Skip to main content
Log in

Effect of dopant on the characterization of KAP crystal

Thermal and spectral analysis

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Potassium Hydrogen Phthalate also known as Potassium Acid phthalate (KAP) has 14 natural growth faces with dominating (010) face. As the (010) face is more suitable for any surface morphological studies, a number of crystal growth studies have been made on this material in recent years. Here this semi organic crystal was grown by Slow Evaporation Solution Growth Technique. The effect of ammonium sulphate as dopant on the characteristic properties of KAP crystal was studied by thermal and spectral analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Srinivasan K, Meera K, Ramasamy P. Enhancement of metastable zone width for solution growth of potassium acid phthalate. J Cryst Growth. 1999;205:457–9.

    Article  CAS  Google Scholar 

  2. Miniewicz A. Electro-optic investigations in some molecular-ionic crystals. Mol Cryst Liq Cryst. 1993;229:13–8.

    Article  CAS  Google Scholar 

  3. Meenakshisundarm SP, Parthiban S, Madhurambal G, Mojumdar SC. Effect of chelating agent (1, 10-phenanthroline) on potassium hydrogen phthalate crystals. J Therm Anal Calorim. 2008;94:21–5.

    Article  Google Scholar 

  4. Jayalakshmi D, Kumar J. Growth and characterization of bis thiourea zinc acetate. Cryst Res Technol. 2006;41:37–40.

    Article  CAS  Google Scholar 

  5. Mojumdar SC, Mazanec K, Drabik M. Macro-defect-free (MDF) cements: synthesis, thermal, chemical, SEM and magnetometric study and moisture Resistance. J Therm Anal Calorim. 2006;83:135–9.

    Article  CAS  Google Scholar 

  6. Sweta M, Tanusree K. Growth and characterization of nonlinear optical crystal zinc tris (thiourea) sulphate in presence of l-arginine. Optical Mat. 2007;30:508–12.

    Article  Google Scholar 

  7. Mojumdar SC, Raki L. Preparation, thermal, spectral and microscopic studies of calcium silicate hydrate-poly(acrylic acid) nanocomposite materials. J Therm Anal Calorim. 2006;85:99–105.

    Article  CAS  Google Scholar 

  8. Ezhilvizhi R, Kalainathan S, Bagavannarayana G. Structural and microhardness studies of purea and thiourea doped glycine phosphate single crystal. Cryst Res Technol. 2008;43:778–82.

    Article  Google Scholar 

  9. Meera K, Muralidharan R, Tripathi AK, Dhanasekaran R. Growth of thiourea-doped TGS crystals and their characterization. J Cryst Growth. 2004;260:414–21.

    Article  CAS  Google Scholar 

  10. Mojumdar SC. Processing-moisture resistance and thermal analysis of MDF materials. J Therm Anal Calorim. 2001;64:1133–9.

    Article  CAS  Google Scholar 

  11. Ambujam K, Thomas PC, Aruna S. Growth and characterization of dichloro tetrakis thiourea nickel single crystals. Cryst Res Technol. 2006;41:1082–8.

    Article  CAS  Google Scholar 

  12. Meenakshisundaram S, Parthiban S, Sarathi N, Kalavathy R, Bhagavannarayana G. Effect of organic dopants on ZTS single crystals. J Cryst Growth. 2006;293:376–81.

    Article  CAS  Google Scholar 

  13. Mojumdar SC. Thermal properties, environmental deterioration and applications of macro-defect-free cements. Res J Chem Environ. 2005;9:23–7.

    CAS  Google Scholar 

  14. Arunmozhi G, De Gomes EM, Ganesamoorthy S. Growth kinetics of zinc (tris) thiourea sulphate (ZTS) crystals. Cryst Res Technol. 2004;39:408–13.

    Article  CAS  Google Scholar 

  15. Skorsepa JS, Gyoryova K, Melnik M. Preparation, identification and thermal properties of (CH3CH2COO)2Zn·2L·H2O (-L  = thiourea, nicotinamide, caffeine or theorbromine). J Therm Anal. 1995;44:169–77.

    Article  CAS  Google Scholar 

  16. Madhurambal G, Mojumdar SC, Hariharan S, Ramasamy P. TG, DTC, FT-IR and Raman spectral analysis of Zna/Mgb ammonium sulfate mixed crystals. J Therm Anal Calorim. 2004;78:125–33.

    Article  CAS  Google Scholar 

  17. Ushasree PM, Jayavel R, Ramasamy P. Growth and characterization of phosphate mixed ZTS single crystals. Mater Sci Eng B. 1999;65:153–8.

    Article  Google Scholar 

  18. Gupte SS, Desai CF. Vickers hardness anisotropy and slip system in zinc(tris)thioureasulphate crystals. Cryst Res Technol. 1999;34:1329–32.

    Article  CAS  Google Scholar 

  19. Selvaraju K, Valluvan R, Kumararaman S. A new metal organic potassium thiourea chloride single crystal. Mat Lett. 2006;44:577–81.

    Google Scholar 

  20. Rajasekaran R, Rajendran KV. Investigation on nucleation of cadmium thiourea chloride single crystals. Mater Chem Phys. 2003;82:273–80.

    Article  CAS  Google Scholar 

  21. Sawant SY, Verenkar VMS, Mojumdar SC. Preparation, thermal, XRD, chemical and FT-IR spectral analysis of NiMn2O4 nanoparticles and respective precursor. J Therm Anal Calorim. 2007;90:669–72.

    Article  CAS  Google Scholar 

  22. Porob RA, Khan SZ, Mojumdar SC, Verenkar VMS. Synthesis, TG, SDC and infrared spectral study of NiMn2(C4H4O4)3·6N2H4–A precursor for NiMn2O4 nanoparticles. J Therm Anal Calorim. 2006;86:605–8.

    Article  CAS  Google Scholar 

  23. Mojumdar SC, Varshney KG, Agrawal A. Hybrid fibrous ion exchange materials: past, present and future. Res J Chem Environ. 2006;10:89–103.

    CAS  Google Scholar 

  24. Doval M, Palou M, Mojumdar SC. Hydration behaviour of C2S and C2AS nanomaterials, synthesized by sol-gel method. J Therm Anal Calorim. 2006;86:595–9.

    Article  CAS  Google Scholar 

  25. Tiwari NR, Rathore A, Prabhune A, Kulkarni SK. Gold Nanoparticles for colorimetric detection of hydrolysis of antibiotics by penicillin G acylase. Adv Biosci Biotechnol. 2010;1:322–9.

    Article  Google Scholar 

  26. Varshney G, Agrawal A, Mojumdar SC. Pyridine based cerium(IV) phosphate hybrid fibrous ion exchanger: Synthesis, characterization and thermal behaviour. J Therm Anal Calorim. 2007;90:731–4.

    Article  CAS  Google Scholar 

  27. Mojumdar SC, Melnik M, Jona E. Thermal and spectral properties of Mg(II) and Cu(II) complexes with heterocyclic N-donor ligands. J Anal Appl Pyrolysis. 2000;53:149–60.

    Article  CAS  Google Scholar 

  28. Borah B, Wood JL. Complex hydrogen bonded cations. The benzimidazole benzimidazolium cation. Can J Chem. 1976;50:2470–81.

    Article  Google Scholar 

  29. Mojumdar SC, Sain M, Prasad RC, Sun L, Venart JES. Selected thermoanalytical methods and their applications from medicine to construction. J Therm Anal Calorim. 2007;60:653–62.

    Article  Google Scholar 

  30. Rejitha KS, Mathew S. Investigations on the thermal behavior of hexaamminenickel(II) sulphate using TG-MS and TR-XRD. Glob J Anal Chem. 2010;1(1):100–8.

    Google Scholar 

  31. Ondrusova D, Jona E, Simon P. Thermal properties of N-ethyl-N-phenyldithiocarbamates and their influence on the kinetics of cure. J Therm Anal Calorim. 2002;67:147–52.

    Article  CAS  Google Scholar 

  32. Madhurambal G, Ramasamy P, Anbusrinivasan P, Vasudevan G, Kavitha S, Mojumdar SC. Growth and characterization studies of 2-bromo-4′-chloro-acetophenone (BCAP) crystals. J Therm Anal Calorim. 2008;94:59–62.

    Article  CAS  Google Scholar 

  33. Ukraintseva EA, Logvinenko VA, Soldatov DV, Chingina TA. Thermal dissociation processes for clathrates [CuPy4(NO3)2]·2G (G = tetrahydrofurane, chloroform). J Therm Anal Calorim. 2004;75:337–45.

    Article  CAS  Google Scholar 

  34. Raileanu M, Todan L, Crisan M, Braileanu A, Rusu A, Bradu C, Carpov A, Zaharescu M. Sol-gel materials with pesticide delivery properties. J Environ Protect. 2010;1:302–13.

    Article  CAS  Google Scholar 

  35. Varshney KG, Agrawal A, Mojumdar SC. Pectin based cerium(IV) and thorium(IV) phosphates as novel hybrid fibrous ion exchangers synthesis, characterization and thermal behaviour. J Therm Anal Calorim. 2005;81:183–9.

    Article  CAS  Google Scholar 

  36. Mojumdar SC, Šimon P, Krutošíková A. [1]Benzofuro[3, 2-c]pyridine: synthesis and coordination reactions. J Therm Anal Calorim. 2009;96:103–9.

    Article  CAS  Google Scholar 

  37. Jona E, Rudinska E, Sapietova M, Pajtasova M, Ondrusova D, Jorik V, Mojumdar SC. Interaction of pyridine derivatives into the interlayer spaces of Cu(II)-montmorillonites. Res J Chem Environ. 2005;9:41–3.

    CAS  Google Scholar 

  38. Mojumdar SC, Miklovic J, Krutosikova A, Valigura D, Stewart JM. Furopyridines and furopyridine-Ni(II) complexes—synthesis, thermal and spectral characterization. J Therm Anal Calorim. 2005;81:211–5.

    Article  CAS  Google Scholar 

  39. Mojumdar SC. Thermoanalytical and IR spectroscopy investigation of Mg(II) complexes with heterocyclic ligands. J Therm Anal Calorim. 2001;64:629–36.

    Article  CAS  Google Scholar 

  40. Vasudevan G, AnbuSrinivasan P, Madhurambal G, Mojumdar SC. Thermal analysis, effect of dopants, spectral characterisation and growth aspects of KAP crystals. J Therm Anal Calorim. 2009;96:99–102.

    Article  CAS  Google Scholar 

  41. Rao CNR. Ultraviolet and visible spectroscopy, chemical applications. New York: Plenum Press; 1975.

    Google Scholar 

  42. Kalsi P. Spectroscopy of organic compounds. New Delhi: Wiley Eastern; 1987.

    Google Scholar 

  43. Dyer JR. Applications of absorption spectroscopy of organic compounds. New Delhi: Prentice-hall of India; 1987.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. C. Mojumdar.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vasudevan, G., AnbuSrinivasan, P., Madhurambal, G. et al. Effect of dopant on the characterization of KAP crystal. J Therm Anal Calorim 104, 975–979 (2011). https://doi.org/10.1007/s10973-011-1493-x

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-011-1493-x

Keywords

Navigation