Molar heat capacity and thermodynamic properties of crystalline Eu(C2H5O2N)2Cl3·3H2O
- 114 Downloads
A complex of europium hydrochloric acid coordinated with 2-aminoacetic acid (C2H5O2N), Eu(C2H5O2N)2Cl3·3H2O was synthesized and characterized by IR and elements analysis. The heat capacities of the complex was measured with an automatic adiabatic calorimeter, and the thermodynamic functions [H T − H 298.15] and [S T − S 298.15] were derived in the temperature range from 80 to 340 K with temperature interval of 5 K. Thermal decomposition behavior of the complex in nitrogen atmosphere was studied by thermogravimetric (TG) analysis and differential scan calorimeter (DSC).
KeywordsEu(C2H5O2N)2Cl3·3H2O Adiabatic calorimetry Low-temperature heat capacity Thermal analysis
This work was financially supported by the National Nature Science Foundation of China under the grant NSFC No 21103078, 21003069, 21073189.
- 1.Anghileri LJ. On the antitumor activity of gallium and lanthanides. Arzneim Forsch. 1975;25:793–5.Google Scholar
- 13.Jin TZ, Sun XD, Xu GX, Ma ZS, Shi NC. Research on rare earth complexes with amino acid III. J Chin Rare Earths Soc. 1990;8:193–6.Google Scholar
- 18.Moeller T. Inorganic chemistry, a morder introduction. New York: Wiley; 1982.Google Scholar