Journal of Thermal Analysis and Calorimetry

, Volume 116, Issue 3, pp 1111–1116 | Cite as

Thermal instabilities of organic carbonates with discharged cathode materials in lithium-ion batteries

  • Wei-Jie Ou
  • Chen-Shan Kao
  • Yih-Shing Duh
  • Jing-Ming Hsu


Thermal instability of lithiated cathode materials with organic carbonate were investigated using DSC. Lithium transition metal oxides of LiFePO4, LiMn2O4, and LiCoO2 were mixed with diethyl carbonate, dimethyl carbonate, ethylene carbonate, ethyl methyl carbonate, and propylene carbonate then dynamically screened to about 500 °C. Curves were acquired and analyzed to determine exothermic onset temperatures and reaction enthalpies. These data for assessing the thermal hazards of lithium-ion batteries under discharged conditions were compared to those data published in the literature.


Lithium-ion battery Thermal hazard Cathode material Transition metal oxides 


  1. 1.
    Spotnitz R, Franklin J. Abuse behavior of high-power, lithium-ion cells. J Power Sources. 2003;113:81–100.CrossRefGoogle Scholar
  2. 2.
    Koksbang R, Barker J, Shi H, Said MY. Cathode materials for lithium rocking chair batteries. Solid State Ion. 1996;84:1–21.CrossRefGoogle Scholar
  3. 3.
    Xu K. Nonaqueous liquid electrolytes for lithium-based rechargeable batteries. Chem Rev. 2004;104:4303–17.CrossRefGoogle Scholar
  4. 4.
    Lisbona D, Snee T. A review of hazards associated with primary lithium and lithium-ion batteries. Process Saf Environ Prot. 2011;89:434–44.CrossRefGoogle Scholar
  5. 5.
    Wang Q, Ping P, Zhao X, Chu G, Sun J, Chen C. Thermal runaway caused fire and explosion of lithium ion battery. J Power Sources. 2012;208:210–24.CrossRefGoogle Scholar
  6. 6.
    MacNeil DD, Lu Z, Chen Z, Dahn JR. A comparison of the electrode/electrolyte reaction at elevated temperatures for various Li-ion battery cathodes. J Power Sources. 2002;108:8–14.CrossRefGoogle Scholar
  7. 7.
    Venkatachalapathy R, Lee CW, Lu W, Prakash J. Thermal investigations of transitional metal oxide cathodes in Li-ion cells. Electrochem Commun. 2000;2:104–7.CrossRefGoogle Scholar
  8. 8.
    Yamaki J, Baba Y, Katayama N, Takatsuji H, Egashira M, Osada S. Thermal stability of electrolytes with LixCoO2 cathode or lithiated carbon anode. J Power Sources. 2003;119–121:789–93.CrossRefGoogle Scholar
  9. 9.
    Xia Y, Fujieda T, Tatsumi K, Prosini PP, Sakai T. Thermal and electrochemical stability of cathode materials in solid polymer electrolyte. J Power Sources. 2001;92:234–43.CrossRefGoogle Scholar
  10. 10.
    Zhang Z, Fouchard D, Rea JR. Differential scanning calorimetry material studies: implications for the safety of lithium-ion cells. J Power Sources. 1998;70:16–20.CrossRefGoogle Scholar
  11. 11.
    Jiang J, Dahn JR. ARC studies of the thermal stability of three different cathode materials: LiCoO2; Li[Ni0.1Co0.8Mn0.1]O2; and LiFePO4, in LiPF6 and LiBoB EC/DEC electrolytes. Electrochem Commun. 2004;6:39–43.CrossRefGoogle Scholar
  12. 12.
    Wang Y, Jiang J, Dahn JR. The reactivity of delithiated Li(Ni1/3Co1/3Mn1/3)O2, Li(Ni0.8Co0.15Al0.05)O2 or LiCoO2 with non-aqueous electrolyte. Electrochem Commun. 2007;9:2534–40.CrossRefGoogle Scholar
  13. 13.
    MacNeil DD, Dahn JR. The reaction of charged cathodes with nonaqueous solvents and electrolytes. J Electrochem Soc. 2001;148:A1205–10.CrossRefGoogle Scholar
  14. 14.
    Watanabe I, Yamaki J. Thermalgravimetry–mass spectrometry studies on the thermal stability of graphite anodes with electrolyte in lithium-ion battery. J Power Sources. 2006;153:402–4.CrossRefGoogle Scholar
  15. 15.
    Kong W, Li H, Huang X, Chen L. Gas evolution behaviors for several cathode materials in lithium-ion batteries. J Power Sources. 2005;142:285–91.CrossRefGoogle Scholar
  16. 16.
    Choi N, Profatilova IA, Kim S, Song E. Thermal reactions of lithiated graphite anode in LiPF6-based electrolyte. Thermochim Acta. 2008;480:10–4.CrossRefGoogle Scholar
  17. 17.
    STARe thermal analysis system, operation instructions to the DSC822e module. San Francisco: Mettler Company; 2004.Google Scholar
  18. 18.
    ASTM E537-86, Standard test method for assessing the stability of chemicals by methods of differential thermal analysis.Google Scholar
  19. 19.
    Chen G, Richardson TJ. Thermal instability of Olivine-type LiMnPO4 cathodes. J Power Sour. 2010;195:1221–4.CrossRefGoogle Scholar
  20. 20.
    Hsieh TY, Duh YS, Kao CS. Evaluation of thermal hazard for commercial 14500 lithium-ion batteries. J Therm Anal Calorim. (accepted) 2014.Google Scholar
  21. 21.
    Dubaniewicz TH, DuCarme JP. Industry application society annual meeting, IEEE, 7–11 Oct, Las Vegas; 2012.Google Scholar
  22. 22.
    Wen CY, Jhu CY, Wang YW, Ching CC, Shu CM. J Therm Anal Calorim. 2012;109:1297–302.CrossRefGoogle Scholar
  23. 23.
    Jhu CY, Wang YW, Wen CY, Chiang CC, Shu CM. J Therm Anal Calorim. 2011;106:159–63.CrossRefGoogle Scholar
  24. 24.
    Wang L, Maxisch T, Ceder G. A first-principles approach to studying the thermal stability of oxide cathode materials. Chem Mater. 2007;19:543–52.CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2014

Authors and Affiliations

  • Wei-Jie Ou
    • 1
  • Chen-Shan Kao
    • 2
    • 4
  • Yih-Shing Duh
    • 3
    • 4
  • Jing-Ming Hsu
    • 1
    • 4
  1. 1.Department of Occupational Safety & HealthChia Nan University of Pharmacy & ScienceTainanTaiwan
  2. 2.Department of Safety, Health and Environmental EngineeringNational United UniversityMiaoliTaiwan
  3. 3.Department of Occupational Safety and Health, Jen-Teh Junior College of MedicineNursing and ManagementMiaoliTaiwan
  4. 4.Disaster Investigation and Research Center (DIRC)Chia Nan University of Pharmacy & ScienceTainanTaiwan

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