Phase diagram study of CaBr2–CaHBr system
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A study of binary, CaBr2–CaHBr system was carried out by differential thermal analysis (DTA), covering the composition range from 100 % CaBr2 to 100 % CaHBr between room temperature and 800 °C. From DTA results, the contour of solidus and liquidus temperatures with composition is plotted and the phase diagram of CaBr2–CaHBr system is constructed. The system shows an eutectic reaction at 576 °C and the eutectic composition is 79.6 mol% CaBr2. Co-existing phases in different phase fields are characterized by X-ray diffraction analysis.
KeywordsCaHBr CaBr2 Phase diagram DTA Alkaline earth halide–hydride Peritectic
- 1.Gnanasekaran T, Mahendran KH, Sridharan R, Ganesan V, Periaswami G, Mathews CK. An electrochemical hydrogen monitor for measuring dissolved hydrogen in liquid sodium. Nucl Technol. 1990;90:408–16.Google Scholar
- 3.Smith CA. Berkeley Nuclear Laboratories, Central Electricity Generating Board, U.K., Report. 1972; R/D/BN-2331.Google Scholar
- 8.MMW Chase, Jr. CA davies, JR Downey, Jr., DR Frurip, RA McDonald and AN Syverud (eds), JANAF thermochemical tables, third edition part 1, Al–Co, J Phys Chem Ref Data. 1985;14(1).Google Scholar