Thermo-oxidative decomposition of biodiesel samples obtained from mixtures of beef tallow, soybean oil, and babassu oil
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Biodiesel can be obtained from various fatty acid sources. Each raw material has a different chemical composition that leads to different properties. Owing to these properties, the mixture of different proportions of raw materials can lead to biodiesels with best features in relation to physicochemical parameters such as viscosity, oxidative stability and flow properties, generating a fuel whose characteristics meet the requirements of the current legislation of the Brazilian National Agency of Petroleum, Natural Gas and Biofuels (ANP). The objective of this study was to determine the physicochemical properties of biodiesel samples produced from mixtures of beef tallow, babassu oil, and soybean oil. The thermo-oxidative stability was evaluated using thermogravimetry (TG/DTG) and differential scanning calorimetry (DSC). The results showed that all samples were in accordance to the ANP specifications. The biodiesel obtained from a mixture containing 50% of babassu oil had lower values of pour point, cold filter plugging point, and freezing point. This biodiesel also showed a higher thermo-oxidative stability in synthetic air and in oxygen atmospheres.
KeywordsBiodiesel TG DSC Blends
The authors acknowledge the following Brazilian Agencies for the financial support of this study: Research and Projects Financing (FINEP/MCT) and Coordination for the Improvement of Higher Education Personnel (CAPES).
- 16.SMAOFD - Standard methods for the analysis of oils, fats and derivatives. In: International Union of Pure and Applied Chemistry, Method 2507. 7th ed. Boston: IUPAC; 1987.Google Scholar
- 17.ANP – National agency of petrol, natural gas and biofuels. Resolução nº. 07, de 19 de março de 2008. http://www.anp.gov.br. Accessed 10 Jan 2010. (in Portuguese).