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Journal of Thermal Analysis and Calorimetry

, Volume 116, Issue 3, pp 1111–1116 | Cite as

Thermal instabilities of organic carbonates with discharged cathode materials in lithium-ion batteries

  • Wei-Jie Ou
  • Chen-Shan Kao
  • Yih-Shing Duh
  • Jing-Ming Hsu
Article

Abstract

Thermal instability of lithiated cathode materials with organic carbonate were investigated using DSC. Lithium transition metal oxides of LiFePO4, LiMn2O4, and LiCoO2 were mixed with diethyl carbonate, dimethyl carbonate, ethylene carbonate, ethyl methyl carbonate, and propylene carbonate then dynamically screened to about 500 °C. Curves were acquired and analyzed to determine exothermic onset temperatures and reaction enthalpies. These data for assessing the thermal hazards of lithium-ion batteries under discharged conditions were compared to those data published in the literature.

Keywords

Lithium-ion battery Thermal hazard Cathode material Transition metal oxides 

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2014

Authors and Affiliations

  • Wei-Jie Ou
    • 1
  • Chen-Shan Kao
    • 2
    • 4
  • Yih-Shing Duh
    • 3
    • 4
  • Jing-Ming Hsu
    • 1
    • 4
  1. 1.Department of Occupational Safety & HealthChia Nan University of Pharmacy & ScienceTainanTaiwan
  2. 2.Department of Safety, Health and Environmental EngineeringNational United UniversityMiaoliTaiwan
  3. 3.Department of Occupational Safety and Health, Jen-Teh Junior College of MedicineNursing and ManagementMiaoliTaiwan
  4. 4.Disaster Investigation and Research Center (DIRC)Chia Nan University of Pharmacy & ScienceTainanTaiwan

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