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Journal of Thermal Analysis and Calorimetry

, Volume 108, Issue 3, pp 911–914 | Cite as

Investigation on the growth and characterization of nonlinear optical single crystal of bis thiourea iron(II) sulphate

  • G. Madhurambal
  • B. Ravindran
  • M. Mariappan
  • S. C. Mojumdar
Article

Abstract

Single crystal of bisthiourea iron(II) sulphate was grown by slow evaporation technique at 303 K. The structural properties of the grown crystals were characterized by FTIR spectroscopy, UV spectroscopy and powder X-ray diffraction. FTIR and UV spectra provide information about the presence of functional groups. Thermal analysis confirms the crystal is thermally stable up to 167.02 °C.

Keywords

Bisthiourea iron(II) sulphate Slow evaporation UV FTIR Thermal analysis 

References

  1. 1.
    Sweta M, Tanusree K. Growth and characterization of nonlinear optical crystal zinc tris (thiourea) sulphate in presence of l-arginine. Opt Mater. 2007;30:508–12.CrossRefGoogle Scholar
  2. 2.
    Ezhilvizhi R, Kalainathan S, Bagavannarayana G. Structural and microhardness studies of purea and thiourea doped glycine phosphate single crystal. Cryst Res Technol. 2008;43:778–82.CrossRefGoogle Scholar
  3. 3.
    Meera K, Muralidharan R, Tripathi AK, Dhanasekaran R. Growth of thiourea-doped TGS crystals and their characterization. J Cryst Growth. 2004;260:414–21.CrossRefGoogle Scholar
  4. 4.
    Selvakumar S, Ravikumar M, Rajarajan K. Growth and characterization of a novel organometallic nonlinear optical crystal: bis (thiourea) cadmium formate. J Cryst Growth Design. 2006;11:2607–10.CrossRefGoogle Scholar
  5. 5.
    Jayalakshmi D, Kumar J. Growth and characterization of bis thiourea zinc acetate. Cryst Res Technol. 2006;41:37–40.CrossRefGoogle Scholar
  6. 6.
    Sunil V, Sing MK, Wadhavan VK. Growth morphology of zinc tris (thiourea) sulphate crystals. Pramana. 2000;54:879–88.CrossRefGoogle Scholar
  7. 7.
    Ambujam K, Thomas PC, Aruna S. Growth and characterization of dichloro tetrakis thiourea nickel single crystals. Cryst Res Technol. 2006;41:1082–8.CrossRefGoogle Scholar
  8. 8.
    Meenakshisundaram S, Parthiban S, Sarathi N, Kalavathy R, Bhagavannarayana G. Effect of organic dopants on ZTS single crystals. J Cryst Growth. 2006;293:376–81.CrossRefGoogle Scholar
  9. 9.
    Ushasree PM, Muralidharan R, Jayavel R, Ramasamy P. Metastable zone width, induction period and interfacial energy of zinc tris(thiourea)sulfate. J Cryst Growth. 2000;210:741–5.CrossRefGoogle Scholar
  10. 10.
    Madhurambal G, Mojumdar SC, Hariharan S, Ramasamy P. TG, DTC, FT-IR and Raman spectral analysis of Zna/Mgb ammonium sulfate mixed crystals. J Therm Anal Calorim. 2004;78:125–33.CrossRefGoogle Scholar
  11. 11.
    Ushasree PM, Jayavel R, Ramasamy P. Growth and characterization of phosphate mixed ZTS single crystals. Mater Sci Eng B. 1999;65:153–8.CrossRefGoogle Scholar
  12. 12.
    Gupte SS, Desai CF. Vickers hardness anisotropy and slip system in zinc(tris)thioureasulphate crystals. Cryst Res Technol. 1999;34:1329–32.CrossRefGoogle Scholar
  13. 13.
    Arunmozhi G, De Gomes EM, Ganesamoorthy S. Growth kinetics of zinc (tris) thiourea sulphate (ZTS) crystals. Cryst Res Technol. 2004;39:408–13.CrossRefGoogle Scholar
  14. 14.
    Meenakshisundarm SP, Parthiban S, Madhurambal G, Mojumdar SC. Effect of chelating agent (1,10-phenanthroline) on potassium hydrogen phthalate crystals. J Therm Anal Calorim. 2008;94:21–5.CrossRefGoogle Scholar
  15. 15.
    Skorsepa JS, Gyoryova K, Melnik M. Preparation, identification and thermal properties of (CH3CH2COO)2Zn·2L·H2O (-L = thiourea, nicotinamide, caffeine or theorbromine). J Therm Anal. 1995;44:169–77.CrossRefGoogle Scholar
  16. 16.
    Mojumdar SC, Raki L. Preparation, thermal, spectral and microscopic studies of calcium silicate hydrate-poly(acrylic acid) nanocomposite materials. J Therm Anal Calorim. 2006;85:99–105.CrossRefGoogle Scholar
  17. 17.
    Sawant SY, Verenkar VMS, Mojumdar SC. Preparation, thermal, XRD, chemical and FT-IR spectral analysis of NiMn2O4 nanoparticles and respective precursor. J Therm Anal Calorim. 2007;90:669–72.CrossRefGoogle Scholar
  18. 18.
    Porob RA, Khan SZ, Mojumdar SC, Verenkar VMS. Synthesis, TG, SDC and infrared spectral study of NiMn2(C4H4O4)3·6N2H4: a precursor for NiMn2O4 nanoparticles. J Therm Anal Calorim. 2006;86:605–8.CrossRefGoogle Scholar
  19. 19.
    Mojumdar SC, Varshney KG, Agrawal A. Hybrid fibrous ion exchange materials: past, present and future. Res J Chem Environ. 2006;10:89–103.Google Scholar
  20. 20.
    Doval M, Palou M, Mojumdar SC. Hydration behaviour of C2S and C2AS nanomaterials, synthesized by sol–gel method. J Therm Anal Calorim. 2006;86:595–9.CrossRefGoogle Scholar
  21. 21.
    Mojumdar SC, Moresoli C, Simon LC, Legge RL. Edible wheat gluten (WG) protein films: preparation, thermal, mechanical and spectral properties. J Therm Anal Calorim. 2011;104:929–36.CrossRefGoogle Scholar
  22. 22.
    Varshney G, Agrawal A, Mojumdar SC. Pyridine based cerium(IV) phosphate hybrid fibrous ion exchanger: synthesis, characterization and thermal behaviour. J Therm Anal Calorim. 2007;90:731–4.CrossRefGoogle Scholar
  23. 23.
    Mojumdar SC, Melnik M, Jona E. Thermal and spectral properties of Mg(II) and Cu(II) complexes with heterocyclic N-donor ligands. J Anal Appl Pyrol. 2000;53:149–60.CrossRefGoogle Scholar
  24. 24.
    Borah B, Wood JL. Complex hydrogen bonded cations. The benzimidazole benzimidazolium cation. Canad J Chem. 1976;50:2470–81.CrossRefGoogle Scholar
  25. 25.
    Mojumdar SC, Sain M, Prasad RC, Sun L, Venart JES. Selected thermoanalytical methods and their applications from medicine to construction. J Therm Anal Calorim. 2007;60:653–62.CrossRefGoogle Scholar
  26. 26.
    Meenakshisundarm SP, Parthiban S, Madhurambal G, Mojumdar SC. Effect of chelating agent (1,10-phenanthroline) on potassium hydrogen phthalate crystals. J Therm Anal Calorim. 2008;94:21–5.CrossRefGoogle Scholar
  27. 27.
    Rejitha KS, Mathew S. Investigations on the thermal behavior of hexaamminenickel(II) sulphate using TG–MS and TR–XRD. Glob J Anal Chem. 2010;1(1):100–8.Google Scholar
  28. 28.
    Pajtášová M, Ondrušová D, Jóna E, Mojumdar SC, Ľalíková S, Bazyláková T, Gregor M. Spectral and thermal characteristics of copper(II) carboxylates with fatty acid chains and their benzothiazole adducts. J Therm Anal Calorim. 2010;100:769–77.CrossRefGoogle Scholar
  29. 29.
    Madhurambal G, Ramasamy P, Anbusrinivasan P, Vasudevan G, Kavitha S, Mojumdar SC. Growth and characterization studies of 2-bromo-4′-chloro-acetophenone (BCAP) crystals. J Therm Anal Calorim. 2008;94:59–62.CrossRefGoogle Scholar
  30. 30.
    Gonsalves LR, Mojumdar SC, Verenkar VMS. Synthesis and characterisation of Co0.8Zn0.2Fe2O4 nanoparticles. J Therm Anal Calorim. 2011;104:869–73.CrossRefGoogle Scholar
  31. 31.
    Raileanu M, Todan L, Crisan M, Braileanu A, Rusu A, Bradu C, Carpov A, Zaharescu M. Sol–gel materials with pesticide delivery properties. J Environ Protect. 2010;1:302–13.CrossRefGoogle Scholar
  32. 32.
    Varshney KG, Agrawal A, Mojumdar SC. Pectin based cerium(IV) and thorium(IV) phosphates as novel hybrid fibrous ion exchangers synthesis, characterization and thermal behaviour. J Therm Anal Calorim. 2005;81:183–9.CrossRefGoogle Scholar
  33. 33.
    Mojumdar SC, Šimon P, Krutošíková A. [1]Benzofuro[3,2-c]pyridine: synthesis and coordination reactions. J Therm Anal Calorim. 2009;96:103–9.CrossRefGoogle Scholar
  34. 34.
    Moricová K, Jóna E, Plško A, Mojumdar SC. Thermal stability of Li2O–SiO2–TiO2 gels evaluated by the induction period of crystallization. J Therm Anal Calorim. 2010;100:817–20.CrossRefGoogle Scholar
  35. 35.
    Mojumdar SC, Miklovic J, Krutosikova A, Valigura D, Stewart JM. Furopyridines and furopyridine–Ni(II) complexes: synthesis, thermal and spectral characterization. J Therm Anal Calorim. 2005;81:211–5.CrossRefGoogle Scholar
  36. 36.
    Vasudevan G, AnbuSrinivasan P, Madhurambal G, Mojumdar SC. Thermal analysis, effect of dopants, spectral characterisation and growth aspects of KAP crystals. J Therm Anal Calorim. 2009;96:99–102.CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2012

Authors and Affiliations

  • G. Madhurambal
    • 1
  • B. Ravindran
    • 2
  • M. Mariappan
    • 2
  • S. C. Mojumdar
    • 3
    • 4
  1. 1.ADM College for WomenNagapattinamIndia
  2. 2.EGS Pillay Engineering CollegeNagapattinamIndia
  3. 3.Department of ChemistryUniversity of GuelphGuelphCanada
  4. 4.Department of Chemical Technologies and Environment, Faculty of Industrial TechnologiesTrenčín University of A. DubčekPúchovSlovakia

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