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Journal of Thermal Analysis and Calorimetry

, Volume 117, Issue 2, pp 783–787 | Cite as

Applicability of Kissinger model in nonisothermal crystallization assessed using a computer simulation method

  • Zhiying Zhang
  • Jia Chen
  • Haijing Liu
  • Changfa Xiao
Article

Abstract

The Kissinger method is one of the most popular approaches for determining kinetic parameters from the nonisothermal processes. The applicability of the Kissinger model in describing the nonisothermal crystallization was verified using the data of the simulated experiments with the given crystallization mechanism. The results show that the data of the Monte Carlo experiments for nonisothermal crystallization can be used to evaluate the nonisothermal crystallization model. The Kissinger model can be used to estimate the parameter of the activation energy of the nonisothermal crystallization from the DSC curves with the different heating rates, but unsuitable to obtain the parameter from the DSC curves with the different cooling rates.

Keywords

Kissinger model Nonisothermal crystallization Poly(ethylene terephthalate) Monte Carlo method 

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2014

Authors and Affiliations

  • Zhiying Zhang
    • 1
  • Jia Chen
    • 1
  • Haijing Liu
    • 1
  • Changfa Xiao
    • 1
  1. 1.School of Materials Science and EngineeringTianjin Polytechnic UniversityTianjinChina

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