Journal of Thermal Analysis and Calorimetry

, Volume 118, Issue 1, pp 323–331 | Cite as

Bulk size crystal growth, spectral, optical, luminescence, thermal, mechanical, and dielectric properties of organic single crystal

2-[2-(4-methoxy-phenyl)-vinyl]-1-methylstilbazolium iodide (4MESI)
  • K. Senthil
  • S. Kalainathan
  • A. Ruban Kumar


Single crystal of 2-[2-(4-methoxy-phenyl)-vinyl]-1-methylstilbazolium iodide (4MESI) was grown by the slow evaporation method. Single-crystal X-ray diffraction analysis reveals the formation of the title crystal. The density of the grown crystals was measured, and it was compared with theoretically calculated value. The FTIR and powder XRD of 4MESI were performed at room temperature. The different types of proton present in the crystal structure have been confirmed by NMR spectroscopic study. UV–Vis–NIR spectral studies reveal that 4MESI crystals are good optical transparency in the entire visible region. The photoluminescence spectrum of 4MESI shows violet and blue emission. Thermal stability and behavior of the grown crystal have been investigated by TG and DTG analysis. It shows that the grown crystal has melting point at 243 °C. Mechanical hardness of the grown crystals was estimated by Vickers microhardness tester. The grown crystals were also characterized by chemical etching and dielectric studies, and the results are discussed in detail.


Characterization Single-crystal growth Organic compounds FTIR Dielectric materials 



The authors are thankful to V.Ramkumar, Department of Chemistry, IIT Madras, India for providing single-crystal XRD studies. The authors thank DRDO, Government of India, for financial support and VIT University management, Vellore for their constant support and encouragements.


  1. 1.
    Munn RW, Ironside CN. Principles and applications of nonlinear optical materials. London: Champman and Hall; 1993.CrossRefGoogle Scholar
  2. 2.
    Williams D J. Nonlinear optical properties of organic and polymeric materials. ACS symposium series. 1983: 233.Google Scholar
  3. 3.
    Hann RA, Bloor D. Organicmaterials for nonlinear optics. London: The Royal Society of Chemistry Special Publications; 1989.Google Scholar
  4. 4.
    Li Zhengdong, Baichang Wu, Genbo Su. Nonlinear-optical, optical, and crystallographic properties of methyl p-hydroxybenzoate. J Crystal Growth. 1997;178:539.CrossRefGoogle Scholar
  5. 5.
    Zhang HW, Batra AK, Lal RB. Growth of large MNA: MAP crystals for nonlinear optical applications. J Crystal Growth. 1994;137:141.CrossRefGoogle Scholar
  6. 6.
    Indira J, PrakashKarat P, Sarogini BK. Growth, characterization and nonlinear optical property of chalcone derivative. J Crystal Growth. 2002;242:209.CrossRefGoogle Scholar
  7. 7.
    Frazier CC, Cockerham MP. Second-harmonic generation in aromatic organic compounds. J Opt Soc Am. 1987;B4:1899–903.CrossRefGoogle Scholar
  8. 8.
    De Matos Gomes E, Venkataraman V, Nogueria E, Belsley M, Criado PA, Dianez MJ, Estrada MD, Perez-Garrido S. Synthesis, crystal growth and characterisation of a new nonlinear optical material Ð urea L-malic acid. Synth Metals. 2000;115:225.CrossRefGoogle Scholar
  9. 9.
    Senthil K, Kalainathan S, RubanKumar A, Ramkumar V, Podder J. 2-[(E)-2-(4-Methoxyphenyl)ethenyl]-1-methylpyridinium iodide. Acta Cryst. 2013;E69:o1848.Google Scholar
  10. 10.
    Kaminsky W. From CIF to virtual morphology using the WinXMorph program. J Appl Crystallogr. 2007;40:382.CrossRefGoogle Scholar
  11. 11.
    Ioffe AF. Floatation method of precise density measurement. Phys Status Solidi. 1989;116:426–57.Google Scholar
  12. 12.
    Wang XQ, Xu D, Lu MK, Yuan DR, Huang J, Li SG, Lu GW, Sun HQ, Guo SY, Zhang GH, Duan XL, Liu H, Liu HYWL. Physicochemical behavior of nonlinear optical crystal CdHg (SCN)4. J Crystal Growth. 2003;247:432.CrossRefGoogle Scholar
  13. 13.
    Jerald Vijay R, Melikechi N, Thomas Tina, Gunaseelan R, Antony Arockiaraj M, Sagayaraj P. Growth, structural, optical and thermal properties of potential THz material: N, N-dimethylamino-N′-methylstilbazolium 4-styrenesulphonate. J Crystal Growth. 2012;338:170–6.CrossRefGoogle Scholar
  14. 14.
    Bairava Ganesh R, Kannan V, Sathyalakshmi R, Ramasamy P. The growth of l-Glutamic acid hydrochloride crystals by Sankaranarayanan–Ramasamy (SR) method. Mater Lett. 2007;61:706.CrossRefGoogle Scholar
  15. 15.
    Willard HH, Merritt LL Jr, Dean JA, Settle FA Jr. Instrumental methods of analysis. 6th ed. USA: Wadsworth Publishing Company; 1986.Google Scholar
  16. 16.
    Skoog DA. Principles of instrumental analysis. 1st ed. New York: Holt, Rinehart and Winston; 1971.Google Scholar
  17. 17.
    Sherwood JN. The growth, perfection and structural properties of organic electro-optic materials. Pure Appl Opt. 1998;7:229.CrossRefGoogle Scholar
  18. 18.
    Onitsch EM. The present status of testing the hardness of the materials. Microscope. 1950;95:12.Google Scholar
  19. 19.
    Karan S. Gupta SPS, Vickers microhardness studies on solution-grown single crystals of magnesium sulphate hepta-hydrate. Mater Sci Eng A. 2005;398:198–203.CrossRefGoogle Scholar
  20. 20.
    Bhat HL. X-ray topographic assessment of dislocations in crystals grown from solution. Prog. Crystal Growth Charact. 1985;11:57.CrossRefGoogle Scholar
  21. 21.
    Mukerji S, Kar T. Etch pit study of different crystallographic faces of l-arginine hydrobromide monohydrate (LAHBr) in some organic acids. J Crystal Growth. 1999;204:341.CrossRefGoogle Scholar
  22. 22.
    Saucedo E, Fornaro L, Corregidor V, Die guez E. Some structural aspects of PbxCd1−xTe bulk material. Eur Phys J Appl Phys. 2004;27:427–30.CrossRefGoogle Scholar
  23. 23.
    Balarew C, Duhlew R. Application of the hard and soft acids and bases concept to explain ligand coordination in double salt structures. J Solid State Chem. 1984;55:1–6.CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2014

Authors and Affiliations

  1. 1.Centre for Crystal Growth, School of Advanced SciencesVIT UniversityVelloreIndia

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