Journal of Thermal Analysis and Calorimetry

, Volume 107, Issue 3, pp 983–987 | Cite as

Decomposition processes of nickel hydroxide

  • V. Logvinenko
  • V. Bakovets
  • L. Trushnikova


The dehydration processes of nickel hydroxide were studied by means of thermogravimetry in a temperature range from 300 to 900 K. The kinetics of the low-temperature dehydroxylation (≈300–600 K) was studied under non-isothermal conditions. A model-free method was used to calculate the activation energy and to analyze the stepwise checking; the non-linear regression method was applied to calculate the kinetic parameters of multi-stage decomposition reactions. The features of the dehydroxylation kinetics for the multi-stage process are explained by the formation and decomposition of hydrogel and xerogel phases.


Metal hydroxides Model-free kinetics Nano-dimensional materials Non-isothermal kinetics Thermal analysis 


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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2011

Authors and Affiliations

  1. 1.Nikolaev Institute of Inorganic ChemistrySiberian Branch of the Russian Academy of SciencesNovosibirskRussia

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