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The role of thermal analysis in detecting impurity levels during aluminum recycling

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Abstract

Recycling of aluminum scrap has gained interest owing to its economic and ecological benefits. Unfortunately, during the collection of scrap from a mixer of junk from various sectors it is difficult to ensure that the recycled alloy has the same chemical composition as that of already existing commercial alloys. Consequently, some of the alloying elements become trace/tramp elements in the recycled alloy. Therefore, in order to obtain high performance recycled alloys, controlling the impurity levels of the aluminum melt is of vital importance. Normally, computer aided cooling curve analysis (CA-CCA) is used to find the relationship between cooling curve parameters, melt treatments, alloy composition, and properties. In the present study, the first differential thermal analysis (DTA) approach has been used to detect and quantify impurity elements in scrap-like liquid aluminum alloys.

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References

  1. Mahfoud M. Controlled thermal analysis using heat pipe technology. PhD Thesis, McGill University, 1997.

  2. Khalifa W, Samuel FH, Gruzleski JE. Nucleation of solid aluminum on inclusion particles injected into Al–Si–Fe alloys. Metall Mater Trans. 2003;34A:807–25.

    CAS  Google Scholar 

  3. Rilvin VG, Raynor GV. Critical evaluation of constitution of aluminum–iron–silicon system. Int Metall Rev. 1981;3:133–52.

    Google Scholar 

  4. Narayanan A, Samuel FH, Gruzleski JE. Crystallization behaviour of iron-containing intermetallic compounds in 319 aluminium alloy. Metall Mater Trans. 1994;25A:1761–73.

    Article  CAS  Google Scholar 

  5. Sreeja Kumari SS, Pillai RM, Rajan TPD, Pai BC. The effects of individual and combined additions of Be, Mn, Ca and Sr on the solidification, structure and mechanical properties of Al–7Si–0.3Mg–0.8Fe alloy. Mater Sci Eng. 2007;460-461A:561–73.

    Google Scholar 

  6. Prasada Rao AK, Das K, Murty BS, Chakraborty M. Prediction of grain size of Al–7Si alloy by neural networks. Mater Lett. 2008;62(2):273.

    Article  CAS  Google Scholar 

  7. Prasada Rao AK, Das K, Murty BS, Chakraborty M. Al-Ti-C-Sr master alloy - A melt inoculant for simultaneous grain refinement and modification of hypo-eutectic Al-Si alloys. J Alloys Compd. 2009; 480(2):L49–51.

    Article  Google Scholar 

  8. Mahfoud M, Emadi D. Advances in materials and processing technologies (AMPT) conference. Manama, Kingdom of Bahrain, Nov; 2008.

  9. Mahfoud M, Emadi D. 2nd International aluminum casting conference & exhibition, Moscow, Russia, April 1–3; 2009.

  10. Emadi D, Whiting LV. Determination of solidification characteristics of Al-Si alloys by thermal analysis. AFS Trans. 2002; 110(1):285–96

    CAS  Google Scholar 

  11. Fornaro O, Palacio HA. Study of dilute Al–Cu solidification by cooling curve analysis J Mater Sci. 2009; 44(16):4342–4347.

    Google Scholar 

  12. Emadi D. In: Proceedings of the 12th annual technical meeting & exhibition of the Canadian thermal analysis society (CTAS), Mississauga, Canada, 14–15 May 2002; p. 58.

  13. Pelayo G, Sokolowski JH, Lashkari R. A case based reasoning aluminium thermal analysis platform for the prediction of W319 Al cast component characteristics. J Achiev Mfg Eng. 2009; 36(1):7–17.

    Google Scholar 

  14. Malekan M, Shabestari SG. Effect of grain refinement on the dendrite coherency point during solidification of the A319 aluminum alloy. Metall Mater Trans. 2009;40A:3196–203.

    Article  CAS  Google Scholar 

  15. Mahfoud M, Emadi D. Application of heat pipe technology in thermal analysis of metals. J Therm Anal Calorim. 2005;81:161–7.

    Article  CAS  Google Scholar 

  16. Mackay RI. Quantification of iron content in Al–Si foundry alloys via thermal Analysis. Master’s Thesis, McGill University, 1996.

  17. Phillips HWL. Institute of Metals Monograph and Report Series, 1959; No. 25: p. 56.

  18. Phillips HW. Annotated equilibrium diagrams of some aluminum alloy systems. London: The Institute of Metals; 1976.

    Google Scholar 

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Acknowledgements

The authors would like to express their appreciation to Qatar National Research Fund for their financial support. The technical assistance of the staff at Qatar University (Department of Mechanical and Industrial Engineering), McGill University (Department of Materials Engineering) and College of North the Atlantic-Qatar is very much appreciated.

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Correspondence to Daryoush Emadi.

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Mahfoud, M., Prasada Rao, A.K. & Emadi, D. The role of thermal analysis in detecting impurity levels during aluminum recycling. J Therm Anal Calorim 100, 847–851 (2010). https://doi.org/10.1007/s10973-010-0742-8

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  • DOI: https://doi.org/10.1007/s10973-010-0742-8

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