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Coordination and inclusion compounds formed by addition of quinoline (Q) or isoquinoline (Iq) to a metal(II) dibenzoylmethanate (Co, Ni, Zn, Cd)

Composition, structure and thermal dissociation properties

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Abstract

Three isomorphous series of new compounds are reported: complexes [M(DBM)2Q2] and [M(DBM)2Iq2] (M = M(II) = Co, Ni, Zn, Cd; DBM is C6H5COCHCOC6H5 −) and inclusion compounds [M(DBM)2Q2]*Q (M = Co, Zn, Cd). All the compounds comprise a trans configured octahedral complex molecule. Inclusion compounds of modified Zn and Cd DBM complexes are reported for the first time and their inclusion ability is attributed to the trans isomeric state induced by the bulky Q or Iq ligand. The TG measurements indicate the following order of thermal stability of the complexes defined by the strength of the metal–ligand bonds: Ni > Co > Cd > Zn. The inclusion compounds do not follow this trend.

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Acknowledgements

This study was financially supported by the University of Guelph through a start-up grant and by the Natural Sciences and Engineering Research Council through a Discovery Grant and Research Tools and Equipment Grant. We thank G. D. Enright and K. A. Udachin (Materials Structure and Function group at SIMS NRC), and S. F. Kycia and A. Gomez (Department of Physics at University of Guelph) for help with XRD measurements. We also thank D. Ben-Israel (University of Guelph) for TG of metal DBMs.

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    E. B. Okeke & D. V. Soldatov

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Okeke, E.B., Soldatov, D.V. Coordination and inclusion compounds formed by addition of quinoline (Q) or isoquinoline (Iq) to a metal(II) dibenzoylmethanate (Co, Ni, Zn, Cd). J Therm Anal Calorim 100, 801–810 (2010). https://doi.org/10.1007/s10973-010-0689-9

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