patterns: how we model subject matter. J Therm Anal Calorim. 2012;110:5–16.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Laboratory of Inorganic Chemistry, Aristotle University of Thessaloniki, 54124, Thessaloniki, Greece

    Ariadni Zianna, Antonis Hatzidimitriou & Maria Lalia-Kantouri

  2. Solid State Physics Department, School of Physics, Aristotle University of Thessaloniki, 54124, Thessaloniki, Greece

    Konstantinos Chrissafis

Authors
  1. Ariadni Zianna
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Konstantinos Chrissafis
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Antonis Hatzidimitriou
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Maria Lalia-Kantouri
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Maria Lalia-Kantouri.

Electronic supplementary material

Below is the link to the electronic supplementary material.

10973_2014_4188_MOESM1_ESM.pdf

Detailed crystal data and structure refinement for complexes [Cu(3-OCH3-salo)2(H2O)]. 0.25 H2O (1) and [Cu(5-CH3-salo)2] (2) have been deposited with the Cambridge Crystallographic Data Centre under No CCDC 1014202 (1) and No CCDC 014203 (2). (PDF 133 kb)

10973_2014_4188_MOESM2_ESM.pdf

Copies of this information may be obtained free of charge from the Director, CCDC, 12 Union Road, Cambridge, CB2 IEZ, UK (fax: +44-1223-336033; e-mail: deposit@ccdc.cam.ac.uk or http://www.ccdc.cam.ac.uk). (PDF 99 kb)

(CIF 21 kb)

(CIF 27 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zianna, A., Chrissafis, K., Hatzidimitriou, A. et al. Thermal analysis and structural characterization of copper(II) complexes with salicyladehydes. J Therm Anal Calorim 120, 59–66 (2015). https://doi.org/10.1007/s10973-014-4188-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-014-4188-2

Keywords

Search

Navigation