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Journal of Thermal Analysis and Calorimetry

, Volume 101, Issue 3, pp 1027–1037 | Cite as

Thermal properties of PA 6 and PA 6 modified with copolyamides and layered silicates

  • J. Ryba
  • A. Ujhelyiová
  • M. Krištofič
  • I. Vassová
Article

Abstract

This article focuses on the thermal properties of PA 6 and additives, i.e. ternary copolyamides, concentrates consisting of binary or ternary copolyamides + nanoadditive montmorillonite Bentonite 11958 or Cloisite 15A and PA 6 fibres modified with Bentonite, copolyamide and concentrate. The copolyamides are prepared from ε-caprolactam as a major comonomer and nylon salts AN2 from adipic acid + 1-(2-aminoethyl)piperazine and ADETA from adipic acid + diethylenetriamine. All copolyamides and concentrates exhibit lower melting temperatures T m and lower melting enthalpies ΔH m compared to neat PA 6. PA 6 fibres modified with 0.25–2.5 wt% MMT exhibit higher melting enthalpies in comparison with unmodified PA 6 fibres. PA 6 fibres modified with 10 wt% of ternary copolyamide containing 21.4 wt% of comonomers AN2 and ADETA have higher melting enthalpy as well. PA 6 fibres modified with 10 and 20 wt% of concentrate containing the same ternary copolyamide + 5 wt% of MMT have higher melting enthalpies and higher tensile strength in comparison with these characteristics of unmodified PA 6 fibres.

Keywords

DSC Copolyamides Nanoadditives 

Notes

Acknowledgements

This study was supported by the Slovak Research and Development Agency under the contract APVV-0226-06 and VEGA Agency under the contract No 1/0406/08

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2010

Authors and Affiliations

  • J. Ryba
    • 1
  • A. Ujhelyiová
    • 1
  • M. Krištofič
    • 1
  • I. Vassová
    • 1
  1. 1.Department of Fibres and Textile Chemistry, Faculty of Chemical and Food Technology, Institute of Polymer MaterialsSlovak University of Technology in BratislavaBratislavaSlovak Republic

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