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Journal of Thermal Analysis and Calorimetry

, Volume 110, Issue 1, pp 349–356 | Cite as

Thermal behaviour of some ester derivatives of p-tert-butyl calix[n]arene

  • A. Saponar
  • E.-J. Popovici
  • I. Perhaita
  • G. Nemes
  • A.-I. Cadis
Article

Abstract

The thermal behaviour of three ester derivatives of p-tert-butyl calix[n]arene (n = 4, 6 and 8) in comparison with the parent calixarene was investigated by means of the thermogravimetric (TG) and differential thermogravimetic (DTG) analysis and differential scanning calorimetry (DSC). The thermal stability domains, the composition of the pyrolysis products and the thermal effects, were determined on the basis of TG, DTG and DSC plots registered in nitrogen flow. Attempts to analyse the evolved gases by TG-FTIR coupling were also performed. It was demonstrated that the stability of the calix[n]arene derivatives depends on both the size of the hydrophobic cavity and number of the substituting groups grafted on the calix[n]arene skeleton.

Keywords

p-tert-butyl calix[n]arene Calix[n]arene ester derivatives Thermal analysis Evolved gas analysis 

Notes

Acknowledgements

This work was possible with the financial support of the Sectorial Operational Programme for Human Resources Development 2007–2013, co-financed by the European Social Fund, under the Project No: POSDRU 89/1.5/S/60189 with the title “Postdoctoral programs for sustainable development in a knowledge based society”.

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2012

Authors and Affiliations

  • A. Saponar
    • 1
  • E.-J. Popovici
    • 1
  • I. Perhaita
    • 1
  • G. Nemes
    • 2
  • A.-I. Cadis
    • 1
  1. 1.Raluca Ripan Institute for Research in ChemistryBabes Bolyai UniversityCluj-NapocaRomania
  2. 2.Faculty of Chemistry and Chemical EngineeringBabes-Bolyai UniversityCluj-NapocaRomania

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